基于金属促进的化学键活化的有机合成方法学研究

20632010
2006
B0108.新反应与新试剂
席振峰
重点项目
教授
北京大学
190万元
方法学;有机合成;选择性;化学键活化;金属有机化合物
2007-01-01到2010-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Synthetic Methods for Multiply Substituted Butadiene-containing Building Blocks 期刊论文
2 Co-operative effect of Lewis acids with transition metals for organic synthesis 期刊论文
3 Highly Enantioselective and Organocatalytic (-Amination of 2-Oxindoles 期刊论文
4 Skeletal rearrangement of all-carbon spiro skeletons mediated by Lewis acid 期刊论文
5 In(III)-Catalyzed tandem reaction of chromone-derived Morita–Baylis–Hillman alcohols with amines 期刊论文
6 Three-Component Barbier Allylation, Friedel–Crafts Alkylation and Intramolecular Hydroalkoxylation in an Ionic Liquid for the Direct Synthesis of 4-Arylchromans 期刊论文
7 A Highly (-Regioselective AgOTf-Catalyzed Nucleophilic Substitution of the Baylis-Hillman Acetates with Indoles 期刊论文
8 Zirconium- and Silicon-Containing Intermediates with Three Fused Rings in a Zirconocene-Mediated Intermolecular Coupling Reaction 期刊论文
9 Formation of α-Lithio Siloles from Silylated 1,4-Dilithio-1,3-butadienes: Mechanism and Applications 期刊论文
10 An Organocatalytic, (-Regioselective, and Highly Enantioselective Nucleophilic Substitution of Cyclic Morita–Baylis–Hillman Alcohols with Indoles 期刊论文
11 A mild and efficient C-3 allylic alkylation of indoles catalyzed by FeCl3 期刊论文
12 Organocatalytic enantioselective Friedel–Crafts alkylation of simple phenols with trifluoropyruvate 期刊论文
13 Synthesis and Reactivity of 2H-Pyran Moiety in [60]Fullerene Cage Skeleton 期刊论文
14 Tunable and Highly Regio- and Diastereoselective Vinylogous Mannich-Type Reaction of Dioxinone-Derived Silyl Dienolate 期刊论文
15 Isolation and X-ray Structure of a Trimeric 1,4-Dilithio-1, 3-butadiene and a Dimeric Me3Si-substituted 1,4-dilithio-1,3-butadiene 期刊论文
16 Efficient One-pot Synthesis of N-Containing Heterocycles by Multi-Component Coupling of Silicon-tethered Diynes, Nitriles and Isocyanides via Intramolecular Cyclization of Iminoacyl-Zr Intermediates 期刊论文
17 Enantioselective Organocatalytic anti-Mannich-Type Reaction of N-Unprotected 3-Substituted 2-Oxindoles with Aromatic N-Ts Aldimines 期刊论文
18 TfOH-catalyzed allylation of alkynes with cyclic Baylis–Hillman alcohols 期刊论文
19 Reactivity of fullerene epoxide: Preparation of fullerene-fused thiirane, tetrahydrothiazolidin-2-one, and 1,3-dioxolane 期刊论文
20 Synthesis of Multiply Substituted Alkylidene Silacyclohexadiene Derivatives via Palladium-Catalyzed Insertion of Alkynes into Alkylidene Silacyclobutenes 期刊论文
21 Selective Synthesis of Multiply Substituted 7-Norbornenone Derivatives or Diels-Alder Cycloadducts from 1,2,3,4-Tetrasubstituted 1,3-Butadienes and Maleic Anhydride with or without Lewis Acids 期刊论文
22 Catalytic and asymmetric Friedel–Crafts alkylation of indoles with nitroacrylates. Application to the synthesis of tryptophan analogues 期刊论文
23 Calix[n]arene sulfonic acids bearing pendant aliphatic chains as recyclable surfactant-type Br?nsted acid catalysts for allylic alkylation with allyl alcohols in water 期刊论文
24 Facile Construction of Polycyclic Frameworks via a Synergistic Strategy Combining the Diels-Alder Reaction, Ene Reaction and Allylation Reaction in One-pot 期刊论文
25 硅杂四元环化合物的合成和反应 期刊论文
26 “水上” (“on water”) 有机反应 期刊论文
27 Switchable Open-Cage Fullerene for Water Encapsulation 期刊论文
28 One-pot Selective Synthesis of 5-Azaindoles via Zirconocene-Mediated Multi-Component Reaction of Three Different Nitriles and One Alkyne 期刊论文
29 InCl3–Catalyzed Propargylation of Indoles and Phenols with Propargylic Acetates: Application to the Syntheses of Benzofurans and Naphthofurans 期刊论文
30 An Efficient Synthetic Method to Nonnatural (- and β-Tryptophan Analogues via Friedel-Crafts Alkylation of Indoles with Nitroacrylates 期刊论文
31 Star-shaped Silacyclobutene-Containing π-Systems: Synthesis and Optical Properties 期刊论文
32 Pyranylidene Carbene Complexes from 1-Lithio-1,3-Dienes and M(CO)6 (M = Cr, Mo,W):Novel Synthesis and De-metallation reaction 期刊论文
33 One-pot Multi-Component Synthesis of Azaindoles and Pyrroles from One Molecule of Si-Tethered Diyne and Three or Two Molecules of Organonitriles Mediated by Zirconocence 期刊论文
