【21172029】基于双烷硫基α-烯基联烯的成环反应研究国家自然基金项目

基于双烷硫基α-烯基联烯的成环反应研究

项目批准号： 21172029

批准年份： 2011

学科分类： B0105.催化合成反应

项目负责人：毕锡和

资助类别：面上项目

负责人职称：教授

依托单位：东北师范大学

资助金额： 60万元

关键词：成环反应;双烷硫基a-烯基联烯;碳环;杂环;新合成子

起止时间： 2012-01-01到2015-12-31

中英文摘要
结题摘要
结题报告
项目成果
项目参与人

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序号	标题	类型	作者
1	Decarbonylative C￠C Bond-Forming Reactions of Saccharins by Nickel Catalysis: Homocoupling and Cycloaddition	期刊论文	Mi Pengbing\|Liao Peiqiu\|Tu Tao\|Bi Xihe\|
2	Synthesis of N-sulfonylazetidin-2-imines via the copper(I) oxide catalyzed multicomponent reaction of alkynes, sulfonyl azides and diimines under solvent-free conditions	期刊论文	Yi Xiaohu\|Barry Badru-Deen\|Liao Peiqiu\|Bi Xihe\|
3	Lewis and Br？nsted acid cocatalyzed reductive deoxyallenylation of propargylic alcohols with 2-nitrobenzenesulfonylhydrazide	期刊论文	Zhaohong Liu\|Peiqiu Liao\|Xihe Bi\|
4	Chemoselective Oxidative C(CO)-C(methyl) Bond Cleavage of Methyl Ketones to Aldehydes Catalyzed by CuI with Molecular Oxygen	期刊论文	Li XQ\|Liu Q\|Barry BD\|Liao PQ\|
5	Base-catalyzed intramolecular 5-exo-dig cyclization of 2-propynyl-1,3- dicarbonyl compounds: An atom-economic route to stereodefined 2-methylene-2,3-dihydrofurans	期刊论文	Zhao Yuegang\|Liao Peiqiu\|Sun Bo\|Bi Xihe\|
6	Intramolecular hydrogen bonding-assisted cyclocondensation of α-diazoketones with various amines: A strategy for highly efficient Wolff 1,2,3-triazole synthesis	期刊论文	Liao PQ\|Zhang R\|Liang YJ\|Dong DW\|
7	Synthesis of dihydrothiophenes and thiophenes by the strategic use of 2-vinylidene-1,3-dithiolane as a masked thiolate anion	期刊论文	Wang YM\|Zhou BY\|Yang Y\|Bi XH\|
8	Coinage Metal-Catalyzed Reactions of PropargylicAlcohols	期刊论文	Zhang Lin\|Fang Guichun\|Kumar Rapolu Kiran\|Bi Xihe\|
9	An atom-economic route to thiophenes and 2,2′-bithiophenes by intramolecular transannulation of gem-dialkylthio enynes	期刊论文	Gou Mingyu\|Liu Qun\|Li Xingqi\|Bi Xihe\|
10	Silver(I)-catalyzed hydroazidation of ethynyl carbinols: Synthesis of 2-azidoallyl alcohols	期刊论文	Zhang L.\|Liao P.\|Song J.\|Bi X.\|
11	Regiospecific β-lactam ring-opening/recyclization reactions of N-aryl-3-spirocyclic-β-lactams catalyzed by a Lewis-Br？nsted acids combined superacid catalyst system: A new entry to 3-spirocyclicquinolin-4(1H)- ones	期刊论文	Fu Xiaolan\|Barry Badru-Deen\|Bi Xihe\|Dong Dewen\|
12	Base-catalyzed intramolecular 5-exo-dig cyclization of 2-propynyl-1,3- dicarbonyl compounds: An atom-economic route to stereodefined 2-methylene-2,3-dihydrofurans	期刊论文	Yuegang Zhao\|Peiqiu Liao\|Bo Sun\|Xihe Bi\|
13	Silver-catalyzed cross-coupling of propargylic alcohols with isocyanides: An atom-economical synthesis of 2,3-ALLENAMIDES	期刊论文	Liu Zhenhua\|Wu Nanan\|Liao Peiqiu\|Bi Xihe\|
