银催化多组分条件产生亚胺自由基与反应研究

21871043
2018
B0108.新反应与新试剂
毕锡和
面上项目
教授
东北师范大学
66万元
官能团迁移;银催化;亚胺自由基;多组分反应;炔烃
2019-01-01到2022-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 The merger of vinyl-N-triftosylhydrazones and silver catalysis to enable stereoselective vinylcyclopropanation of alkenes 期刊论文 Yong Yang;Zhaohong Liu;Qingmin Song;Paramasivam Sivaguru;Giuseppe Zanoni;Kuan Wang;Qiaowei Bi;Xihe Bi
2 Difluoroacetaldehyde N-triftosylhydrazone (DFHZ-Tfs) as a bench-stable crystalline diazo surrogate for diazoacetaldehyde and difluorodiazoethane 期刊论文 Yingying Wang;Bhoomireddy Rajendra Prasad Reddy;Giuseppe Zanoni;Xihe Bi
3 Chemoselective carbene insertion into the N−H bonds of NH3·H2O 期刊论文 Zhaohong Liu;Yong Yang;Qingmin Song;Linxuan Li;Giuseppe Zanoni;Shaopeng Liu;Meng Xiang;Edward A. Anderson;Xihe Bi
4 大量制备α-乙烯基叠氮类化合物的合成方法 专利 毕锡和;季庆贺;曹姗姗
5 Defluorinative [4 + 1] annulation of perfluoroalkyl N-mesylhydrazones with primary amines provides 5-fluoroalkyl 1,2,3-triazoles 期刊论文 Yongquan Ning;Hongwei Wang;Paramasivam Sivaguru;Shuang Li;Giuseppe Zanoni;Steven P. Nolan;Xihe Bi
6 Fluoroalkyl N-triftosylhydrazones as easily decomposable diazo surrogates for asymmetric [2 + 1] cycloaddition: Synthesis of chiral fluoroalkyl cyclopropenes and cyclopropanes 期刊论文 Xinyu Zhang;Chunqi Tian;Zhanjing Wang;Paramasivam Sivaguru;Steven P. Nolan;Xihe Bi
7 Silver-catalyzed C- to N-center remote arene migration 期刊论文 Yongquan Ning;Aroonroj Mekareeya;Kaki Raveendra Babu;Edward A. Anderson;Xihe Bi
8 Direct transformation of terminal alkynes into amidines by a silver-catalyzed four-component reaction 期刊论文 Binbin Liu;Yongquan Ning;Matteo Virelli;Giuseppe Zanoni;Edward A. Anderson;Xihe Bi
9 Direct gem-difluoroalkenylation of X–H bonds with trifluoromethyl ketone N-triftosylhydrazones for synthesis of tetrasubstituted heteroatomic gem-difluoroalkenes 期刊论文 Xinyu Zhang;Linxuan Li;Giuseppe Zanoni;Xinyue Han;Xihe Bi
10 Neighbouring carbonyl group-assisted sequential 1,2-azide and 1,4-oxygen migrations of vinyl azides leading to α-azido ketones 期刊论文 Yi Gai;Yongquan Ning;Paramasivam Sivaguru;Xiaomeng Li;Yue Zhao;Jiayi Wu;Xihe Bi
11 Cleavage of carbon–carbon bonds by radical reactions 期刊论文 Paramasivam Sivaguru;Zikun Wang;Giuseppe Zanoni;Xihe Bi
12 一种α-偕二氟叠氮化合物及其制备方法和应用 专利 毕锡和;宁永泉;张欣宇
13 Silver-catalyzed anti-Markovnikov hydroboration of C–C multiple bonds 期刊论文 Yan Wang;Rui Guan;Paramasivam Sivaguru;Xuefeng Cong;Xihe Bi
14 N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry 期刊论文 Zhaohong Liu;Paramasivam Sivaguru;Giuseppe Zanoni;Xihe Bi
15 [4 + 1] Annulation of in situ generated azoalkenes with amines:A powerful approach to access 1-substituted 1,2,3-triazoles 期刊论文 Wang Hongwei;Ning Yongquan;Sivaguru Paramasivam;Zanoni Giuseppe;Bi Xihe
16 Silver-catalyzed sequential cascade reaction of isocyanides with 1-(2-Ethynyl-phenyl)-prop-2-yn-1-ol: Access to benzo[b]fluorenes and benzofuran-pyrroles 期刊论文 Jian-Quan Liu;Xinyi Chen;Xuanyu Shen;Yihan Wang;Xiang-Shan Wang;Xihe Bi
17 Computational studies on reaction mechanism of the catalyst-controlled selective insertion of metal carbenoids into C–C and C–H bonds of 1,3-dicarbonyI compounds 期刊论文 Cao Shanshan;Liu Zhaohong;Yuan Haiyan;Yang Liu;Zhang Jingping;Bi Xihe
