【21272221】Corey-Link反应的不对称催化研究及其在天然产物合成中的应用国家自然基金项目

Corey-Link反应的不对称催化研究及其在天然产物合成中的应用

项目批准号： 21272221

批准年份： 2012

学科分类： B0106.不对称合成

项目负责人：顾振华

资助类别：面上项目

负责人职称：教授

依托单位：中国科学技术大学

资助金额： 80万元

关键词： Corey-Link反应;全合成;不对称催化;三氯甲基化

起止时间： 2013-01-01到2016-12-31

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序号	标题	类型	作者
1	Palladium-Catalyzed Chemoselective Catellani ortho-Arylation Reactions and Their Applications in Natural Products Synthesis	期刊论文	Xianwei Sui\|Rui Zhu\|Zhenhua Gu\|
2	Palladium-Catalyzed Heck-type Domino Cyclization and Carboxylation to Synthesize Carboxylic Acids by Utilizing Chloroform as the Carbon Monoxide Source	期刊论文	Xianglei Liu\|Bin Li\|Zhenhua Gu\|
3	Synthesis of 2-(1-Alkoxyvinyl)anilines by Palladium/Norbornene-Catalyzed Amination Followed by Termination with Vinyl Ethers	期刊论文	Jie Wang\|Zhenhua Gu\|
4	Highly e？cient and practical resolution of 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione and stereoselective synthesis of its chiral diamine derivatives	期刊论文	Bin Wang\|Zhenhua Gu\|
5	BF3·OEt2？Promoted Synthesis of 2,3- Metallocenocyclohexanones: A 1,2-Hydride Shift and Cationic Cyclization Strategy	期刊论文	Congfa He\|Jie Wang\|Zhenhua Gu\|
6	Total Synthesis of Aquatolide: Wolff Ring Contraction and Late-Stage Nozaki-Hiyama-Kishi Medium-Ring Formation	期刊论文	Yuanzhen Xie\|Qin Yang\|Guozhu Zhang\|Zhenhua Gu\|
7	Pd/norbornene-catalyzed sequential ortho-C–H alkylation and ipso-alkynylation: a 1,1-dimethyl-2-alkynol strategy	期刊论文	Fenggang Sun\|Miao Li\|Zhenhua Gu\|
8	Cleavage of the C(O)-S Bond of Thioesters by Palladium/Norbornene/Copper Cooperative Catalysis: An Efficient Synthesis of 2-(Arylthio)aryl Ketone	期刊论文	Bin Wang\|Bin Li\|Xianwei Sui\|Zhenhua Gu\|
9	Pd-Catalyzed Chemoselective Catellani Ortho-Arylation of Iodopyrroles: Rapid Total Synthesis of Rhazinal	期刊论文	Rui Zhu\|Gencheng Li\|Xinna Ma\|Zhenhua Gu\|
10	Enantioselective Synthesis of Atropisomeric Vinyl Arene Compounds by Palladium Catalysis: A Carbene Strategy	期刊论文	Jia Feng\|Bin Li\|Yun He\|Zhenhua Gu\|
11	Stereoselective Synthesis of 1,3-Amino Alcohols by the Pd-Catalyzed Cyclization of Trichloroacetimidates	期刊论文	Yuanzhen Xie\|Kai Yu\|Zhenhua Gu\|
12	A Catalyst-Free Synthesis of Phosphinic Amides Using O？Benzoylhydroxylamines	期刊论文	Rui Zhu\|Chongqing Pan\|Zhenhua Gu\|
13	Palladium-Catalyzed Catellani ortho-Acylation Reaction: An Efficient and Regiospecific Synthesis of Diaryl Ketones	期刊论文	Yunze Huang\|Rui Zhu\|Kun Zhao\|Zhenhua Gu\|
14	Pd-Catalyzed Heck-Type Cascade Reactions with N-Tosyl Hydrazones: An Efficient Way to Alkenes via in Situ Generated Alkylpalladium	期刊论文	Xianglei Liu\|Xinna Ma\|Yunze Huang\|Zhenhua Gu\|
15	Palladium-catalyzed intramolecular Cp-H bond functionalization/arylation: an enantioselective approach to planar chiral quinilinoferrocenes	期刊论文	Xinna Ma\|Zhenhua Gu\|
16	Decarboxylative Alkynyl Termination of Palladium-Catalyzed Catellani Reaction: A Facile Synthesis of α？Alkynyl Anilines via Ortho C？H Amination and Alkynylation	期刊论文	Fenggang Sun\|Zhenhua Gu\|
17	N-Bromoacetamide-mediated domino cyclization and elimination of homoallylic trichloroacetimidates: a novel approach toward the synthesis of 1-bromo-2-amino-3-butene derivatives	期刊论文	Rui Zhu\|Kai Yu\|Zhenhua Gu\|
18	Palladium-Catalyzed Intramolecular Asymmetric C-H Functionalization/Cyclization Reaction of Metallocenes: An Efficient Approach toward the Synthesis of Planar Chiral Metallocene Compounds	期刊论文	Rui Zhu\|Bin Wang\|Yan-Biao Kang\|Zhenhua Gu\|
19	Pd-catalyzed Heck cyclization and in situ hydrocarboxylation or hydromethenylation via a hydrogen borrowing strategy	期刊论文	Xianglei Liu\|Zhenhua Gu\|
20	The palladium/norbornene-catalyzed ortho-silylmethylation reaction: a practical protocol for ortho-functionalized one-carbon homologation of aryl iodides.	期刊论文	Xianwei Sui\|Linlin Ding\|Zhenhua Gu\|
21	Catalytically Asymmetric Pd/Norbornene Catalysis: Enantioselective Synthesis of (+)-Rhazinal, (+)-Rhazinilam, and (+)-Kopsiyunnanine C1-3	期刊论文	Shibo Xu\|Chongqing Pan\|Xianwei Sui\|Zhenhua Gu\|

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