有机膦催化的含质子供体的不饱和化合物的环化反应: 基于质子迁移原理的合理设计

21572264
2015
B0108.新反应与新试剂
郭红超
面上项目
教授
中国农业大学
65万元
有机膦;环化反应;催化;质子迁移;质子供体
2016-01-01到2019-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Phosphine-Catalyzed Enantioselective [4+3] Annulation of Allenoates with C,N-Cyclic Azomethine Imines: Synthesis of Quinazoline-Based Tricyclic Heterocycles 期刊论文 Yuan Chunhao;Zhou Leijie;Xia Miaoren;Sun Zhanhu;Wang Dongqi;Guo Hongchao
2 Thermal [3+2] cycloaddition of phthalazinium dicyanomethanide with allenoates 期刊论文 Wang Bo;Liu Honglei;Wang Qijun;Yuan Chunhao;Jia Hao;Liu Chunxiao;Guo Hongchao
3 Phosphine-promoted [4+3] annulation of allenoate with aziridines for synthesis of tetrahydroazepines: phosphine-dependent [3+3] and [4+3] pathways 期刊论文 Liu Honglei;Lin Yan;Zhao Yan;Xiao Miaoren;Zhou Leijie;Wang Qijun;Zhang Cheng;Wang Dongqi;Kwon Ohyun;Guo Hongchao
4 Phosphine-Catalyzed [4+2] Annulation of Allenoate with Sulfamate-Derived Cyclic 'mines: A Reaction Mode Involving gamma '-Carbon of alpha-Substituted Allenoate 期刊论文 Mao Biming;Shi Wangyu;Liao Jianning;Liu Honglei;Zhang Cheng;Guo Hongchao
5 Lewis base-catalyzed diastereoselective [3+2] cycloaddition reaction of nitrones with electrondeficient alkenes: an access to isoxazolidine derivatives 期刊论文 Liu Honglei;Zhao Yan;Li Zhen;Jia Hao;Zhang Cheng;Xiao Yumei;Guo Hongchao
6 Phosphine-Catalyzed [8+2]-Annulation of Heptafulvenes with Allenoates and Its Asymmetric Variant: Construction of Bicyclo[5.3.0]decane Scaffold 期刊论文 Gao Zhenzhen;Wang Chang;Zhou Leijie;Yuan Chunhao;Xiao Yumei;Guo Hongchao
7 Phosphine-Catalyzed Enantioselective [2+4] Cycloaddition to Synthesize Pyrrolidin-2-one Fused Dihydropyrans Using alpha-Substituted Allenoates as C-2 Synthons 期刊论文 Wang Chang;Jia Hao;Zhang Cheng;Gao Zhenzhen;Zhou Leijie;Yuan Chunhao;Xiao Yumei;Guo Hongchao
8 Double [3+2] cycloaddition of nitrile oxides with allenoates: Synthesis of spirobidihydroisoxazoles 期刊论文 Sun Wei;Jiang Feng;Liu Honglei;Gao Xing;Jia Hao;Zhang Cheng;Guo Hongchao
9 A chiral squaramide-catalyzed asymmetric dearomative tandem annulation reaction through a kinetic resolution of MBH alcohols: highly enantioselective synthesis of three-dimensional heterocyclic compounds 期刊论文 Zhou Leijie;Zeng Yuan;Gao Xing;Wang Qijun;Wang Chang;Wang Bo;Wang Wei;Wu Yongjun;Zheng Bing;Guo Hongchao
10 Direct Activation of Unmodified Morita-Baylis-Hillman Alcohols through Phosphine Catalysis for Rapid Construction of Three-Dimensional Heterocyclic Compounds 期刊论文 Zhou Leijie;Yuan Chunhao;Zeng Yuan;Wang Qijun;Wang Chang;Liu Min;Wang Wei;Wu Yongjun;Zheng Bing;Guo Hongchao
11 Phosphine-Catalyzed Asymmetric Cycloaddition Reaction of Diazenes: Enantioselective Synthesis of Chiral Dihydropyrazoles 期刊论文 Wang Chang;Chen Yuehua;Li Jingyu;Zhou Leijie;Wang Bo;Xiao Yumei;Guo Hongchao
12 A [4+3] Annulation Reaction of aza-o-Quinone Methides with Arylcarbohydrazonoyl Chlorides for Synthesis of 2,3-Dihydro-1H-benzo[e][1,2,4]triazepines 期刊论文 Guo Zhenyan;Jia Hao;Liu Honglei;Wang Qijun;Huang Jiaxing;Guo Hongchao
13 DMAP-catalyzed [4 2] annulation of alpha-substituded allenoates with unsaturated pyrazolones 期刊论文 Xu Jiaqing;Yang Wenjun;Shi Wangyu;Mao Biming;Lin Yan;Xiao Yumei;Guo Hongchao
14 Phosphine-catalyzed [5+1] annulation of delta-sulfonamido-substituted enones with N-sulfonylimines: a facile synthesis of tetrahydropyridines 期刊论文 Leijie Zhou;Chunhao Yuan;Yuan Zeng;Honglei Liu;Chang Wang;Xing Gao;Qijun Wang;Cheng Zhang;Hongchao Guo
15 Asymmetric Construction of Highly Functionalized Spirobarbiturate-Cyclopentenes through Chiral Phosphine-Catalyzed [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Barbiturate-Derived Alkenes 期刊论文 Liu Yang;Yang Wenjun;Wu Yang;Mao Biming;Gao Xing;Liu Honglei;Sun Zhanhu;Xiao Yumei;Guo Hongchao