18 Dearomative [4 + 3] cycloaddition of furans with vinyl-N-triftosylhydrazones by silver catalysis: stereoselective access to oxa-bridged seven-membered bicycles 期刊论文 Zhaohong Liu;Yong Yang;Xinyu Jiang;Qingmin Song;Giuseppe Zanoni;Shaopeng Liu;Xihe Bi
19 Synthesis of β-difluoroalkyI azides via elusive 1,2-azide migration 期刊论文 Yongquan Ning;Paramasivam Sivaguru;Giuseppe Zanoni;Edward A. Anderson;Xihe Bi
20 Defluorinative Carboimination of Trifluoromethyl Ketones 期刊论文 Xiaolong Zhang;Yongquan Ning;Zhaohong Liu;Shuang Li;Giuseppe Zanoni;Xihe Bi
21 Carbodefluorination of fluoroalkyl ketones via a carbene-initiated rearrangement strategy 期刊论文 Linxuan Li;Xinyu Zhang;Yongquan Ning;Xiaolong Zhang;Binbin Liu;Zhansong Zhang;Paramasivam Sivaguru;Giuseppe Zanoni;Shuang Li;Edward A. Anderson;Xihe Bi
22 Synthetic exploration of sulfinyI radicals using sulfinyl sulfones 期刊论文 Zikun Wang;Zhansong Zhang;Wanjun Zhao;Paramasivam Sivaguru;Giuseppe Zanoni;Yingying Wang;Edward A. Anderson;Xihe Bi
23 Silver-catalyzed site-selective C(sp3)−H benzylation of ethers with N-triftosylhydrazones 期刊论文 Zhaohong Liu;Hongwei Wang;Paramasivam Sivaguru;Steven P. Nolan;Qingmin Song;Weijie Yu;Xinyu Jiang;Edward A. Anderson;Xihe Bi
24 Computational insights into different mechanisms for Ag-, Cu-, and Pd-catalyzed cyclopropanation of alkenes and sulfonyl hydrazones 期刊论文 Yong Wu;Shanshan Cao;Iskander Douair;Laurent Maron;Xihe Bi
25 Silver-Catalyzed Vinylcarbene Insertion into C–C Bonds of 1,3-Diketones with Vinyl-N-triftosylhydrazones 期刊论文 Yong Wu;Yongquan Ning;Xinyue Han;Peiqiu Liao;Ying Xia;Paramasivam Sivaguru;Xihe Bi
26 Silver-catalyzed unstrained C(CO)-alkyl bond scission via [3+2]/retro-[3+2] cycloaddition of ketones with N-isocyanoiminotriphenylphosphorane 期刊论文 Zikun Wang;Linxuan Li;Xueying Zhang;Xihe Bi
27 Highly electrophilic silver carbenes 期刊论文 Xiaolong Zhang;Linxuan Li;Paramasivam Sivaguru;Giuseppe Zanoni;Xihe Bi
28 Use of trifluoroacetadehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications 期刊论文 Xinyu Zhang;Zhaohong Liu;Xiangyu Yang;Yuanqing Dong;Matteo Virelli;Giuseppe Zanoni;Edward A. Anderson;Xihe Bi
29 New strategies for the synthesis of aliphatic azides 期刊论文 Paramasivam Sivaguru;Yongquan Ning;Xihe Bi
30 Fluoroalkyl N-sulfonyl hydrazones: An efficient reagent for the synthesis of fluoroalkylated compounds 期刊论文 Paramasivam Sivaguru;Xihe Bi
31 Directed copper-catalyzed intermolecular aminative difunctionalization of unactivated alkenes 期刊论文 Yang Li;Yujie Liang;Junchao Dong;Yi Deng;Chunyang Zhao;Zhongmin Su;Wei Guan;Xihe Bi;Qun Liu;Junkai Fu
32 Silver-catalyzed cyclopropanation of alkenes with alkynyl N-nosylhydrazones leading to alkynyl cyclopropanes 期刊论文 Yongquan Ning;Mengtian Huo;Lizuo Wu;Xihe Bi
33 Ag-catalyzed insertion of alkynyl carbenes into C−C bonds of β-ketocarbonyls: A formal C(sp2) insertion 期刊论文 Yongquan Ning;Qingmin Song;Paramasivam Sivaguru;Lizuo Wu;Edward A. Anderson;Xihe Bi
34 Silver-catalyzed reduction of quinolines in water 期刊论文 Yan Wang;Baobiao Dong;Zikun Wang;Xuefeng Cong;Xihe Bi
35 Synthesis of β-difluoroalkyI azides via elusive 1,2-azide migration 期刊论文 Yongquan Ning;Paramasivam Sivaguru;Giuseppe Zanoni;Edward A. Anderson;Xihe Bi
36 Silver-mediated [3 + 2] cycloaddition of alkynes and N-isocyanoiminotriphenylphosphorane: Access to monosubstituted pyrazoles 期刊论文 Fanhua Yi;Wanjun Zhao;Zikun Wang;Xihe Bi
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