α位氧取代氮烯中间体的产生、光谱、结构与反应机理
21372173
2013
B0113.结构与反应机制
曾小庆
面上项目
教授
苏州大学
80万元
结构与活性;电子结构;反应机理;α位氧取代氮烯;分子光谱
2014-01-01到2017-12-31
- 中英文摘要
- 结题摘要
- 结题报告
- 项目成果
- 项目参与人
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| 序号 | 标题 | 类型 | 作者 |
|---|---|---|---|
| 1 | Photolysis of Carbonyl Diisocyanate: Generation of Isocyanatocarbonyl Nitrene and Diazomethanone | 期刊论文 | Qifan Liu;Hongmin Li;Zhuang Wu;Dingqing Li;Helmut Beckers;Guntram Rauhut;Xiaoqing Zeng |
| 2 | Decomposition of fluorophosphoryl diazide: a joint experimental and theoretical study | 期刊论文 | Dingqing Li;Hongmin Li;Bifeng Zhu;Xiaoqing Zeng;Helge Willner;Helmut Beckers;Patrik Neuhaus;Dirk Grote;Wolfram Sander |
| 3 | Photochemistry of Matrix Isolated (Trifluoromethyl)sulfonyl Azide, CF3SO2N3 | 期刊论文 | Xiaoqing Zeng;Helmut Beckers;Helge Willner;Patrik Neuhaus;Dirk Grote;Wolfram Sander |
| 4 | Difluoroacetyl azide: Synthesis, characterization, and decomposition | 期刊论文 | Ruijuan Feng;Zhuang Wu;Jian Xu;Qifan Liu;Xiaoqing Zeng |
| 5 | SN2P2 : A Neutral Five-Membered Sulfur–Pnictogen(III) Ring | 期刊论文 | Xiaoqing Zeng;Hongmin Li;Hailong Sun;Helmut Beckers;Helge Willner;Henry F. Schaefer III |
| 6 | Fast Heavy-Atom Tunneling in Trifluoroacetyl Nitrene | 期刊论文 | Zhuang Wu;Ruijuan Feng;Hongmin Li;Jian Xu;Guohai Deng;Manabu Abe;Didier Begue;Kun Liu;Xiaoqing Zeng |
| 7 | A Singlet Thiophosphoryl Nitrene and Its Interconversion with Thiazyl and Thionitroso Isomers | 期刊论文 | Hongmin Li;Zhuang Wu;Dingqing Li;Xiaoqing Zeng;Helmut Beckers;Joseph S. Francisco |
| 8 | Dichlorophosphanyl isocyanate – spectroscopy, conformation and molecular structure in the gas phase and the solid state | 期刊论文 | Dingqing Li;Jan Schwabedissen;Hans-Georg Stammler;Norbert W. Mitzel;Helge Willner;Xiaoqing Zeng |
| 9 | Conformational composition, molecular structure and decomposition of difluorophosphoryl azide in the gas phase | 期刊论文 | Zhuang Wu;Hongmin Li;Bifeng Zhu;Xiaoqing Zeng;Stuart A. Hayes;Norbert W. Mitzel;Helmut Beckers;Raphael J. F. Berger |
| 10 | The decomposition of benzenesulfonyl azide: a matrix isolation and computational study | 期刊论文 | Guohai Deng;Xuelin Dong;Qifan Liu;Dingqing Li;Hongmin Li;Qiao Sun;Xiaoqing Zeng |
| 11 | The hypothiocyanite radical OSCN and its isomers | 期刊论文 | Zhuang Wu;Jian Xu;Qifan Liu;Xuelin Dong;Dingqing Li;Nicole Holzmann;Gernot Frenking;Tarek Trabelsi;Joseph S. Francisco;Xiaoqing Zeng |
| 12 | Thermally Persistent Carbonyl Nitrene: FC(O)N | 期刊论文 | Hailong Sun;Bifeng Zhu;Zhuang Wu;Xiaoqing Zeng;Helmut Beckers;William S. Jenks |
| 13 | Direct observation of methoxycarbonylnitrene | 期刊论文 | Hongmin Li;Zhuang Wu;Dingqing Li;Huabin Wan;Jian Xu;Manabu Abe;Xiaoqing Zeng |
| 14 | Simplest N‑Sulfonylamine HNSO2 | 期刊论文 | Guohai Deng;Zhuang Wu;Dingqing Li;Roberto Linguerri;Joseph S. Francisco;Xiaoqing Zeng |
| 15 | Isomers of Disulfur Dinitride, S2N2 | 期刊论文 | Xiaoqing Zeng;Andrea Flores Antognini;Helmut Beckers;Helge Willner |
| 16 | Contrasting Photolytic and Thermal Decomposition of Phenyl Azidoformate: The Curtius Rearrangement Versus Intramolecular C− H Amination | 期刊论文 | Huabin Wan;Jian Xu;Qian Liu;Hongmin Li;Yan Lu;Manabu Abe;Xiaoqing Zeng |
| 17 | The Photochemical and Thermal Decomposition of Azidoacetylene in the Gas Phase, Solid Matrix, and Solutions | 期刊论文 | Xiaoqing Zeng;Helmut Beckers;Jennifer Seifert;Klaus Banert |
| 18 | Toward Understanding the Decomposition of Carbonyl Diazide (N3)2C=O and Formation of Diazirinone cycl-N2CO: Experiment and Computations | 期刊论文 | Hongmin Li;Dingqing Li;Xiaoqing Zeng;Kun Liu;Helmut Beckers;Henry F. Schaefer III;Brian J. Esselman;Robert J. McMahon |
| 19 | Methanesulfonyl Azide: Molecular Structure and Photolysis in Solid Noble Gas Matrices | 期刊论文 | Guohai Deng;Dingqing Li;Zhuang Wu;Hongmin Li;Eduard Bernhardt;Xiaoqing Zeng |
| 20 | The Methylsulfonyloxyl Radical, CH3SO3 | 期刊论文 | Bifeng Zhu;Xiaoqing Zeng;Helmut Beckers;Joseph S. Francisco;Helge Willner |
| 21 | N-Methylcarbamoyl azide: spectroscopy, X-ray structure and decomposition via methylcarbamoyl nitrene | 期刊论文 | Huabin Wan;Hongmin Li;Jian Xu;Zhuang Wu;Qifan Liu;Xianxu Chu;Manabu Abe;Didier Bégué;Xiaoqing Zeng |
| 22 | Direct Observation of Carbamoylnitrenes | 期刊论文 | Hongmin Li;Huabin Wan;Zhuang Wu;Dingqing Li;Didier Begue;Curt Wentrup;Xiaoqing Zeng |
| 23 | Heterocumulene Sulfinyl Radical OCNSO | 期刊论文 | Zhuang Wu;Qifan Liu;Jian Xu;Hailong Sun;Dingqing Li;Chao Song;Diego M. Andrada;Gernot Frenking;Tarek Trabelsi;Joseph S. Francisco;Xiaoqing Zeng |
| 24 | Gas-Phase Generation and Decomposition of a Sulfinylnitrene into the Iminyl Radical OSN | 期刊论文 | Zhuang Wu;Dingqing Li;Hongmin Li;Bifeng Zhu;Hailong Sun;Joseph S. Francisco;Xiaoqing Zeng |
| 25 | Flash vacuum pyrolysis of methoxysulfinyl azide: Stepwisedecomposition via methoxysulfinyl nitrene | 期刊论文 | Zhuang Wu;Qifan Liu;Dingqing Li;Ruijuan Feng;Xiaoqing Zeng |
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