14	Chemoselective oxidative C(CO)-C(methyl) bond cleavage of methyl ketones to aldehydes catalyzed by CuI with molecular oxygen	期刊论文	Li Xingqi\|Liu Qun\|Barry Badru-Deen\|Liao Peiqiu\|
15	Silver-catalyzed cross-coupling of propargylic alcohols with isocyanides: An atom-economical synthesis of 2,3-ALLENAMIDES	期刊论文	Liu ZH\|Wu NN\|Liao PQ\|Bi XH\|
16	General silver-catalyzed hydroazidation of terminal alkynes by combining TMS-N3 and H2O: Synthesis of vinyl azides	期刊论文	Liu Z.\|Liao P.\|Bi X.\|
17	Iron-Catalyzed [4C+1N] Cyclization of 4-Acetylenic Ketones with Primary Amines: Synthesis of 5-(Aryl)alkylidene-4,5-dihydropyrroles	期刊论文	Wang Yeming\|Zhao Yuegang\|Liao Peiqiu\|Bi Xihe\|
18	铜催化炔基溴与丙炔醇的偶联-异构化反应合成戊炔烯酮	期刊论文	杨宗莲\|廖沛球\|李兴奇\|毕锡和\|
19	Silver-catalyzed cyclization of 2-pyridyl alkynyl carbinols with isocyanides: Divergent synthesis of indolizines and pyrroles	期刊论文	Meng Xianyu\|Liao Peiqiu\|Liu Jianquan\|Bi Xihe\|
20	Silver(I)-catalyzed hydroazidation of ethynyl carbinols: Synthesis of 2-azidoallyl alcohols	期刊论文	Zhang Lin\|Liao Peiqiu\|Song Jinna\|Bi Xihe\|
21	Copper-mediated chelation-assisted ortho nitration of (hetero)arenes	期刊论文	Barry Badru-Deen\|Belay Tuemay Abadi\|Bi Xihe\|Liu Qun\|
22	Direct C(sp 2)-H chlorination of ketene dithioacetals using FeCl 3 as the chloride source and PhI(OAc) 2 as an oxidant	期刊论文	Fang ZX\|Barry BD\|Liao PQ\|Bi XH\|
23	Synthesis of dihydrothiophenes and thiophenes by the strategic use of 2-vinylidene-1,3-dithiolane as a masked thiolate anion	期刊论文	Wang Yeming\|Zhou Biying\|Yang Yang\|Bi Xihe\|
24	Silver-Catalyzed Tandem Hydroazidation/Alkyne？Azide Cycloaddition of Diynes with TMS？N3: An Easy Access to 1,5-Fused 1,2,3-Triazole Frameworks	期刊论文	Yu Haifeng\|Liao Peiqiu\|Li Xingqi\|Bi Xihe\|
25	Regiospecific β-lactam ring-opening/recyclization reactions of N-aryl-3-spirocyclic-β-lactams catalyzed by a Lewis-Br？nsted acids combined superacid catalyst system: A new entry to 3-spirocyclicquinolin-4(1H)- ones	期刊论文	Fu XL\|Barry BD\|Bi XH\|Dong DW\|
26	Metal-free hydroacyloxylation and hydration reactions of ynamides: synthesis of α-acyloxyenamides and N-acylsulfonamides	期刊论文	Xu Shijie\|Liu Jianquan\|Hu Donghua\|Bi Xihe\|
27	Solvent-controlled, regio-switchable formation of 3-/5-arylaminopyrazole isomer in cyclocondensation of β-aminoenones with hydrazides: Intermolecular hydrogen bonding plays a role	期刊论文	Fang Guichun\|Wang Zikun\|Xin Xiaoqing\|Dong Dewen\|
28	Cycloaddition of propargylic alcohols and α-oxo ketene dithioacetals: Synthesis of functionalized cyclopentadienes and further application in a diels-alder reaction	期刊论文	Fang Zhongxue\|Liu Jianquan\|Liu Qun\|Bi Xihe\|
