氮杂卡宾催化的单电子转移自由基反应活化模式研究

21772029
2017
B0106.不对称合成
池永贵
面上项目
教授
贵州大学
66万元
功能分子;单电子转移;新活化模式;不对称催化合成;自由基反应
2018-01-01到2021-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Carbene-catalyzed activation of cyclopropylcarbaldehydes for mannich reaction and δ-lactam formation: remote enantioselecitvity control and dynamic kinetic asymmetric transformation 期刊论文 Jie Lv;Jun Xu;Xuling Pan;Zhichao Jin;Yonggui Robin Chi
2 NHC-Catalyzed Cascade Reaction between beta-Methyl Enals and Dienones for Quick Construction of Complex Multicyclic Lactones 期刊论文 Sun Jun;Xu Jun;Nie Guihua;Jin Zhichao;Chi Yonggui Robin
3 Chiral Nitroarenes as Enantioselective Single-Electron-Transfer Oxidants for Carbene-Catalyzed Radical Reactions 期刊论文 Wang Hongling;Wang Yuhuang;Chen Xingkuan;Mou Chengli;Yu Shuyan;Chai Huifang;Jin Zhichao;Chi Yonggui Robin
4 Gold and Carbene Relay Catalytic Enantioselective Cycloisomerization/Cyclization Reactions of Ynamides and Enals 期刊论文 Liejin Zhou;Xingxing Wu;Xing Yang;Chengli Mou;Runjiang Song;Shuyan Yu;Huifang Chai;Lutai Pan;Zhichao Jin;Yonggui Robin Chi
5 Kinetic Resolution of 1,2-Diols via NHC-Catalyzed Site-Selective Esterification 期刊论文 Liu Bin;Yan Jiekuan;Huang Ruoyan;Wang Weihong;Jin Zhichao;Zanoni Giuseppe;Zheng Pengcheng;Yang Song;Chi Yonggui Robin
6 Access to Optically Enriched alpha-Aryloxycarboxylic Esters via Carbene-Catalyzed Dynamic Kinetic Resolution and Transesterification 期刊论文 Liu Bin;Song Runjiang;Xu Jun;Majhi Pankaj Kumar;Yang Xing;Yang Song;Jin Zhichao;Chi Yonggui Robin
7 Catalytic asymmetric acetalization of carboxylic acids for access to chiral phthalidyl ester prodrugs 期刊论文 Liu Yingguo;Chen Qiao;Mou Chengli;Pan Lutai;Duan Xiaoyong;Chen Xingkuan;Chen Hongzhong;Zhao Yanli;Lu Yunpeng;Jin Zhichao;Chi Yonggui Robin
8 Access to All-Carbon Spirocycles through a Carbene and Thiourea Cocatalytic Desymmetrization Cascade Reaction 期刊论文 Zhuo Shitian;Zhu Tingshun;Zhou Liejin;Mou Chengli;Chai Huifang;Lu Yunpeng;Pan Lutai;Jin Zhichao;Chi Yonggui Robin
9 Carbene- catalyzed enal c- carbon addition to a- ketophosphonates for enantioselective access to bioactive 2-pyranylphosphonates 期刊论文 Sun Jun;He Fangcheng;Wang Zhongyao;Pan Dingwu;Zheng Pengcheng;Mou Chengli;Jin Zhichao;Chi Yonggui Robin
10 Sulfinate and Carbene Co-catalyzed Rauhut–Currier Reaction for Enantioselective Access to Azepino[1,2-a]indoles 期刊论文 Xingxing Wu;Liejin Zhou;Rakesh Maiti;Chengli Mou;Lutai Pan;Yonggui Robin Chi
11 Carbene-Catalyzed [4+2] Cycloadditions of Vinyl Enolate and (in Situ Generated) Imines for Enantioselective Synthesis of Quaternary alpha-Amino Phosphonates 期刊论文 Sun Jun;Mou Chengli;Wang Zhongyao;He Fangcheng;Wu Jian;Chi Yonggui Robin
12 N-Heterocyclic Carbene Catalyzed Radical Coupling of Aldehydes with Redox-Active Esters 期刊论文 Song Runjiang;Chi Yonggui Robin
13 Carbene-Catalyzed Enantioselective Aldol Reaction: Post-Aldol Stereochemistry Control and Formation of Quaternary Stereogenic Centers 期刊论文 Xing Yang;Pankaj Kumar Majhi;Huifang Chai;Bin Liu;Jun Sun;Ting Liu;Yonggui Liu;Liejin Zhou;Jun Sun;Jiawei Liu;Dongdong Wang;Yanli Zhao;Zhichao Jin;Yonggui Robin Chi
14 Carbene-Catalyzed Direct Functionalization of the beta-sp(3)-Carbon Atoms of alpha-Chloroaldehydes 期刊论文 Liu Bin;Luo Guoyong;Wang Hongling;Hao Lin;Yang Song;Jin Zhichao;Chi Yonggui Robin
15 Carbene-Catalyzed alpha,gamma-Deuteration of Enals under Oxidative Conditions 期刊论文 Zhang Xiaolei;Chen Quo;Song Runjiang;Xu Jun;Tian Weiyi;Li Shaoyuan;Jin Zhichao;Chi Yonggui Robin
16 Carbene-Catalyzed Enantioselective Addition of Benzylic Carbon to Unsaturated Acyl Azolium for Rapid Synthesis of Pyrrolo[3,2-c]quinolines 期刊论文 Wang Jilan;Li Yongjia;Sun Jun;Wang Hongling;Jin Zhichao;Chi Yonggui Robin
