过渡金属催化α官能化烷基自由基参与的环化反应研究

21302148
2013
B0102.配位化学
刘超
青年科学基金项目
研究员
武汉大学
25万元
自由基;环化;过渡金属催化;α官能化烷基自由基
2014-01-01到2016-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Bimetallic zinc complex - active species in coupling of terminal alkynes with aldehydes via nucleophilic addition/Oppenauer oxidation 期刊论文 Jeffrey T. Miller|A. Jeremy Kropf|Emilio E. Bunel|Aiwen Lei|
2 Nickel-Catalyzed Selective Oxidative Radical Cross-Coupling: An Effective Strategy for Inert Csp3–H Functionalization 期刊论文 Qi, Xiaotian|Liu, Chao|Lan, Yu|Lei, Aiwen|
3 A facile access for the C-N bond formation by transition metal-free oxidative coupling of benzylic C-H bonds and amides 期刊论文 Zhang, Heng|Yi, Hong|Liu, Chao|Lei, Aiwen|
4 Oxidative cross S-H/S-H coupling: selective synthesis of unsymmetrical aryl tert-alkyl disulfanes 期刊论文 Yuan, Jiwen|Liu, Chao|Lei, Aiwen|
5 Direct oxidative esterification of alcohols 期刊论文 Tang, Shan|Yuan, Jiwen|Liu, Chao|Lei, Aiwen|
6 Revealing the metal-like behavior of iodine: an iodide-catalysed radical oxidative alkenylation 期刊论文 Liao, Wenqing|Bai, Ruopeng|Liu, Chao|Lei, Aiwen|
7 Copper-Catalyzed Radical/Radical Csp3-H/P-H Cross-Coupling: α-Phosphorylation of Aryl Ketone O-Acetyloximes 期刊论文 Li, Yali|Cheng, Yongde|Liu, Chao|Lei, Aiwen|
8 Tuning the Reactivity of Radical through a Triplet Diradical Cu(II) Intermediate in Radical Oxidative Cross-Coupling. 期刊论文 Liu, Chao|Feng, Yuqi|Lan, Yu|Lei, Aiwen|
9 Palladium catalysed beta-selective oxidative Heck reaction of an electron-rich olefin 期刊论文 Liu, Chao#|Zhang, Wei|Zhou, Chao|Lei, Aiwen|
10 Nickel-Catalyzed Aromatic C-H Alkylation with Secondary or Tertiary Alkyl-Bromine Bonds for the Construction of Indolones 期刊论文 Liu, Dong|Zhang, Wei|Zhou, Liangliang|Lei, Aiwen|
11 Recent Advances of Transition-Metal Catalyzed Radical Oxidative Cross-Couplings 期刊论文 Liu, Chao|Liu, Dong|Lei, Aiwen|
12 Acid-Promoted Cross-Dehydrative Aromatization for the Synthesis of Tetraaryl-Substituted Pyrroles. 期刊论文 Li, Ke|Wang, Siyuan|Liu, Chao|Lei, Aiwen|
13 Palladium-Catalyzed Oxidative Carbonylation of N-Allylamines for the Synthesis of beta-Lactams 期刊论文 Zhang, Wangzheng|Duan, Zhengli|You, Shuli|Lei, Aiwen|
14 Dinuclear versus mononuclear pathways in zinc mediated nucleophilic addition: a combined experimental and DFT study 期刊论文 Li, Yang|Lei, Aiwen|Liu, Chao|Lan, Yu|
15 Revealing the Ligand Effect on Copper(I) Disproportionation via Operando IR Spectra 期刊论文 Yi, Hong|He, Chuan|Liu, Chao|Lei, Aiwen|
16 External Oxidant-Free Oxidative Cross-Coupling: A Photoredox Cobalt-Catalyzed Aromatic C-H Thiolation for Constructing C-S Bonds. 期刊论文 Chen, Hong|Jian, Jing-Xin|Wu, Li-Zhu|Lei, Aiwen|
17 Carbon-Centered Radical Addition to C=X Bonds for C?X Bond Formation 期刊论文 Liu, Dong|Liu, Chao|Lei, Aiwen|
