新型手性双齿硼基配体的合成及其在不对称碳氢键硼化反应中的应用研究

91956116
2019
B0106.不对称合成
徐森苗
重大研究计划
研究员
中国科学院兰州化学物理研究所
75万元
手性有机硼;手性配体;不对称金属催化;不对称碳杂键形成;不对称碳氢键活化
2020-01-01到2022-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Iridium-Catalyzed Enantioselective C-H Borylation of Diarylphosphinates 期刊论文 Shu-Yong Song;Yinwu Li;Zhuofeng Ke;Senmiao Xu
2 Iridium-Catalyzed Enantioselective Unbiased Methylene C(sp3)–H Borylation of Acyclic Amides 期刊论文 Yuhuan Yang;Lili Chen;Senmiao Xu
3 Synthesis of Chiral Sulfoximines via Iridium‐Catalyzed Regio‐and Enantioselective C‐H Borylation: A Remarkable Sidearm Effect of Ligand 期刊论文 Shuyong Song;Xiaoyu Zhou;Zhuofeng Ke;Senmiao Xu
4 Thieme Chemistry Journals Award 奖励 Senmiao Xu
5 Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Enantioselective Dual C-H Borylation of Ferrocenes: Reaction Development and Mechanistic Insights 期刊论文 Xiaoliang Zou;Yinwu Li;Zhuofeng Ke;Senmiao Xu
6 Boron-nitrogen ligand with chiral 1,2-ethylenediamine backbone, and preparation method and use thereof 专利 Senmiao Xu;Xiaoliang Zou;Haonan Zhao;Qian Gao
7 Iridium-Catalyzed Regio- and Enantioselective Borylation of Unbiased Methylene C(sp3)-H Bonds at the Position β to a Nitrogen Center 期刊论文 Rongrong Du;Luhua LIu;Senmiao Xu
8 JSPS Invitational Fellowships 奖励 Senmiao Xu
9 Iridium-Catalyzed Enantioselective C(sp3)–H Borylation of Cyclobutanes 期刊论文 Xiang Chen;Lili Chen;Hongliang Zhao;Qian Gao;Zhenlu Shen;Senmiao Xu
10 Site‐ and Stereoselective C(sp3)‐H Borylation of Strained (Hetero)Cycloalkanols Enabled by Iridium Catalysis 期刊论文 Qian Gao;Senmiao Xu
11 Iridium-Catalyzed Enantioselective C(sp3)-H Borylation of Aminocyclopropanes 期刊论文 Yongjia Shi;Yuhuan Yang;Senmiao Xu
12 Iridium-Catalyzed Enantioselective alpha-C(sp3)-H Borylation of Azacycles 期刊论文 Chen Lili;Yang Yuhuan;Liu Luhua;Gao Qian;Xu Senmiao
13 Enantioselective C‐H Borylation for the Synthesis of Axially Chiral N‐Aryl phthalimides 期刊论文 Hongliang Zhao;Lili Chen;Chungu Xia;Senmiao Xu
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