17 Umpolung of donor–acceptor cyclopropanes via N-heterocyclic carbene organic catalysis 期刊论文 Guihua Nie;Zhongyao Wang;Xuan Huang;Dingwu Pan;Junmin Zhang;Yonggui Robin Chi
18 N-HeterocyclicCarbene Organocatalysis: Activation Modes and Typical Reactive Intermediates 期刊论文 Chen Xingkuan;Wang Hongling;Jin Zhichao;Chi Yonggui Robin
19 Addition of a Carbene Catalyst to Indole Aryl Aldehyde Activates a Remote delta-sp(2) Carbon for Protonation and Formal [4+2] Reaction 期刊论文 Zheng Pengcheng;Wu Shuquan;Mou Chengli;Xue Wei;Jin Zhichao;Chi Yonggui Robin
20 N-Heterocyclic carbene catalyzed aza-benzoin reaction for access to aaminoketone molecules containing benzothiazole fragments 期刊论文 Wei Li;Jie Lv;Yonggui Robin Chi
21 Carbene-Catalyzed Dynamic Kinetic Resolution and Asymmetric Acylation of Hydroxyphthalides and Related Natural Products 期刊论文 Yingguo Liu;Pankaj Kumar Majhi;Runjiang Song;Chengli Mou;Lin Hao;Huifang Chai;Zhichao Jin;Yonggui Robin Chi
22 NHC-catalyzed covalent activation of heteroatoms for enantioselective reactions 期刊论文 Runjiang Song;Zhichao Jin;Yonggui Robin Chi
23 Efficient Access to 2-Pyrones via Carbene-Catalyzed Oxidative [3+3] Reactions between Enals and Nitrogen Ylides 期刊论文 Zheng Pengcheng;Li Chengcheng;Mou Chengli;Pan Dingwu;Wu Shuquan;Xue Wei;Jin Zhichao;Chi Yonggui Robin
24 Hydrodehalogenation of Aryl Halides through Direct Electrolysis 期刊论文 Ke Jie;Wang Hongling;Zhou Liejin;Mou Chengli;Zhang Jingjie;Pan Lutai;Chi Yonggui Robin
25 NHC-Catalyzed Chemoselective Reactions of Enals and Aminobenzaldehydes for Access to Chiral Dihydroquinolines 期刊论文 Wu Shuquan;Liu Changyi;Luo Guoyong;Jin Zhichao;Zheng Pengcheng;Chi Yonggui Robin
26 Carbene-Catalyzed Enantioselective Addition of Thioamides to Bromoenals for Access to Thiazinone Heterocycles 期刊论文 Liu Changyi;Wu Shuquan;Xu Jun;Chen Lingzhu;Zheng Pengcheng;Chi Yonggui Robin
27 Enantioselective access to multi-cyclic α-amino phosphonates via carbene-catalyzed cycloaddition reactions between enals and six-membered cyclic imines 期刊论文 Jun Sun;Chengli Mou;Changyi Liu;Ruoyan Huang;Shupeng Zhang;Pengcheng Zheng;Yonggui Robin Chi
28 NaOH-Promoted Chemoselective Cascade Cyclization of Cyclopropyl Esters with Unsaturated lmines: Access to Bioactive Cyclopenta[c]pyridine Derivatives 期刊论文 Pan Dingwu;Mou Chengli;Zan Ningning;Lv Ya;Song Bao-An;Chi Yonggui Robin;Jin Zhichao
29 Enantioselective Indole N-H Functionalization Enabled by Addition of Carbene Catalyst to Indole Aldehyde at Remote Site 期刊论文 Yang Xing;Luo Guoyong;Zhou Liejin;Liu Bin;Zhang Xiaolei;Gao Hui;Jin Zhichao;Chi Yonggui Robin
30 Carbene-Catalyzed Reaction of Indolyl Methylenemalononitriles and Enals for Access to Complex Tetrahydrocarbazoles 期刊论文 Mou Chengli;Zhou Liejin;Song Runjiang;Chai Huifang;Hao Lin;Chi Yonggui Robin
31 N-heterocyclic carbene-catalyzed arene formation reactions 期刊论文 Tingting Li;Zhichao Jin;Yonggui Robin Chi
32 Carbene-Catalyzed Desymmetrization and Direct Construction of Arenes with All-Carbon Quaternary Chiral Center 期刊论文 Zhu Tingshun;Liu Yingguo;Smetankova Marie;Zhuo Shitian;Mou Chengli;Chai Huifang;Jin Zhichao;Chi Yonggui Robin
33 Access to Cyclic beta-Amino Acids by Amine-Catalyzed Enantioselective Addition of the gamma-Carbon Atoms of alpha,beta-Unsaturated Imines to Enals 期刊论文 Luo Guoyong;Huang Zhijian;Zhuo Shitian;Mou Chengli;Wu Jian;Jin Zhichao;Chi Yonggui Robin
34 Carbene-Catalyzed alpha-Carbon Amination of Chloroaldehydes for Enantioselective Access to Dihydroquinoxaline Derivatives 期刊论文 Huang Ruoyan;Chen Xingkuan;Mou Chengli;Luo Guoyong;Li Yongjia;Li Xiangyang;Xue Wei;Jin Zhichao;Chi Yonggui Robin
35 Carbene-Catalyzed Atroposelective Annulation and Desymmetrization of Urazoles 期刊论文 Jiamiao Jin;Xuan Huang;Jun Xu;Tingting Li;Xiaolin Peng;Xun Zhu;Junmin Zhang;Zhichao Jin;Yonggui Robin Chi
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