16 Phosphine-Catalyzed [2+4] Annulation of Allenoates with Thiazolone-Derived Alkenes: Synthesis of Functionalized 6,7-Dihydro-5H-pyrano[2,3-d]thiazoles 期刊论文 Wang Chang;Gao Zhenzhen;Zhou Leijie;Yuan Chunhao;Sun Zhanhu;Xiao Yumei;Guo Hongchao
17 Synthesis of Dihydropyrano[3,2-c]pyrazolone through 1,3-Dipolar Cycloaddition of Nitrilimines with Methyl Coumalate 期刊论文 Wang Bo;Wang Qijun;Liu Honglei;Liao Jianning;Huang Jiaxing;Guo Hongchao
18 Phosphine-Catalyzed [3+2] Annulation of beta-Sulfonannido-Substituted Enones with Sulfamate-Derived Cyclic Imines 期刊论文 Shi Wangyu;Zhou Leijie;Mao Biming;Wang Qijun;Wang Chang;Zhang Cheng;Li Xuefeng;Xiao Yumei;Guo Hongchao
19 Lewis-Base-Catalyzed Asymmetric [3+3] Annulation Reaction of Morita-Baylis-Hillman Carbonates: Enantioselective Synthesis of Spirocyclohexenes 期刊论文 Yang Wenjun;Sun Wei;Zhang Cheng;Wang Qijun;Guo Zhenyan;Mao Biming;Liao Jianning;Guo Hongchao
20 Phosphine-catalyzed [3+2] and [4+2] annulation reactions of ynones with barbiturate-derived alkenes 期刊论文 Gao Xing;Li Zhen;Yang Wenjun;Liu Yang;Chen Wufeng;Zhang Cheng;Zheng Lufei;Guo Hongchao
21 Phosphine-Catalyzed [3+2] Annulation of 2-Hydroxy-1,4-naphthaquinones and Allenoate: An Allene-Alkene [3+2] Annulation Mechanism Involving Consecutive gamma-Addition-Aldol Reaction 期刊论文 Zhou Leijie;Wang Chang;Yuan Chunhao;Liu Honglei;Zhang Cheng;Guo Hongchao
22 Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric AnnulationsNucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations 期刊论文 Xiao Yumei;Guo Hongchao;Kwon Ohyun
23 Synthesis of Spirobidihydropyrazole through Double 1,3-Dipolar Cycloaddition of Nitrilimines with Allenoates 期刊论文 Liu Honglei;Jia Hao;Wang Bo;Xiao Yumei;Guo Hongchao
24 Phosphane-Catalyzed [3+3] Annulation of C,N-Cyclic Azomethine Imines with Ynones: A Practical Method for Tricyclic Dinitrogen-Fused Heterocycles 期刊论文 Li Zhen;Yu Hao;Liu Yang;Zhou Leijie;Sun Zhanhu;Guo Hongchao
25 Diastereodivergent Synthesis of Pyrazoline Derivatives through [3+2] Cycloaddition of Baylis-Hillman Adducts and Nitrilimines 期刊论文 Zeng Yuan;Zhou Leijie;Gao Xing;Wu Yang;Wang Qijun;Guo Zhenyan;Huang Jiaxing;Guo Hongchao
26 Chiral Phosphine-Catalyzed Enantioselective [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Cyclic 1-Azadienes: Synthesis of Functionalized Cyclopentenes 期刊论文 Wu Yang;Liu Yang;Yang Wenjun;Liu Honglei;Zhou Leijie;Sun Zhanhu;Guo Hongchao
27 Multifunctional chiral phosphine-catalyzed [3+2] annulation of Morita-Baylis-Hillman carbonates with cyclopentenones: asymmetric synthesis of 4-oxo-hexahydropentalenes 期刊论文 Wang Chang;Gao Zhenzhen;Zhou Leijie;Wang Qijun;Wu Yang;Yuan Chunhao;Liao Jianning;Xiao Yumei;Guo Hongchao
28 Phosphine Organocatalysis 期刊论文 Guo Hongchao;Fan Yi Chiao;Sun Zhanhu;Wu Yang;Kwon Ohyun
29 Phosphine-catalyzed [3+2] cycloaddition of phthalazinium dicyanomethanides with allenoates: highly efficient synthesis of 1,2,3,10b-tetrahydropyrrolo[2,1-a]phthalazine derivatives 期刊论文 Yuan Chunhao;Zhou Leijie;Sun Zhanhu;Guo Hongchao
30 Enantioselective Synthesis of Quinazoline-Based Heterocycles through Phosphine-Catalyzed Asymmetric [3+3] Annulation of Morita-Baylis-Hillman Carbonates with Azomethine Imines 期刊论文 Zhou Leijie;Yuan Chunhao;Zhang Cheng;Zhang Lei;Gao Zhenzhen;Wang Chang;Liu Honglei;Wu Yang;Guo Hongchao
31 Phosphine-Catalyzed [3+2] Annulation of beta-Sulfonannido-Substituted Enones with Sulfamate-Derived Cyclic Imines 期刊论文 Shi Wangyu;Zhou Leijie;Mao Biming;Wang Qijun;Wang Chang;Zhang Cheng;Li Xuefeng;Xiao Yumei;Guo Hongchao
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