经历卡宾中间体的炔烃不对称转化

21871096
2018
B0113.结构与反应机制
祝诗发
面上项目
教授
华南理工大学
66万元
卡宾;炔烃;反应机理;反应选择性;金属催化
2019-01-01到2022-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Deconstructive Reorganization: De Novo Synthesis of Hydroxylated Benzofuran 期刊论文 Ling Zhang;Tongxiang Cao;Huanfeng Jiang;Shifa Zhu
2 Gold-catalyzed generation of azafulvenium from an enyne sulfonamide: rapid access to fully substituted pyrroles 期刊论文 Feng Wu;Lianfen Chen;Yongdong Wang;Shifa Zhu
3 Catalytic regio- and stereoselective intermolecular [5+2] cycloaddition via conjugative activation of oxidopyrylium 期刊论文 Ling Zhang;Qiu Shi;Tongxiang Cao;Shifa Zhu
4 A Strategy To Obtain o-Naphthoquinone Methides: Ag(I)-Catalyzed Cyclization of Enynones for the Synthesis of Benzo[h]chromanes and Naphthopyryliums 期刊论文 Feng Wu;Shifa Zhu
5 1,4-Addition of o-naphthoquinone methides induced by silver-catalyzed cyclization of enynones: an approach to unsymmetrical triarylmethanes and benzo[f]chromenes 期刊论文 Wu Feng;Zhang Li;Zhu Shifa
6 Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation 期刊论文 Bo Yang;Shi-Jun Li;Yongdong Wang;Yu Lan;Shifa Zhu
7 Synergy of activating substrate and introducing C–H···O interaction to achieve Rh_2(II)-catalyzed asymmetric cycloisomerization of 1,n-enynes 期刊论文 Wu Rui;Chen Kai;Ma Jun;Yu Zhixiang;Zhu Shifa
8 Rapid Access to Oxabicyclo[2.2.2]octane Skeleton through Cu(I)‐Catalyzed Generation and Trapping of Vinyl‐. o. ‐quinodimethanes (. Vinyl‐. o. ‐QDMs. ). † 期刊论文 Hejiang Luo;Chuan He;Huanfeng Jiang;Shifa Zhu
9 Migratory insertion of copper-allenylidene from propargyl ester 期刊论文 Qinglin Yao;Boxiang Liu;Tongxiang Cao;Shifa Zhu
10 Rh2(ii)-catalyzed enantioselective intramolecular Büchner reaction and aromatic substitution of donor–donor carbenes 期刊论文 Dong Zhu;Tongxiang Cao;Kai Chen;Shifa Zhu
11 Cu-Catalyzed Carboboration of Acetylene with Michael Acceptors 期刊论文 Tairan Cheng;Boxiang Liu;Rui Wu;Shifa Zhu
12 儿茶酚类化合物及其制备方法和应用 专利 祝诗发;曹同祥;王永东;黄志鹏
13 Catalytic regio- and stereoselective intermolecular [5+2] cycloadditionviaconjugative activation of oxidopyrylium 期刊论文 Zhang Ling;Shi Qiu;Cao Tongxiang;Zhu Shifa
14 Rapid access to oxa-bridged bicyclic skeletons through gold-catalyzed tandem rearrangement reaction 期刊论文 Zhang Jiantao;Liao Zhehui;Chen Lianfen;Zhu Shifa
15 一种多取代吡咯化合物的制备方法 专利 祝诗发;吴烽;王永东;黄志鹏;陈莲芬
16 Construction of polycyclic bridged indene derivatives by a tandem 1,3-rearrangement/intramolecular Friedel–Crafts cyclization of propargyl acetates 期刊论文 Jiantao Zhang;Zhehui Liao;Lianfen Chen;Huanfeng Jiang;Shifa Zhu
17 De Novo Synthesis of α‐Oligo(arylfuran)s and Its Application in OLED as Hole‐Transporting Material 期刊论文 Zhuwen Wei;Yang Chen;Jianghui Wang;Tao Yang;Zujin Zhao;Shifa Zhu
18 Benzene-Free Synthesis of Multisubstituted Catechol via Oxidative Dearomatic Reorganization 期刊论文 Tongxiang Cao;Qiu Shi;Shifa Zhu
19 Diverse synthesis of C2-linked functionalized molecules via molecular glue strategy with acetylene 期刊论文 Bo Yang;Shaodong Lu;Yongdong Wang;Shifa Zhu
20 苯并呋喃类化合物的制备方法 专利 祝诗发;张玲;曹同祥;王永东;黄志鹏;杨波;吕少东
21 Trimerization of Acetylene and Alkene: Rapid Access to Polyenes 期刊论文 Boxiang Liu;Zhicong Lin;Yu Wang;Tairan Cheng;Tongxiang Cao;Shifa Zhu
22 Thiol-Yne click chemistry of acetylene-enabled macrocyclization. 期刊论文 Shiwei Lü;Zipeng Wang;Shifa Zhu