29	Lewis and Br？nsted acid cocatalyzed reductive deoxyallenylation of propargylic alcohols with 2-nitrobenzenesulfonylhydrazide	期刊论文	Liu Zhenhua\|Liao Peiqiu\|Bi Xihe\|
30	Gem-Dialkylthio vinylallenes: Alkylthio-regulated reactivity and application in the divergent synthesis of pyrroles and thiophenes	期刊论文	Liao Peiqiu\|Zhang Jingping\|Liu Qun\|Bi Xihe\|
31	Catalytic C-H α-trifluoromethylation of α,β-unsaturated carbonyl compounds	期刊论文	Ning Yongquan\|Mi Pengbing\|Liao Peiqiu\|Bi Xihe\|
32	Iron-Catalyzed [4C+1N] Cyclization of 4-Acetylenic Ketones with Primary Amines: Synthesis of 5-(Aryl)alkylidene-4,5-dihydropyrroles	期刊论文	Yeming Wang\|Yuegang Zhao\|Peiqiu Liao\|Xihe Bi\|
33	Regiospecific 6-endo-annulation of in situ generated 3,4-dienamides/acids: Synthesis of δ-lactams and δ-lactones	期刊论文	Yu Haifeng\|Liu Jianquan\|Liao Peiqiu\|Bi Xihe\|
34	Cu(ii)-catalyzed cyclization of α-diazo-β-oxoamides with amines leading to pyrrol-3(2H)-ones	期刊论文	Bi Xihe\|Liao Peiqiu\|Liu Xu\|Dong Dewen\|
35	General silver-catalyzed hydroazidation of terminal alkynes by combining TMS-N3 and H2O: Synthesis of vinyl azides	期刊论文	Liu Zhenhua\|Liao Peiqiu\|Bi Xihe\|
36	Recent developments of ketene dithioacetal chemistry	期刊论文	Pan Ling\|Bi Xihe\|Liu Qun\|
37	Cu(II)-catalyzed cyclization of a-diazo-b-oxoamides with amines leading to pyrrol-3(2H)-ones	期刊论文	Bi XH\|Liao PQ\|Liu X\|Dong DW\|
38	Recent developments of ketene dithioacetal chemistry	期刊论文	Pan L\|Bi XH\|Liu Q\|
39	Modular synthesis of sulfonyl benzoheteroles by silver-catalyzed heteroaromatization of propargylic alcohols with p -toluenesulfonylmethyl isocyanide (TosMIC): Dual roles of TosMIC	期刊论文	Jianquan Liu\|Zhenhua Liu\|Peiqiu Liao\|Xihe Bi\|
40	Silver-Catalyzed Cross-Coupling of Isocyanides and Active Methylene Compounds by a Radical Process	期刊论文	Peiqiu Liao\|Lin Zhang\|Tao Tu\|Xihe Bi\|
41	Catalytic r-activation of carbon–carbon triple bonds: reactions of propargylic alcohols and alkynes	期刊论文	Kumar Rapolu Kiran\|Bi Xihe\|
42	Silver-Catalyzed Isocyanide-Alkyne Cycloaddition: A General and Practical Method to Oligosubstituted Pyrroles	期刊论文	Fang ZX\|Zhang Q\|Liu Q\|Bi XH\|
43	Intramolecular hydrogen bonding-assisted cyclocondensation of α-diazoketones with various amines: A strategy for highly efficient Wolff 1,2,3-triazole synthesis	期刊论文	Liao Peiqiu\|Zhang Rui\|Liang Yongjiu\|Dong Dewen\|
44	An atom-economic route to thiophenes and 2,2′-bithiophenes by intramolecular transannulation of gem-dialkylthio enynes	期刊论文	Gou MY\|Liu Q\|Li XQ\|Bi XH\|