34 Lithio Siloles: Facile Synthesis and Applications 期刊论文
35 Tandem allylic amination/ring-opening/oxa-Michael addition reactions of chromone-derived Morita-Baylis-Hillman acetates with amines 期刊论文
36 Triflic acid-catalyzed Michael reactions of indole and pyrrole compounds with (,(-unsaturated ketones in water 期刊论文
37 Preparation of Open-Cage Fullerenes and Incorporation of Small Molecules Through Their Orifices 期刊论文
38 Highly diastereoselective reactions of 2-lithiated indoles with chiral N-tert-butanesulfinyl aldimines for the synthesis of chiral (2-indolyl) methanamine derivatives 期刊论文
39 An efficient one-pot reaction of indoles, nitroacetate, and paraformaldehyde for the synthesis of tryptophan derivatives 期刊论文
40 Highly enantioselective Michael additions of a-cyanoacetate with chalcones catalyzed by bifunctional cinchona-derived thiourea organocatalyst 期刊论文
41 Preparation of fullerenol, fullerenone and aminofullerene derivatives through selective cleavage of fullerene C-H, C-C, C-N and C-O bonds in fullerene-mixed peroxide derivative 期刊论文
42 Alkyl Aluminum Catalyzed Addition of Amines to Carbodiimides: A Highly Efficient Route to Substituted Guanidines 期刊论文
43 Towards the rational synthesis of norfullerenes. Controlled deletion of one carbon atom from C-60 and preparation of 2,5,9-trioxo-1-nor(C60-Ih)[5,6]fullerene C59(O)3 derivatives 期刊论文
44 The Chemistry of Open-cage Fullerene, Hydroxylamine Mediated Hole-closing and -opening Reactions 期刊论文
45 Preparation of Azafullerene Derivatives from Fullerene-mixed Peroxides and Single Crystal X-Ray Structures of Azafulleroid and Azafullerene 期刊论文
46 1-Zircona-2-cyclohexenes: Novel Synthesis and Preliminary Reactions 期刊论文
47 Facile Synthesis of δ-Amino-β-ketoesters and Piperidinediones via a Vinylogous Mannich-Type Reaction of Brassard-Type Diene with Aldimines without Catalyst 期刊论文
48 Synthesis of Fullerene Oxides Containing Both 6,6-Closed Epoxide and 5,6-Open Ether Moieties through Thermolysis of Fullerene Peroxides 期刊论文
49 A highly (-regioselective In(OTf)3-catalyzed N-nucleophilic substitution of cyclic Baylis–Hillman adducts with aromatic amines 期刊论文
50 Catalyst-free tandem Michael addition-cyclization reactions in aqueous media for the synthesis of benzimidazo[1,2-a]pyrimidinone derivatives 期刊论文
51 Tunably Regioselective Control of Iodine-Catalyzed Allylic Substitution of Cyclic Baylis-Hillman Adducts with Indoles 期刊论文
52 Carving two adjacent holes on [60]fullerene through two consecutive epoxide to diol to dione transformations 期刊论文
53 Hydride-induced Novel Cyclization of Dienedinitriles Leading to Multi-functionalized Cyclopentadienes 期刊论文
54 Organo-di-lithio Reagents: Reaction and Synthetic Applications 期刊论文
55 Synthesis of [59]Fullerenones through Peroxide-Mediated Stepwise Cleavage of Fullerene Skeleton Bonds and X-ray Structures of Their Water-Encapsulated Open-Cage Complexes 期刊论文
56 Efficient One-Pot Synthesis of?2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur and Carbodiimides 期刊论文
57 TFA-Mediated Tandem Friedel-Crafts Alkylation/Cyclization/Hydrogen Transfer Process for the Synthesis of Flavylium Compound 期刊论文
58 Efficient Construction of Pyrazolo[1,5-a]pyrimidine Scaffold and its Exploration as a New Heterocyclic Fluorescent Platform 期刊论文
59 Iodine-catalyzed allylation and propargylation of indoles with allylic and propargylic acetates 期刊论文
60 Asymmetric organocatalytic N-nitroso aldol reaction of oxindoles 期刊论文
61 Efficient Synthesis of Benzimidazo[1,2-a]pyrimidinone Derivatives via Catalyst-Free Reactions of Baylis-Hillman Acetates, Alcohols, and Amines with 2-Aminobenzimidazole 期刊论文
62 Three-component Barbier Allylation-Friedel-Crafts Alkylation Promoted by BuPyCl/SnCl2?2H2O: Application to the Synthesis of 4-(Substituted phenyl)chromans 期刊论文
63 Isolation, Structural Characterization and Synthetic Application of Oxy-cyclopentadienyl Dianions 期刊论文
64 Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C60–Br bond 期刊论文
65 Cleavage and Re-organization of Zr-C/Si-C Bonds Leading to Zr/Si-N Organometallic and Heterocyclic Compounds 期刊论文
66 1-Lithio-1,3-dienes as Useful Building Blocks in Organic Synthesis 期刊论文
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