23 An efficient method to synthesize N/O, O-difluoroboron complexes from alkynes 期刊论文 Yanmei Chen;Zhehui Liao;Tongxiang Cao;Shifa Zhu
24 Copper-Catalyzed Asymmetric Synthesis of Bicyclo[3.n.1]alkenones 期刊论文 Zhehui Liao;Jiantao Zhang;Tongxiang Cao;Shifa Zhu
25 Domino Reaction between Nitrosoarenes and Ynenones for Catalyst-Free Preparation of Indanone-Fused Tetrahydroisoxazoles 期刊论文 Qiu Shaotong;Liang Renxiao;Wang Yongdong;Zhu Shifa
26 Construction of [2,5]-Furanophanes by Carbene-Mediated Alkynyl Migration Cyclization 期刊论文 Qiu Shi;Yang Chen;Tongxiang Cao;Shifa Zhu
27 Enynone-enabled migratory insertion and Schmittel cyclization cascade for the synthesis of furan-fused fluorenes 期刊论文 He Zhang;Tongxiang Cao;Hejiang Luo;Lianfen Chen;Shifa Zhu
28 Recent progress on donor and donor-donor carbenes 期刊论文 Zhu Dong;Chen Lianfen;Fan Hanlin;Yao Qinglin;Zhu Shifa
29 Construction of polycyclic bridged indene derivatives by a tandem 1,3-rearrangement/intramolecular Friedel-Crafts cyclization of propargyl acetates 期刊论文 Jiantao Zhang;Zhehui Liao;Lianfen Chen;Huanfeng Jiang;Shifa Zhu
30 Domino Reaction between Nitrosoarenes and Ynenones for Catalyst-Free Preparation of Indanone-Fused Tetrahydroisoxazoles 期刊论文 Shaotong Qiu;Renxiao Liang;Yongdong Wang;Shifa Zhu
31 Bottom-up modular synthesis of well-defined oligo(arylfuran)s 期刊论文 Yang Chen;Pingchuan Shen;Tongxiang Cao;Hao Chen;Zujin Zhao;Shifa Zhu
32 Rapid Access to Oxa‐Bridged Bicyclic Skeletons through Gold‐Catalyzed Tandem Rearrangement Reaction 期刊论文 Jiantao Zhang;Zhehui Liao;Lianfen Chen;Shifa Zhu
33 Rh(II)-Catalyzed Enynal Cycloisomerization for the Generation of Vinyl Carbene: Divergent Access to Polycyclic Heterocycles 期刊论文 Rui Wu;Yang Chen;Shifa Zhu
34 Construction of Partially Protected Nonsymmetrical Biaryldiols via Semipinacol Rearrangement of o-NQM Derived from Enynones 期刊论文 Feng Wu;Tairan Cheng;Shifa Zhu
35 Regioselectivity‐Switchable Intramolecular Hydroarylation of Ynone 期刊论文 Feng Wu;Shiwei Lu;Shifa Zhu
36 Divergent synthesis of benzazepines and bridged polycycloalkanones via dearomative rearrangement 期刊论文 Qiu Shi;Zhehui Liao;Zhili Liu;Jiajia Wen;Chenguang Li;Jiamin He;Jiazhen Deng;Shan Cen;Tongxiang Cao;Jinming Zhou;Shifa Zhu
37 Enantioselective Rh(II)-Catalyzed Desymmetric Cycloisomerization of Diynes: Constructing Furan-Fused Dihydropiperidines with an Alkyne-Substituted Aza-Quaternary Stereocenter 期刊论文 Rui Wu;Jiajun Lu;Tongxiang Cao;Jun Ma;Kai Chen;Shifa Zhu
38 Dirhodium(ii)-catalysed cycloisomerization of azaenyne: rapid assembly of centrally and axially chiral isoindazole frameworks 期刊论文 Shaotong Qiu;Xiang Gao;Shifa Zhu
39 Catalyst-free synthesis of isoxazolidine from nitrosoarene and haloalkyne via a 1,2-halo-migration/[3 + 2] cycloaddition cascade 期刊论文 Shaotong Qiu;Tongxiang Cao;Shifa Zhu
40 Gold-Catalyzed Enynal and Enynol Coupling by Selectively Steering Two Transient Vinyl-Gold Intermediates 期刊论文 Zipeng Wang;Tongxiang Cao;Shifa Zhu
41 TEMPO-Regulated Regio- and Stereoselective Cross-Dihalogenation with Dual Electrophilic X+ Reagents 期刊论文 Kong Yi;Cao Tongxiang;Zhu Shifa
42 Divergent Synthesis of Ketone-Fused Indoles/Pyrroles via Metal-Guided Friedel-Crafts Cyclization 期刊论文 Hejiang Luo;Tongxiang Cao;Shifa Zhu
43 一种半棉酚、棉酚及它们的类似物的合成方法 专利 祝诗发;曹同祥;王永东;黄志鹏
44 具有生物活性的多取代苯化合物及其制备方法和应用 专利 祝诗发;曹同祥;王永东;黄志鹏
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