“负氟效应”规律指导下利用金属调控的氟烷基化反应研究

21372246
2013
B0101.元素化学
胡金波
面上项目
研究员
中国科学院上海有机化学研究所
90万元
金属调控;氟化学;有机合成;氟烷基化;氟效应
2014-01-01到2017-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Silver-Mediated Trifluoromethylthiolation-Iodination of Arynes 期刊论文 Zeng Yuwen;Hu Jinbo
2 Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone 期刊论文 Li Xinjin;Zhao Jingwei;Hu Mingyou;Chen Dingben;Ni Chuanfa;Wang Limin;Hu Jinbo
3 Iron-Catalyzed Difluoromethylation of Arylzincs with Difluoromethyl 2-Pyridyl Sulfone 期刊论文 Miao Wenjun;Zhao Yanchuan;Ni Chuanfa;Gao Bing;Zhang Wei;Hu JInbo
4 Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes 期刊论文 Zeng Yuwen;Li Guangyu;Hu Jinbo
5 Radical (2-pyridylsulfonyl)difluoromethylation of terminal alkenes with iododifluoromethyl 2-pyridyl sulfone 期刊论文 Miao Wenjun;Ni Chuanfa;Zhao Yanchuan;Hu Jinbo
6 Fluorinated Sulfoximines: Preparation, Reactions and Applications 期刊论文 Shen Xiao;Hu Jinbo
7 Bridging Fluorine and Aryne Chemistry: Vicinal Difunctionalization of Arynes Involving Nucleophilic Fluorination, Trifluoromethylation, or Trifluoromethylthiolation 期刊论文 Zeng Yuwen;Hu Jinbo
8 gem-Difluoroolefination of Diazo Compounds with TMSCF3 or TMSCF2Br: Transition-Metal-Free Cross-Coupling of Two Carbene Precursors 期刊论文 Hu Mingyou;Ni Chuanfa;Li Lingchun;Han Yongxin;Hu Jinbo
9 Stereoselective Nucleophilic Fluoromethylation of Aryl Ketones: Dynamic Kinetic Resolution of Chiral alpha-Fluoro Carbanions 期刊论文 Shen Xiao;Miao Wenjun;Ni Chuanfa;Hu Jinbo
10 Nucleophilic Difluoromethylation of Epoxides with PhSO(NTBS)CF2H by a Preorganization Strategy 期刊论文 Shen Xiao;Liu Qinghe;Luo Tao;Hu Jinbo
11 Stereoselective Carbonyl Olefination with Fluorosulfoximines: Facile Access to Z or E Terminal Monofluoroalkenes 期刊论文 Liu Qinghe;Shen Xiao;Ni Chuanfa;Hu Jinbo
12 O-Trifluoromethylation of Phenols: Access to Aryl Trifluoromethyl Ethers by O-Carboxydifluoromethylation and Decarboxylative Fluorination 期刊论文 Zhou Min;Ni Chuanfa;He Zhengbiao;Hu Jinbo
13 China's flourishing synthetic organofluorine chemistry: innovations in the new millennium 期刊论文 Liu Qinghe;Ni Chuanfa;Hu Jinbo
14 Copper-Catalyzed Trifluoromethylation of Polysubstituted Alkenes Assisted by Decarboxylation 期刊论文 He Zhengbiao;Tan Ping;Hu Jinbo
15 Difluoromethyl 2-pyridyl sulfone: a versatile carbonyl gem-difluoroolefination reagent 期刊论文 Gao Bing;Zhao Yanchuan;Hu Jingyu;Hu Jinbo
16 Stereoselective Synthesis of (Sulfonimidoyl)cyclopropanes with (R)-PhSO(NTs)CH2Cl and ,-Unsaturated Weinreb Amides: Tuning the of Selectivity between C-Cl and C-S Bond Cleavage 期刊论文 Shen Xiao;Liu Qinghe;Zhang Wei;Hu Jinbo
17 Deoxyfluorination of alcohols with 3,3-difluoro-1,2-diarylcyclopropenes 期刊论文 Li Lingchun;Ni Chuanfa;Wang Fei;Hu Jinbo
18 Chemically oxidative fluorination with fluoride ions 期刊论文 Ni Chuanfa;Jiang Fanzhou;Zeng Yuwen;Hu Jinbo
19 Copper-Catalyzed gem-Difluoroolefination of Diazo Compounds with TMSCF3 via C-F Bond Cleavage 期刊论文 Hu Mingyou;He Zhengbiao;Gao Bing;Li Lingchun;Ni Chuanfa;Hu Jinbo
20 Nucleophilic Iododifluoromethylation of Carbonyl Compounds Using Difluoromethyl 2-Pyridyl Sulfone 期刊论文 Miao Wenjun;Ni Chuanfa;Zhao Yanchuan;Hu Jinbo
21 Palladium-Catalyzed Monofluoromethylation of Arylboronic Esters with Fluoromethyl Iodide 期刊论文 Hu Jingyu;Gao Bing;Li Lingchun;Ni Chuanfa;Hu Jinbo
22 Recent Advances in the Synthetic Application of Difluorocarbene 期刊论文 Ni Chuanfa;Hu Jinbo
23 Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis 期刊论文 Ni Chuanfa;Hu Mingyou;Hu Jinbo
24 gem-Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2-Pyridyl Sulfone: New Insights into the Julia-Kocienski Reaction 期刊论文 Gao Bing;Zhao Yanchuan;Hu Mingyou;Ni Chuanfa;Hu Jinbo
25 AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes 期刊论文 Gao Bing;Zhao Yanchuan;Ni Chuanfa;Hu Jinbo
26 Efficient nucleophilic difluoromethylation of aldehydes with (phenylsulfonyl)difluoromethylzinc and (phenylsulfonyl) difluoromethylcadmium reagents 期刊论文 Jiang Fanzhou;Ni Chuanfa;Hu Jinbo
