廉价金属催化的醇和不饱和烃的自身氢转移不对称碳碳成键反应研究

21871288
2018
B0106.不对称合成
施世良
面上项目
研究员
中国科学院上海有机化学研究所
66万元
不对称合成;不对称碳碳键形成;手性配体;不对称金属催化;不对称碳氢键活化
2019-01-01到2022-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Thieme Chemistry Journals Award 奖励 Shi-Liang Shi
2 Regio- and Trans-Selective Ni-Catalyzed Coupling of Butadiene, Carbonyls, and Arylboronic Acids to Homoallylic Alcohols under Base-Free Conditions 期刊论文 Yu-Qing Li;Guang Chen;Shi-Liang Shi
3 Pd‐Catalyzed Cross‐Coupling of Alkylzirconocenes and Aryl Chlorides 期刊论文 Binyang Jiang;Shi-Liang Shi
4 Recent Progress in Upgrading of Alcohol and Amine via Asymmetric Dehydrogenative Coupling 期刊论文 Jiang Binyang;Shi Shi-Liang
5 Nickel/NHC-Catalyzed Asymmetric C-H Alkylation of Fluoroarenes with Alkenes: Synthesis of Enantioenriched Fluorotetralins. 期刊论文 Yuan Cai;Xiaodong Ye;Sheng Liu;Shi-Liang Shi
6 Base-Promoted Rapid Hydrosilylation of Aldimine 期刊论文 Zi-Chao Wang;Youjun Xu;Shi-Liang Shi
7 Nickel-Catalyzed Multicomponent Coupling of Butadiene, Al- dehydes, Alkynes, and Schwartz Reagent to Form 1,4-dienes 期刊论文 Yu-Qing Li;Shi-Liang Shi
8 Chemo- and Enantioselective Arylation and Alkenylation of Aldehydes Enabled by Nickel/N-Heterocyclic Carbene Catalysis 期刊论文 Zi-Chao Wang;Jian Gao;Yuan Cai;Xiaodong Ye;Shi-Liang Shi
9 Regio- and Enantioselective C-H Cyclization of Pyridines with Alkenes Enabled by a Nickel/N-Heterocyclic Carbene Catalysis. 期刊论文 Wu-Bin Zhang;Xin-Tuo Yang;Jun-Bao Ma;Zhi-Ming Su;Shi-Liang Shi
10 Enantioselective Ni/N-Heterocyclic Carbene-Catalyzed Redox- Economical Coupling of Aldehydes, Alkynes, and Enones for Rapid Construction of Acyclic All-Carbon Quaternary Stereocenters 期刊论文 Wu-Bin Zhang;Guang Chen;Shi-Liang Shi
11 钯复合物、其制备方法、轴手性联芳香化合物的制备方法 专利 施世良;申迪
12 手性1,3-二芳基咪唑盐卡宾前体、其合成方法、金属盐复合物和应用 专利 施世良;蔡援;杨新拓;李峰
13 Nickel/NHC-Catalyzed Enantioselective Cyclization of Pyridones and Pyrimidones with Tethered Alkenes 期刊论文 Di Shen;Wu-Bin Zhang;Zhiyang Li;Shi-Liang Shi;Youjun Xu
14 Enantio- and Regioselective Ni-Catalyzed para-C–H Alkylation of Pyridines with Styrenes via Intermolecular Hydroarylation 期刊论文 Jun-Bao Ma;Xia Zhao;Chengbu Liu;Shi-Liang Shi
15 Expedient Synthesis of Ketones via N-Heterocyclic Carbene/Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes 期刊论文 Li Yuqing;Li Feng;Shi Shiliang
16 Aluminum-Catalyzed Selective Hydroboration of Alkenes and Alkynylsilanes 期刊论文 Li Feng Bai Xu Cai Yuan Li Han Zhang Shuo-Qing Liu Feng-Hua Hong Xin Xu Youjun;Shi Shi-Liang
17 Bayer Investigate Award 奖励 Shi-Liang Shi
18 Ni-Catalyzed Coupling of Butadiene, Aldimines, and Arylboronic Acids to Homoallylic Amines under Base-Free Conditions 期刊论文 Li Yu-Qing;Shi Shi-Liang
19 nBuLi-promoted anti-Markovnikov selective hydroboration of unactivated alkenes and internal alkynes 期刊论文 Zi-Chao Wang;Min Wang;Jian Gao;Shi-Liang Shi;Youjun Xu
20 Nickel-Catalyzed Ligand-Free Hiyama Coupling of Aryl Bromides and Vinyltrimethoxysilane 期刊论文 Shichao Wei;Yongjun Mao;Shi-Liang Shi
21 Enantioconvergent Arylation of Racemic Secondary Alcohols to Chiral Tertiary Alcohols Enabled by Nickel/N-Heterocyclic Carbene Catalysis 期刊论文 Yuan Cai;Shi-Liang Shi
22 Ni-Catalyzed Three-Component Coupling Reaction of Butadiene, Aldimines and Alkenylboronic Acids 期刊论文 Zhang Yurong;Wang Han;Mao Yongjun;Shi Shiliang
23 一种咪唑盐、其制备方法、其应用及含氟聚合物的制备方法 专利 施世良;马俊宝
24 Base-catalysed reductive relay hydroboration of allylic alcohols with pinacolborane to form alkylboronic esters. 期刊论文 Wang Zi-Chao;Shen Di;Gao Jian;Jia Xian;Xu Youjun;Shi Shi-Liang
25 A Bulky Chiral N-Heterocyclic Carbene Palladium Catalyst Enables Highly Enantioselective Suzuki-Miyaura Cross-Coupling Reactions for the Synthesis of Biaryl Atropisomers. 期刊论文 Di Shen;Youjun Xu;Shi-Liang Shi
26 Nickel/N-Heterocyclic Carbene Complex-Catalyzed Enantioselective Redox-Neutral Coupling of Benzyl Alcohols and Alkynes to Allylic Alcohols 期刊论文 Yuan Cai;Jia-Wen Zhang;Feng Li;Jia-Ming Liu;Shi-Liang Shi
27 Ligand- and Additive-Free CuCl 2 -Catalyzed para-C-H Alkylation of Aniline Derivatives via Carbene Insertion 期刊论文 Lei Gao;Sheng Liu;Zi-Chao Wang;Yongjun Mao;Shi-Liang Shi
28 Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings 期刊论文 Chen-Fei Liu;Zi-Chao Wang;Xiaohua Luo;Jiawei Lu;Charyl Hui Min Ko;Shi-Liang Shi;Ming Joo Koh
29 Fast Enantio- and Chemoselective Arylation of Ketones with Organoboronic Esters Enabled by Nickel/N-Heterocyclic Carbene Catalysis 期刊论文 Yuan Cai;Lin-Xin Ruan;Abdul Rahman;Shi-Liang Shi
30 Dynamic kinetic asymmetric arylation and alkenylation of ketones 期刊论文 Lin-Xin Ruan;Bo Sun;Jia-Ming Liu;Shi-Liang Shi
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