【21072215】质谱学方法研究有机化学反应中的瞬态自由基国家自然基金项目

质谱学方法研究有机化学反应中的瞬态自由基

项目批准号： 21072215

批准年份： 2010

学科分类： B0406.生命与公共安全分析

项目负责人：郭寅龙

资助类别：面上项目

负责人职称：研究员

依托单位：中国科学院上海有机化学研究所

资助金额： 36万元

关键词：自由基检测与表征;质谱学;反应机理研究

起止时间： 2011-01-01到2013-12-31

中英文摘要
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序号	标题	类型	作者
1	Study on reactions of long-lived phenoxathiin radical cation with aliphatic alcohols, phenol and phenyl halides in ambient condition by fused-droplet electrospray ionization mass spectrometry	期刊论文	Yao, Sheng-Jun\|Wang, Hao-Yang\|Zhang, Li\|Zhang, Jing\|Guo, Yin-Long\|
2	Gas Phase Decarbonylation and Cyclization Reactions of Protonated N-Methyl-N-Phenylmethacrylamide and Its Derivatives Via an Amide Claisen Rearrangement	期刊论文	Wang, Hao-Yang\|Xu, Chu\|Zhu, Wei\|Liu, Guo-Sheng\|Guo, Yin-Long\|
3	Comparison of Hair Fatty Alcohols by N-Alkylpyridinium Isotope Quaternization and Matrix-assisted Laser Desorption/ionization Mass Spectrometry for Drug Abuse Monitoring	期刊论文	Wang Hang\|Wang Haoyang\|Zhang Li\|Zhang Jing\|Zhuo Xianyi\|Huang Yi\|Guo Yinlong\|
4	Mechanistic investigations of a palladium-diene catalyzed Suzuki-Miyaura cross-coupling reaction	期刊论文	He, Xiaoshuang\|Zhang, Shusheng\|Guo, Yinlong\|Wang, Haoyang\|Lin, Guoqiang\|
5	Study on the reactive transient a-?3-iodanyl-acetophenone complex in the iodine(III)/PhI(I) catalytic cycle of iodobenzene-catalyzed a-acetoxylation reaction of acetophenone by electrospray ionization tandem mass spectrometry	期刊论文	Wang, Hao-Yang\|Zhou, Juan\|Guo, Yin-Long\|
6	Studies on CH(3)CN-assisted decomposition of 1(st) Grubbs catalyst by electrospray ionization tandem mass spectrometry	期刊论文	Zhao, Zhi-Xiong\|Wang, Hao-Yang\|Guo, Yin-Long\|
7	用于质谱的稳定同位素化学标记技术	期刊论文	张菁\|张立\|王昊阳\|郭寅龙\|
8	Investigation of coordination of Mg(II) cations to 2-pyrimidinyloxy-N-arylbenzylamines by electrosp ray mass spectrometry: insights for Mg(II) catalyzed Smiles rearrangement reactions	期刊论文	Wang, Haoyang\|Xu, Chu\|Zhang, Li\|Tang, Qinghong\|Guo, Yinlong\|Lu, Long\|
9	Mass Spectrometric Study of the Gas-Phase Difluorocarbene Expulsion of Polyfluorophenyl Cations via F-Atom Migration	期刊论文	Wang, Hao-Yang\|Gao, Ying\|Zhang, Fang\|Yu, Chong-Tian\|Xu, Chu\|Guo, Yin-Long\|
10	Studies of Heterogeneous/Homogeneous Ion-Molecule Reactions by Ambient Ionization Mass Spectrometry	期刊论文	Zhao, Zhi-Xiong\|Wang, Hao-Yang\|Guo, Yin-Long\|
11	气相色谱-四极杆飞行时间串联质谱在加拿大一枝黄花挥发性成分检测中的应用	期刊论文	范若静\|张芳\|郭寅龙\|
12	Study of the Gas-Phase Intramolecular Aryltrifluoromethylation of Phenyl(Trifluoromethyl)Iodonium by ESI-MS/MS	期刊论文	Wang, Hao-Yang\|Xiang, Zhang\|Liu, Guo-Sheng\|Guo, Yin-Long\|
13	Integration of High Accuracy N-Terminus Identification in Peptide Sequencing and Comparative Protein Analysis Via Isothiocyanate-Based Isotope Labeling Reagent with ESI Ion-trap TOF MS	期刊论文	Leng, Jiapeng\|Wang, Haoyang\|Zhang, Li\|Zhang, Jing\|Wang, Hang\|Cai, Tingting\|Yao, Jinting\|Guo, Yinlong\|
14	Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry analyses of Grubbs catalysts and ferrocene derivatives using sulfur as matrix	期刊论文	Zhu, Wei\|Wang, Hao-Yang\|Guo, Yin-Long\|
15	Analysis of low molecular weight compounds by MALDI-FTICR-MS	期刊论文	Wang, Hao-Yang\|Chu, Xu\|Zhao, Zhi-Xiong\|He, Xiao-Shuang\|Guo, Yin-Long\|
16	Rapid simultaneous screening and identification of multiple pesticide residues in vegetables	期刊论文	Zhang, Fang\|Yu, Chongtian\|Wang, Wenwen\|Fan, Ruojing\|Zhang, Zhixu\|Guo, Yinlong\|