18 Cu(II)-Cu(I) Synergistic Cooperation to Lead the Alkyne C-H Activation 期刊论文 Kropf, A. Jeremy|Bunel, Emilio E.|Lan, Yu|Lei, Aiwen|
19 Copper-catalyzed oxidative alkenylation of thioethers via Csp3-H functionalization 期刊论文 Liu, Dong|Liu, Chao|Hu, Xinquan|Lei, Aiwen|
20 Halogen-Adjusted Chemoselective Synthesis of Fluorene Derivatives with Position-Controlled Substituents. 期刊论文 Wei, Fuliang|Liu, Chao|Qian, Yan|Chen, Shufen|
21 Synthesis of Fluoren-9-ones and Ladder-Type Oligo-p-phenylene Cores via Pd-Catalyzed Carbonylative Multiple C–C Bond Formation 期刊论文 Tian, Yanan|Liu, Chao|Li, Yali|Xie, Linghai|
22 Carbon-Centered Radical Addition to O=C of Amides or Esters as a Route to C-O Bond Formations 期刊论文 Liu, Chao|Qi, Xiaotian|Lan, Yu|Lei, Aiwen|
23 Construction of N-containing heterocycles via oxidative intramolecular N-H/X-H coupling 期刊论文 Jiwen Yuan|Chao Liu|Aiwen Lei|
24 Copper-catalysed oxidative Csp(3)-H methylenation to terminal olefins using DMF 期刊论文 Liu, Chao|Liu, Ren|Zhang, Guoting|Lei, Aiwen|
25 Revealing the halide effect on the kinetics of the aerobic oxidation of Cu(I) to Cu(II) 期刊论文 Kropf, A. Jeremy|Bunel, Emilio E.|Lan, Yu|Lei, Aiwen|
26 Trisulfur Radical Anion as the Key Intermediate for the Synthesis of Thiophene via the Interaction between Elemental Sulfur and NaOtBu 期刊论文 Chen, Hong|Bian, Changliang|Liu, Chao|Lei, Aiwen|
27 Olefinic C-H functionalization through radical alkenylation 期刊论文 Tang, Shan|Liu, Kun|Liu, Chao|Lei, Aiwen|
28 Chloroacetate-Promoted Selective Oxidation of Heterobenzylic Methylenes under Copper Catalysis 期刊论文 Liu, Ren|Zhang, Heng|Zhuo, Kelei|Lei, Aiwen|
29 Synergistic Pd/Enamine Catalysis: A Strategy for the C-H/C-H Oxidative Coupling of Allylarenes with Unactivated Ketones 期刊论文 Liu, Kun|Liu, Chao|Luo, Sanzhong|Lei, Aiwen|
30 Oxidative Coupling between Two Hydrocarbons: An Update of Recent C-H Functionalizations. 期刊论文 Tang, Shan|Li, Wu|Shi, Renyi|Lei, Aiwen|
31 I-2-catalyzed oxidative C(sp(3))-H/S-H coupling: utilizing alkanes and mercaptans as the nucleophiles 期刊论文 Ma, Xu|Yi, Hong|Liu, Chao|Lei, Aiwen|
32 Transition-Metal-Assisted Radical/Radical Cross-Coupling: A New Strategy to the Oxidative C(sp(3))-H/N-H Cross-Coupling 期刊论文 Liu, Kun|Liu, Chao|Lan, Yu|Lei, Aiwen|
33 Aerobic C-N bond activation: a simple strategy to construct pyridines and quinolines 期刊论文 Huang, Zhiliang|Liu, Chao|Zhang, Heng|Lei, Aiwen|
34 Highlyefficient C-C cross-coupling for installing thiophene rings into p-conjugatedsystems 期刊论文 Cao Xiao|Liu Chao|Xie Linghai|Huang Wei|
35 From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C-H Bonds 期刊论文 Jiang, Ru|Zeng, Hongyao|Liu, Chao|Lei, Aiwen|
36 Halogen-Adjusted Chemoselective Synthesis of Fluorene Derivatives with Position-Controlled Substituents. 期刊论文 Wei, Fuliang|Liu, Chao|Qian, Yan|Chen, Shufen|
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