45	Copper-mediated chelation-assisted ortho nitration of (hetero)arenes	期刊论文	Barry BD\|Belay TA\|Bi XH\|Liu Q\|
46	Recent developments of ketene dithioacetal chemistry	期刊论文	Pan L\|Bi XH\|Liu Q\|
47	Formation of Benzo[f ]？1-indanone Frameworks by Regulable Intramolecular Annulations of gem-Dialkylthio Trienynes	期刊论文	Liu Ying\|Barry Badru-Deen\|Liao Peiqiu\|Bi Xihe\|
48	Metal-free hydroacyloxylation and hydration reactions of ynamides: synthesis of α-acyloxyenamides and N-acylsulfonamides	期刊论文	Shijie Xu\|Jianquan Liu\|Donghua Hu\|Xihe Bi\|
49	Modular synthesis of sulfonyl benzoheteroles by silver-catalyzed heteroaromatization of propargylic alcohols with p -toluenesulfonylmethyl isocyanide (TosMIC): Dual roles of TosMIC	期刊论文	Liu Jianquan\|Liu Zhenhua\|Liao Peiqiu\|Bi Xihe\|
50	Synthesis of 4？Ynamides and Cyclization by the Vilsmeier Reagent to Dihydrofuran-2(3H)？ones	期刊论文	Kumar Rapolu Kiran\|Li Guangzhi\|Wu Dongmei\|Bi Xihe\|
51	Direct C(sp 2)-H chlorination of ketene dithioacetals using FeCl 3 as the chloride source and PhI(OAc) 2 as an oxidant	期刊论文	Fang Zhongxue\|Barry Badru-Deen\|Liao Peiqiu\|Bi Xihe\|
52	Solvent-controlled, regio-switchable formation of 3-/5-arylaminopyrazole isomer in cyclocondensation of b-aminoenones with hydrazides: intermolecular hydrogen bonding plays a role	期刊论文	Fang GC\|Wang ZK\|Xin XQ\|Dong DW\|
53	Cu2O-Catalyzed Multicomponent Reaction of Alkyne, Sulfonyl Azide and Diimine for the Synthesis of N-sulfonylazetidin-2-imines Under Solvent-Free Conditions	期刊论文	Yi XH\|Barry BD\|Liao PQ\|Bi XH\|
54	Iron(III)-catalyzed dehydration C(sp2)-C(sp2) coupling of tertiary pro-pargyl alcohols and α-oxo ketene dithioacetals: A new route to gem -bis(alkylthio)-substituted vinylallenes	期刊论文	Liao Peiqiu\|Barry Badru-Deen\|Che Guangbo\|Bi Xihe\|
55	Cycloaddition of propargylic alcohols and α-oxo ketene dithioacetals: Synthesis of functionalized cyclopentadienes and further application in a diels-alder reaction	期刊论文	Fang Z.\|Liu J.\|Liu Q.\|Bi X.\|
56	Gem-Dialkylthio vinylallenes: Alkylthio-regulated reactivity and application in the divergent synthesis of pyrroles and thiophenes	期刊论文	Liu JQ\|Zhang JP\|Liu Q\|Bi XH\|
57	Silver-catalyzed isocyanide-alkyne cycloaddition: A general and practical method to oligosubstituted pyrroles	期刊论文	Fang Zhongxue\|Zhang Qian\|Liu Qun\|Bi Xihe\|
58	Silver-catalyzed cyclization of 2-pyridyl alkynyl carbinols with isocyanides: Divergent synthesis of indolizines and pyrroles	期刊论文	Meng X.\|Liao P.\|Liu J.\|Bi X.\|
59	Catalytic C-H α-trifluoromethylation of α,β-unsaturated carbonyl compounds	期刊论文	Ning YQ\|Mi PB\|Liao PQ\|Bi XH\|

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