17	Analysis of Volatile Compounds in Radix Bupleuri Injection by GC-MS-MS	期刊论文	Liu, Suhong\|Lu, Sensen\|Su, Yue\|Guo, Yinlong\|
18	Study of the Transient Reactive Pd(IV) Intermediate in the Pd(OAc)2-Catalyzed Oxidative Coupling Reaction System by Electrospray Ionization Tandem Mass Spectrometry	期刊论文	Zhu, Wei\|Wang, Haoyang\|Peng, Haihui\|Liu, Guosheng\|Guo, Yinlong\|
19	Analysis of the differentially expressed low molecular weight peptides in human serum via an N-terminal isotope labeling technique combining nano-liquid chromatography/matrix-assisted laser desorption/ionization mass spectrometry	期刊论文	Leng, Jiapeng\|Zhu, Dong\|Wu, Duojiao\|Zhu, Tongyu\|Zhao, Ningwei\|Guo, Yinlong\|
20	ESI-MS studies and calculations on second-generation Grubbs and Hoveyda-Grubbs ruthenium olefin metathesis catalysts	期刊论文	Wang, Hao-Yang\|Yim, Wai-Leung\|Guo, Yin-Long\|Metzger, Jürgen O.\|
21	Determination of hazardous volatile organic compounds in the Hoffmann list by ion-molecule reaction mass spectrometry	期刊论文	Wang, Haoyang\|Xie, Wenyan\|Chen, Min\|Liu, Baizhan\|Guo, Yinlong\|
22	A highly sensitive isotope-coded derivatization method and its application for the mass spectrometric analysis of analytes containing the carboxyl group	期刊论文	Leng, Jiapeng\|Wang, Haoyang\|Zhang, Li\|Zhang, Jing\|Wang, Hang\|Guo, Yinlong\|
23	单液滴萃取衍生化技术用于烟气中小分子醛类物质的分析	期刊论文	朱逢君\|张菁\|郑赛晶\|刘百战\|郭寅龙\|
24	Studies of gas-phase reactions of cationic iron complexes of 2-pyrimidinyloxy-N-arylbenzylamines by electrospray ionization tandem mass spectrometry	期刊论文	Xu, Chu\|Wang, Hao-Yang\|Zhu, Feng-Jun\|Guo, Yin-Long\|Lu, Long\|
25	Gas Chromatographic-Ion Trap Mass Spectrometric Analysis of Volatile Organic Compounds by Ion-Molecule Reactions Using the Electron-Deficient Reagent Ion CCl (3) (+)	期刊论文	Wang, Cheng-Zhong\|Su, Yue\|Wang, Hao-Yang\|Guo, Yin-Long\|
26	Analysis of the volatile compounds in Senecio scandens Buch-Ham by gas chromatography-tandem mass spectrometry based on diversified scan technologies	期刊论文	Lu, Sensen\|Su, Yue\|Guo, Yinlong\|
27	Improvement and extension of the application scope for matrix-assisted laser desorption/ionization mass spectrometric analysis-oriented N-alkylpyridinium isotope quaternization	期刊论文	Wang, Hang\|Wang, Haoyang\|Zhang, Li\|Zhang, Jing\|Leng, Jiapeng\|Cai, Tingting\|Guo, Yinlong\|
28	Application of isotope-based carboxy group derivatization in LC-MS/MS analysis of tissue free-fatty acids for thyroid carcinoma	期刊论文	Leng, Jiapeng\|Guan, Qing\|Sun, Tuanqi\|Wu, Yi\|Cao, Yanjing\|Guo, Yinlong\|
29	Facile and fast enrichment of phosphopeptides prior to matrix-assisted laser desorption/ionization time-of-flight mass spectrometric analysis using natural nanoparticle-bentonite	期刊论文	Zhu, Li\|Zhang, Jing\|Ren, Shifang\|Guo, Yinlong\|
30	ESI-MS study on transient intermediates in the fast cyclopropenium-activated chlorination reaction of alcohols	期刊论文	Zhao, Zhi-Xiong\|Wang, Hao-Yang\|Guo, Yin-Long\|
31	N-Alkylpyridinium quaternization for assisting electrospray ionization of sterols in oil by Quadrupole-Time of Flight mass spectrometry	期刊论文	Wang, Hang\|Wang, Haoyang\|Zhang, Li\|Zhang, Jing\|Leng, Jiapeng\|Cai, Tingting\|Guo, Yinlong\|
32	Studies on CH(3)CN-assisted decomposition of 1(st) Grubbs catalyst by electrospray ionization tandem mass spectrometry	期刊论文	Zhao, Zhi-Xiong\|Wang, Hao-Yang\|Guo, Yin-Long\|

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