27 Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes 期刊论文 Shen Xiao;Liu Qinghe;Ni Chuanfa;Hu Jinbo
28 Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds 期刊论文 Zeng Yuwen;Hu Jinbo
29 Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me3SiCF2H 期刊论文 Chen Dingben;Ni Chuanfa;Zhao Yanchuan;Cai Xian;Li Xinjin;Xiao Pan;Hu Jinbo
30 Radical (Phenylsulfonyl)difluoromethylation of Isocyanides with PhSO2CF2H under Transition-Metal-Free Conditions 期刊论文 Xiao Pan;Rong Jian;Ni Chuanfa;Guo Junkai;Li Xinjin;Chen Dingben;Hu Jinbo
31 Selective Monofluorination of Active Methylene Compounds: The Important Role of ZnCl2 in Inhibiting Overfluorination 期刊论文 Jiang Fanzhou;Zhao Yanchuang;Hu JInbo
32 Copper-Mediated Deuterotrifluoromethylation of alpha-Diazo Esters 期刊论文 Hu Mingyou;Xie Qiqiang;Li Xinjin;Ni Chuanfa;Hu Jinbo
33 Metal-Catalyzed Direct Difluoromethylation Reactions 期刊论文 Rong Jian;Ni Chuanfa;Hu Jinbo
34 Radical Fluoroalkylation of Aryl Alkenes with Fluorinated Sulfones by Visible- Light Photoredox Catalysis 期刊论文 Rong Jian;Ni Chuanfa;Wang Yunze;Kuang Cuiwen;Gu Yucheng;Hu Jinbo
35 Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide 期刊论文 Li Xinjin;Zhao Jingwei;Zhang Liang;Hu Mingyou;Wang Limin;Hu Jinbo
36 Fluoroalkylative Aryl Migration of Conjugated N-Arylsulfonylated Amides Using Easily Accessible Sodium Di- and Monofluoroalkanesulfinates 期刊论文 He Zhengbiao;Tan Ping;Ni Chuanfa;Hu Jinbo
37 Carbonyl olefination of diaryl ketones with heteroaryl sulfoxides 期刊论文 Gao Bing;Hu Jingyu;Zhao Yanchuan;Hu Jinbo
38 Decarboxylative Fluorination of β-Ketoacids with N-Fluorobenzenesulfonimide (NFSI) for the Synthesis of α-Fluoroketones: Substrate Scope and Mechanistic Investigation 期刊论文 Zhang Rui;Ni Chuanfa;He Zhengbiao;Hu JInbo
39 Efficient Difluoromethylation of Alcohols Using TMSCF2Br as a Unique and Practical Difluorocarbene Reagent under Mild Conditions 期刊论文 Xie Qiqiang;Ni Chuanfa;Zhang Rongyi;Li Lingchun;Rong Jian;Hu Jinbo
40 Recent Advances in Green Fluorine Chemistry 期刊论文 Zeng Yuwen;Hu Jinbo
41 Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis 期刊论文 Rong Jian;Deng Ling;Tan Ping;Ni Chuanfa;Gu Yucheng;Hu Jinbo
42 Stereoselective [3+2] cycloaddition of N-tert-butanesulfinyl imines to arynes facilitated by a removable PhSO2CF2 group: synthesis and transformation of cyclic sulfoximines 期刊论文 Ye Wenchao;Zhang Laijun;Ni Chuanfa;Rong Jian;Hu Jinbo
43 Selective Incorporation of Difluoromethylene Moieties into Arenes Assisted by Transition Metals 期刊论文 Gao Bing;Ni Chuanfa;Hu Jinbo
44 Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E-Monofluoroalkenes 期刊论文 Zhao Yanchuan;Jiang Fanzhou;Hu Jinbo
45 Recent Advances in the One-Step Synthesis of Distally Fluorinated Ketones 期刊论文 Zeng Yuwen;Ni Chuanfa;Hu Jinbo
46 Advances in Transition-Metal-Mediated Di- and Monofluoroalkylations 期刊论文 Ni Chuanfa;Zhu Lingui;Hu Jinbo
47 Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF2CH3) 期刊论文 Li Xinjin;Zhao Jingwei;Wang Yunze;Rong Jian;Hu Mingyou;Chen Dingben;Xiao Pan;Ni Chuanfa;Wang Limin;Hu Jinbo
48 Copper-Mediated Trifluoromethylthiolation of alpha-Diazoesters 期刊论文 Hu Mingyou;Rong Jian;Miao Wenjun;Ni Chuanfa;Han Yongxin;Hu Jinbo
49 AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to alpha-CF3 Alkenes and beta-CF3 Ketones 期刊论文 Gao Bing;Zhao Yanchuan;Hu Jinbo
50 Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species 期刊论文 Zhu Jieming;Ni Chuanfa;Gao Bing;Hu Jinbo
51 The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations 期刊论文 Ni Chuanfa;Hu Jinbo
52 TMSCF3 as a Convenient Source of CF2=CF2 for Pentafluoroethylation, (Aryloxy)tetrafluoroethylation, and Tetrafluoroethylation 期刊论文 Li Lingchun;Ni Chuanfa;Xie Qiqiang;Hu Mingyou;Wang Fei;Hu Jinbo
53 Divergent Rearrangements of Cyclopropyl-Substituted Fluoroepoxides Involving C-F Bond Cleavage and Formation 期刊论文 Luo Tao;Zhang Rui;Zhang Wei;Shen Xiao;Umemoto Teruo;Hu Jinbo
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