【21272077】共轭氮宾/金属及其与不饱和键的【3+2】环加成反应国家自然基金项目

共轭氮宾/金属及其与不饱和键的【3+2】环加成反应

项目批准号： 21272077

批准年份： 2012

学科分类： B0113.结构与反应机制

项目负责人：徐华栋

资助类别：面上项目

负责人职称：研究员

依托单位：常州大学

资助金额： 80万元

关键词：金属氮宾;3-偶极;1;氮宾;【3+2】环加成;金属催化

起止时间： 2013-01-01到2016-12-31

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序号	标题	类型	作者
1	Stereoselective Construction of Bridged trans-aza-Bicyclo[7/6,3/2,1]alkenyl Imines through Ring Expansion aza-Cope Rearrangement.	期刊论文	Shen, Mei-Hua\|Xu, Ke\|Sun, Chu-Han\|Xu, Hua-Dong\|
2	Substituent Enabled Divergent Synthesis of N-Heterocycles: a Metal Carbene Approach Involving Intramolecular Carbene Interception	期刊论文	Wu, Hao\|Ding, Yun\|Shen, Mei-Hua\|Pan, Xian-Hua\|
3	The Reaction of 2,3-Dimethylimidazole-1-sulfonyl Azide Triflate with 3-Substituted Indoles: Reactivity and Scope.	期刊论文	Shen, Mei-Hua\|Xu, Ke\|Sun, Chu-Han\|Xu, Hua-Dong\|
4	Ring-Strain-Driven Catalytic Carbene Formation-Cyclopropanation-Aza-Cope Rearrangement Cascade: A Facile Entry to Fused Dihydroazepines from 1,3-Dienyltriazoles	期刊论文	Jia, Zhi-Hong\|Wu, Hao\|Lu, Xiao-Long\|Shen, Meihua\|
5	Step-economy etherification of acylated alcohols	期刊论文	Xu, Ke\|Zheng, Qing\|He, Wei-Jie\|Shen, Mei-Hua\|
6	Chemo-, regio-, and stereoselective hydroboration of conjugated enyne alcohol/amine: facile synthesis of Z,Z-/Z,E-1,3-dien-1/2-ylboronic ester bearing hydroxyl/amino group	期刊论文	Wu Hao\|Jiang Chun\|Chen Peng\|Shen Mei-Hua\|
7	One-Pot Conversion of N？Allyl-α-cyano Esters to α？Allyl-α-cyanoLactams through a Hydrolysis/Ketene Formation/Cyclization/Claisen RearrangementSequence.	期刊论文	Shen, Mei-Hua\|Han, Mei\|Xu, Hua-Dong\|
8	Straightforward regioselective construction of 3,4-dihydro-2H-1,4-thiazine by rhodium catalysed [3 + 3] cycloaddition of thiirane with 1-sulfonyl-1,2,3-triazole: a pronounced acid additive effect	期刊论文	Liu Ya-Ting\|Wang Qing-Xia\|Shen Mei-Hua\|Xu Hua-Dong\|
9	Stereoselective Synthesis of Polycycles Containing an Aziridine Group: Intramolecular aza-Diels-Alder Reactions of Unactivated 2H-Azirines with Unactivated Dienes.	期刊论文	Wu, Hao\|Han, Mei\|Han, Run-Ze\|Shen, Mei-Hua\|
10	Stereoselective Halocyclization of Alkenes With N-Acyl Hemiaminal Nucleophiles	期刊论文	Jia, Zhi-Hong\|Guzei, Ilia A.\|Xu, Hua-Dong\|Tang, Weiping\|
11	Evolution of the Aza-Diels–Alder Reaction of 2H-Azirines	期刊论文	Zhou Hao\|Shen Mei-Hua\|Xu Hua-Dong\|
12	A one-pot construction of acridones by rhodium catalyzed reaction of N-phenyl-2-(1-sulfonyl-1H-1,2,3-triazol-4-yl)aniline	期刊论文	Pan, Ying-Peng\|Ren, Xin-Tao\|Zhang, Ping\|Shen, Mei-Hua\|
13	An efficient approach to 1,2,3-trisubstituted indole via rhodium catalyzed carbene C(sp(3))-H bond insertion.	期刊论文	Jia, Zhi-Hong\|Ren, Xin-Tao\|Zhang, Ping\|Xu, Hua-Dong\|
14	Rhodium-Catalyzed Chemo- and Regioselective Cross-Dimerization of Two Terminal Alkynes	期刊论文	Li, Xiaoxun\|Huang, Suyu\|Tang, Weiping\|Hu, Wen-Hao\|
15	Copper-Catalyzed Cyclization/aza-Claisen Rearrangement Cascade Initiated by Ketenimine Formation: An Efficient Stereocontrolled Synthesis of α-Allyl Cyclic Amidines	期刊论文	Jiang, Sai-Nan\|Cao, Jing\|Wang, Jia-Cheng\|Shen Mei-Hua\|
16	Interception of benzyne with thioethers: a facile access to sulfur ylides under mild conditions	期刊论文	Cai, Mao-Qiang\|He, Wei-Jie\|Hu, Wen-Hao\|Shen, Mei-Hua\|
17	One-Pot Protocol to Functionalized Benzopyrrolizidine Catalyzed Successively by Rh2(OAc)4 and Cu(OTf)2: A Transition Metal–Lewis Acid Catalysis Relay	期刊论文	Jia, Zhi-Hong\|Xu, Ke\|Zhou, Hao\|Shen, Mei-Hua\|
18	Facile synthesis of aza-spirocyclopropanyl oxindoles by the reaction of 3-(2-bromoethyl)-indole with 2,3-dimethylimidazole-1-sulfonyl azide triflate.	期刊论文	Shen, Mei-Hua\|Xu, Ke\|Sun, Chu-Han\|Xu, Hua-Dong\|
19	Copper( II ) acetate catalysed ring-opening cross-coupling of cyclopropanols with sulfonyl azides	期刊论文	Shen Mei-Hua\|Lu Xiao-Long\|Xu Hua-Dong\|
20	Expedient catalytic construction of azabicyclo[4.1.0]/[5.1.0] carbaldehydes via intramolecular cyclopropanation	期刊论文	Cao, Jing\|Chen, Chang\|Shen, Mei-Hua\|Xu, Hua-Dong\|

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