手性环戊二烯基稀土配合物不对称催化的立体调控机制及构效关系研究

22003001
2020
B0307.化学反应机制
罗根
青年科学基金项目
教授
安徽大学
24万元
稀土配合物;密度泛函计算;催化剂设计;反应机理研究;不对称催化
2021-01-01到2023-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Unveiling the Detailed Mechanism and Origins of Chemo-, Regio-, and Stereoselectivity of Rare-Earth Catalyzed Alternating Copolymerization of Polar and Nonpolar Olefins 期刊论文 Ni Zhang;Zuqian Xue;Lei Shi;Gen Luo
2 Enantioselective C−H Alkenylation of Ferrocenes with Alkynes by Half-Sandwich Scandium Catalyst 期刊论文 Shao-Jie Lou;Qingde Zhuo;Masayoshi Nishiura;Gen Luo;Zhaomin Hou
3 Syntheses of Rare-Earth Metal Alkyl Complexes Bearing a Dianionic alpha-Iminopyridyl Ligand and Their Catalytic Activities toward Polymerization of 2-Vinylpyridine 期刊论文 Xiuli Zhang;Shuangliu Zhou;Donghan Wang;Lijun Zhang;Yun Wei;Xiancui Zhu;Peng Cui;Gen Luo;Shaowu Wang
4 Modular Access to Spiro-dihydroquinolines via Scandium-Catalyzed Dearomative Annulation of Quinolines with Alkynes 期刊论文 Shao-Jie Lou;Gen Luo;Shigeru Yamaguchi;Kun An;Masayoshi Nishiura;Zhaomin Hou
5 Exo-Selective Intramolecular C−H Alkylation with 1,1-Disubstituted Alkenes by Rare-Earth Catalysts: Construction of Indanes and Tetralins with an All-Carbon Quaternary Center 期刊论文 Aniket Mishra;Ping Wu;Xuefeng Cong;Masayoshi Nishiura;Gen Luo;Zhaomin Hou
6 Three-Coordinate Pd(0) with Rare-Earth Metalloligands: Synergetic CO Activation and Double P-C Bond Cleavage-Formation Reactions 期刊论文 Peng Cui;Changjiang Wu;Jun Du;Gen Luo;Zeming Huang;Shuangliu Zhou
7 Mechanistic insights into rare-earth-catalysed C–H alkylation of sulfides: sulfide facilitating alkene insertion and beyond 期刊论文 Yu Zhou;Ping Wu;Fanshu Cao;Lei Shi;Ni Zhang;Zuqian Xue;Gen Luo
8 Substrate Facilitating Roles in Rare-Earth-Catalyzed C−H Alkenylation of Pyridines with Allenes: Mechanism and Origins of Regio- and Stereoselectivity 期刊论文 Ping Wu;Fanshu Cao;Yu Zhou;Zuqian Xue;Ni Zhang;Lei Shi;Gen Luo
9 Theoretical Studies of Rare-Earth-Catalyzed [3+2] Annulation of Aromatic Aldimine with Styrene: Mechanism and Origin of Diastereoselectivity 期刊论文 Pan Wang;Gen Luo;Jimin Yang;Xuefeng Cong;Zhaomin Hou;Yi Luo
10 Mechanism and Origin of Site Selectivity and Regioselectivity of Scandium-Catalyzed Benzylic C–H Alkylation of Tertiary Anilines with Alkenes 期刊论文 Fanshu Cao;Ping Wu;Yu Zhou;Ni Zhang;Zuqian Xue;Lei Shi;Guangli Zhou;Gen Luo
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