氟离子诱导卤代缺电子烯烃与亲电试剂间的交叉反应研究

21172082
2011
B0108.新反应与新试剂
龚跃法
面上项目
教授
华中科技大学
60万元
卤代烯醛;缺电子烯烃;交叉偶联;不对称催化;四丁基氟化铵
2012-01-01到2015-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 2-酰基1-氯环丙基甲酸酯的立体选择性亲核取代与Mannich反应的串联反应 期刊论文 龚跃法|章敏|罗钒|
2 铜催化烯醛的对映选择性Henry反应和随后的碘环化：手性氮杂三环骨架的立体选择性构架 期刊论文 龚跃法|
3 Synthesis of 2,3,3a,4,5,6-Hexahydrobenzo[b]thiophene-3a-carbaldehydes via a Tandem Reaction of Cyclic beta-Thiocyanatoenals with Electron-Deficient Alkenes Triggered by Fluoride 期刊论文 Zhang, Min|Gong, Yuefa|
4 A highly chemo- and enantioselective nitroaldol reaction of haloenals: preparation of chiral functionalized allylic alcohols 期刊论文 Gu, Lianghu|Zhou, Yirong|Zhang, Jingli|Gong, Yuefa|
5 Camphor-derived C-1-symmetric chiral diamine organocatalysts for asymmetric Michael addition of nitroalkanes to enones 期刊论文 Zhou, Yirong|Liu, Qiang|Gong, Yuefa|
6 2-酰基-1-氯环丙基甲酸酯的高区域选择性取代与羟醛缩合的串联反应 期刊论文 龚跃法|章敏|郭军凯|
7 Stereoselective Cascade Formal Nucleophilic Substitution and Mannich Reaction of Ethyl 2-Aroyl-1-chlorocyclopropanecarboxylates 期刊论文 Zhang, Min|Luo, Fan|Gong, Yuefa|
8 Direct Vinylogous Aldol Reaction Triggered by Tetrabutylammonium Fluoride: A Highly Regioselective and Diastereoselective Addition of Cyclic beta-Haloenals to Aromatic Aldehydes 期刊论文 Zhang, Jingli|Gu, Lianghu|Gong, Yuefa|
9 通过二氯乙酸乙酯的MIRC反应和高区域选择性氟化两步合成1-氟环丙烷甲酸乙酯 期刊论文 龚跃法|
10 Highly Regioselective Cascade Formal Nucleophilic Substitution and Aldol Condensation of 2-Aroyl-1-chlorocyclopropanecarboxylic Esters 期刊论文 Zhang, Min|Guo, Junkai|Gong, Yuefa|
11 Asymmetric synthesis of 1,2,3-trisubstituted indanes via an enantioselective copper(II)-catalyzed asymmetric nitroaldol reaction followed by an intramolecular Michael cyclization 期刊论文 Yuan, Hongling|Hu, Junhao|Gong, Yuefa|
12 Copper-Catalyzed Enantioselective Henry Reaction of Enals and Subsequent Iodocyclization: Stereoselective Construction of Chiral Azatricyclic Frameworks 期刊论文 Zhou, Yirong|Zhu, Yuequan|Yan, Shaobai|Gong, Yuefa|
13 Synthesis of functionalized fulvenes: [3+2] annulation of ethyl alpha-chlorocyclopropaneformates with 1,3-dicarbonyl compounds 期刊论文 Zhu, Yuequan|Zhang, Min|Yuan, Hongling|Gong, Yuefa|
14 A Two-Step Sequence to Ethyl alpha-Fluorocyclopropanecarboxylates Through MIRC Reaction of Ethyl Dichloroacetate and Highly Regioselective Fluorination 期刊论文 Zhang, Min|Gong, Yuefa|Wang, Weizhou|
15 Tandem nucleophilic addition-intramolecular oxa-Michael reaction: Novel synthetic route to trifluoromethylated phthalans 期刊论文 Yuan, Hongling|Gong, Yuefa|
16 官能化富烯的合成：alpha-氯代环丙基甲酸酯与1,3-二羰基化合物间的【3+2】环化反应 期刊论文 龚跃法|朱月泉|章敏|袁红玲|
17 Cross-Coupling Reactions of Two Different Activated Alkenes through Tetrabutylammonium Fluoride (TBAF) Promoted Deprotonation/Activation Strategy: A Regioselective Construction of Quaternary Carbon Centers 期刊论文 Zhang, Jing-Li|Gong, Yue-Fa|
18 Organocatalytic asymmetric Michael addition of ethyl nitroacetate to enones using natural amino acids-derived C1-symmetric chiral primary–secondary diamines 期刊论文 Zhou, Yirong|Liu, Qiang|Gong, Yuefa|
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