镍催化烷基化合物的单氟烷基化反应

21772187
2017
B0101.元素化学
王细胜
面上项目
教授
中国科学技术大学
64万元
自由基;镍催化;交叉偶联;单氟烷基化;烷基化合物
2018-01-01到2021-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Enantioselective Copper-Catalyzed Cyanation of Remote C(sp(3))-H Bonds Enabled by 1,5-Hydrogen Atom Transfer 期刊论文 Cheng-Yu Wang;Zi-Yang Qin;Yu-Ling Huang;Ruo-Xing Jin;Quan Lan;Xi-Sheng Wang
2 Enantioselective Copper-Catalyzed Remote C(sp3)−H Alkynylation of Linear Primary Sulfonamides 期刊论文 Cheng-Yu Wang;Zi-Yang Qin;Yu-Ling Huang;Yi-Ming Hou;Ruo-Xing Jin;Chao Li;Xi-Sheng Wang
3 Nickel-Catalyzed Direct Trifluoroethylation of Aryl Iodides with 1,1,1-Trifluoro-2-Iodoethane via Reductive Coupling 期刊论文 Han Li;Jie Sheng;Guang-Xu Liao;Bing-Bing Wu;Hui-Qi Ni;Yan Li;Xi-Sheng Wang
4 Diverse Synthesis of Chiral Trifluoromethylated Alkanes via Nickel-Catalyzed Asymmetric Reductive Cross-Coupling Fluoroalkylation 期刊论文 Yue Min;Jie Sheng;Jian-Liang Yu;Shan-Xiu Ni;Guobin Ma;Hegui Gong;Xi-Sheng Wang
5 Facile synthesis of axially chiral styrene-type carboxylic acids via palladium-catalyzed asymmetric C–H activation 期刊论文 Chi Yang;Tian-Rui Wu;Yan Li;Bing-Bing Wu;Ruo-Xing Jin;Duo-Duo Hu;Yuan-Bo Li;Kang-Jie Bian;Xi-Sheng Wang
6 Nickel-Catalyzed Carbofluoroalkylation of 1,3-Enynes to Access Structurally Diverse Fluoroalkylated Allenes 期刊论文 Kai-Fan Zhang;Kang-Jie Bian;Chao Li;Jie Sheng;Yan Li;Xi-Sheng Wang
7 Visible light-mediated atom transfer radical addition to styrene: base controlled selective (phenylsulfonyl)difluoromethylation 期刊论文 Jie Sheng;Kang-Jie Bian;Yi-Ming Su;Guang-Xu Liao;Ruomeng Duan;Chen Li;Zhihong Liu;Xi-Sheng Wang
8 Diversity-Oriented Synthesis of Aliphatic Fluorides via Reductive C(sp3)—C(sp3 ) Cross-Coupling Fluoroalkylation 期刊论文 Jie Sheng;Hui-Qi Ni;Shan-Xiu Ni;Yan He;Ru Cui;Guang-Xu Liao;Kang-Jie Bian;Bing-Bing Wu;Xi-Sheng Wang
9 Enantioselective cyanation via radical-mediated C–C single bond cleavage for synthesis of chiral dinitriles 期刊论文 Tao Wang;Yi-Ning Wang;Rui Wang;Bo-Chao Zhang;Chi Yang;Yan-Lin Li;Xi-Sheng Wang
10 Development of Axially Chiral Styrene-Type Carboxylic Acid Ligands via Palladium-Catalyzed Asymmetric C−H Alkynylation 期刊论文 Chi Yang;Fei Li;Tian-Rui Wu;Ru Cui;Bing-Bing Wu;Ruo-Xing Jin;Yan Li;Xi-Sheng Wang
11 Nickel-Catalyzed Cross-Coupling of Ethyl Chlorofluoroacetate with Aryl Bromides 期刊论文 Han Li;Jie Sheng;Bing-Bing Wu;Yan Li;Xi-Sheng Wang
12 Nickel-catalyzed monofluoromethylation of (hetero)aryl bromides via reductive cross-coupling 期刊论文 Han Yin;Jie Sheng;Kai-Fan Zhang;Zi-Qi Zhang;Kang-Jie Bian;Xi-Sheng Wang
13 Highly stereoselective nickel-catalyzed difluoroalkylation of aryl ketones to tetrasubstituted monofluoroalkenes and quaternary alkyl difluorides 期刊论文 Chao Li;Yi-Xuan Cao;Ruo-Xing Jin;Kang-Jie Bian;Zi-Yang Qin;Quan Lan;Xi-Sheng Wang
14 Copper-catalyzed monochloromethylazidation to access transformable terminal alkyl chlorides using stoichiometric BrCH2Cl 期刊论文 Ya-Xuan Zhang;Kang-Jie Bian;Ruo-Xing Jin;Chi Yang;Xi-Sheng Wang
15 Palladium(II)-catalyzed asymmetric C–H carbonylation to diverse isoquinoline derivatives bearing all-carbon quaternary stereocenters 期刊论文 Yan Li;Xiu-Fen Cheng;Fan Fei;Tian-Rui Wu;Kang-Jie Bian;Xin Zhou;Xi-Sheng Wang
16 Remote azidation of C(sp3)–H bonds to synthesize δ-azido sulfonamides via iron-catalyzed radical relay 期刊论文 Kang-Jie Bian;Cheng-Yu Wang;Yu-Ling Huang;Yi-Hao Xu;Xi-Sheng Wang
17 Facile Synthesis of Quaternary -Fluoronitriles by Cobalt-Catalyzed Hydrocyanation of Monofluoroalkenes 期刊论文 Yanlin Li;Ru Cui;Tian-Rui Wu;Xi-Sheng Wang
18 Nickel-catalyzed reductive monofluoroakylation of alkyl tosylate with bromofluoromethane to primary alkyl fluoride 期刊论文 Ru Cui;Jie Sheng;Bing-Bing Wu;Duo-Duo Hu;Hong-Qian Zheng;Xi-Sheng Wang
19 Development of Monofluoroalkenes as Molecular Platform for Diversity-Oriented Syntheses of Tertiary Aliphatic Fluorides via Nickel/Manganese-Dual Catalysis 期刊论文 Yanlin Li;Wei Liu;Zhi-Yuan Liu;Cheng-Yu Wang;Kang-Jie Bian;Jie Sheng;Xi-Sheng Wang
20 Copper-Catalyzed Enantioselective Arylation via Radical-Mediated C−C Bond Cleavage: Synthesis of Chiral ω,ω-Diaryl Alkyl Nitriles 期刊论文 Guo-Qing Cui;Jing-Cheng Dai;Yan Li;Yuan-Bo Li;Duo-Duo Hu;Kang-Jie Bian;Jie Sheng;Xi-Sheng Wang
21 Copper-Catalyzed Trifluoromethylation/Cyclization of Alkynes for Synthesis of Dioxodibenzothiazepines 期刊论文 Zi-Qi Zhang;Yi-Hao Xu;Jing-Cheng Dai;Yan Li;Jie Sheng;Xi-Sheng Wang
22 NHC Ligand-Enabled, Palladium-Catalyzed Non-Directed C(sp(3))-H Carbonylation To Access Indanone Cores 期刊论文 Shou-Le Cai;Yan Li;Chi Yang;Jie Sheng;Xi-Sheng Wang
23 Enantioselective Copper-Catalyzed 1,5-Cyanotrifluoromethylation of Vinylcyclopropanes 期刊论文 Zi-Qi Zhang;Xiang-Yu Meng;Jie Sheng;Quan Lan;Xi-Sheng Wang
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