亲电试剂活化三级胺、三取代肼和二取代羟胺而促进的一些重排反应

21772182
2017
B0108.新反应与新试剂
田仕凯
面上项目
教授
中国科学技术大学
64万元
肼;亲电试剂;胺;重排反应;羟胺
2018-01-01到2021-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Palladium-Catalyzed Highly Regioselective Aromatic Substitution of Benzylic Ammonium Salts with Amines 期刊论文 Xu Ya-Nan;Zhu Meng-Zeng;Lin Yu-Kun;Tian Shi-Kai
2 1,2-Aminohalogenation of arynes with amines and organohalides 期刊论文 Li Sheng-Jun;Han Lu;Tian Shi-Kai
3 Highly Regioselective Aromatic C-H Allylation of N-(Arylmethyl)sulfonimides with Allyl Grignard Reagents Involving Benzylic C-N Cleavage 期刊论文 Zhu Meng-Zeng;Xie Dong;Tian Shi-Kai
4 Convenient Synthesis of Benzofuro[3,2-b]quinolines from 1-Azadienes and Arynes 期刊论文 Wang Qi;Wang Yan;Tian Shi-Kai
5 Facile construction of three-membered rings via benzyne-promoted Darzens-type reaction of tertiary amines 期刊论文 Xu Ya-Nan;Tian Shi-Kai
6 Chiral alpha-Amino Acid/Palladium-Catalyzed Asymmetric Allylation of alpha-Branched beta-Ketoesters with Allylic Amines: Highly Enantioselective Construction of All-Carbon Quaternary Stereocenters 期刊论文 Xu Ya-Nan;Zhu Meng-Zeng;Tian Shi-Kai
7 Aromatic Aza-Claisen Rearrangement of Arylpropargylammonium Salts Generated in situ from Arynes and Tertiary Propargylamines 期刊论文 Han Lu;Li Sheng-Jun;Zhang Xue-Ting;Tian Shi-Kai
8 Nucleophilic addition of tertiary propargylic amines to arynes followed by a [2,3]-sigmatropic rearrangement 期刊论文 Zhou Meng-Guang;Dai Rui-Han;Tian Shi-Kai
9 Strain-release C-C bond cleavage enables the [2,3]-sigmatropic rearrangement of tertiary allylamines 期刊论文 Dai Rui-Han;Han Lu;Wang Qi;Tian Shi-Kai
10 Asymmetric Aza-Claisen Rearrangement between Enantioenriched alpha-Chiral Allylamines and Allenones 期刊论文 Dai Rui-Han;Wang Qi;Chen Zhi-Xiong;Tian Shi-Kai
11 Carbon Tetrachloride-Mediated Cyclization of (2-Alkynyl)arylaldimines for the Synthesis of Polychlorinated Nitrogen Heterocycles 期刊论文 Wang Hai-Yang;Tian Shi-Kai
12 Benzyne-Promoted Curtius-Type Rearrangement of Acyl Hydrazides in the Presence of Nucleophiles 期刊论文 Guo Jing-Yu;Zhong Chen-Hao;He Zeng-Yang;Tian Shi-Kai
13 Copper-Catalyzed Oxidative Carbamoylation of N-Arylacrylamides with Hydrazinecarboxamides Leading to 2-(Oxindol-3-yl)acetamides 期刊论文 He Zeng-Yang;Guo Jing-Yu;Tian Shi-Kai
14 TfNHNHBoc as a SCF3 source for the sulfenylation of indoles 期刊论文 Guo Jing-Yu;Dai Rui-Han;Xu Wen-Cong;Wu Ruo-Xin;Tian Shi-Kai
15 Epoxide-Mediated Stevens Rearrangements of -Amino-Acid-Derived Tertiary Allylic, Propargylic, and Benzylic Amines: Convenient Access to Polysubstituted Morpholin-2-ones 期刊论文 Jin You-Xiang;Yu Bang-Kui;Qin Si-Ping;Tian Shi-Kai
16 Formal Insertion of Imines (or Nitrogen Heteroarenes) and Arynes into the C-Cl Bond of Carbon Tetrachloride 期刊论文 Li Sheng-Jun;Wang Yi;Xu Jing-Kun;Xie Dong;Tian Shi-Kai;Yu Zhi-Xiang
17 Aryne-mediated [2,3]-sigmatropic rearrangement of tertiary 2,3-allenylamines bearing an electron-withdrawing group at the alpha-position 期刊论文 Han Lu;Zhang Xue-Ting;Xie Dong;Tian Shi-Kai
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