新型高效过渡金属催化剂与烯烃结构可控聚合

21234006
2012
B0109.高分子合成
李悦生
重点项目
教授
天津大学
320万元
催化剂;功能化;长链支化;超支化;烯烃聚合
2013-01-01到2017-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Copolymerization of propylene with Si-containing alpha,omega-diolefins:how steric hindrance of diolefins affects long chain branch formation 期刊论文 王彬;张一鸣;马哲;潘莉;于世钧;李悦生
2 Living syndiospecific polymerization of propylene with sterically encumbered titanium complexes activated by MMAO 期刊论文 Long Ying-Yun;Wang Yong-Xia;Li Bai-Xiang;Li Yan-Guo;Li Yue-Sheng
3 Synthesis of Cyclic Olefin Polymers with High Glass Transition Temperature by Ring-Opening Metathesis Copolymerization and Subsequent Hydrogenation 期刊论文 Yang Ji-Xing;Cui Jing;Long Ying-Yun;Li Yan-Guo;Li Yue-Sheng
4 Preparation of novel cyclic olefin copolymer with high glass transition temperature 期刊论文 Hong Miao;Yang Guo-Fan;Long Ying-Yun;Yu Shijun;Li Yue-Sheng
5 一种含铵根离子的等规聚丙烯离聚体及制备方法 专利 李悦生;孟晴晴
6 功能性等规聚丙烯及其制备方法 专利 王晓艳;李彦国;李悦生
7 吡啶亚胺(胺)钒烯烃聚合催化剂(英文) 期刊论文 王家宝;穆红亮;李悦生
8 Synthesis and characterization of novel chromium complexes based on beta-enaminoketonato ligands and their application to ethylene polymerization 期刊论文 Liu Jing-Yu;Tao Ping;Li Yue-Sheng
9 Ring-opening Metathesis Polymerization of Cis-5-norbornene-endo-2,3- dicarboxylic Anhydride Derivatives Using the Grubbs Third Generation Catalyst 期刊论文 杨继兴;任丽霞;李悦生
10 Novel zirconium complexes with constrained cyclic beta-enaminoketonatoligands: improved catalytic capability toward ethylene polymerization 期刊论文 王凯梯;王永霞;王彬;李彦国;李悦生
11 一种环烯烃聚合物及其制备方法 专利 李彦国;王彬;李悦生;刘三荣;崔磊
12 Synthesis of high performance cyclic olefin polymers (COPs) with ester groupvia ring-opening metathesis polymerization 期刊论文 崔静;杨继兴;李彦国;李悦生
13 一种环烯烃共聚物及其制备方法 专利 李悦生;李彦国;杨继兴;崔 磊;王永霞;穆红亮
14 Synthesis of Novel Cyclic Olefin Polymers with Excellent Transparency and High Glass-transition Temperature via Gradient Copolymerization of Bulky Cyclic Olefin and cis-Cyclooctene 期刊论文 Yang Ji-Xing;Cui Jing;Long Ying-Yun;Li Yan-Guo;Li Yue-Sheng
15 New Half-Sandwich Chromium(III) Complexes Bearing Phenoxy-Phosphine (Oxide) [O,P(= O)] Ligands: Synthesis, Structures, and Catalytic Properties for Ethylene (Co)Polymerization 期刊论文 Tao Ping;Mu Hong-Liang;Liu Jing-Yu;Li Yue-Sheng
16 Syntheses of Well-Defined Functional Isotactic Polypropylenes via Efficient Copolymerization of Propylene with omega-Halo-alpha-alkenes by Post-metallocene Hafnium Catalyst 期刊论文 Wang Xiaoyan;Wang Yongxia;Shi Xincui;Liu Jingyu;Chen Changle;Li Yuesheng
17 Ethylene polymerization and ethylene/hexene copolymerizaion with vandium catalysts bearing thiophenolphosphine ligands 期刊论文 Zhang Sen-wang;Li Yan-guo;Lu Ling-pan;Li Yue-sheng
18 一种环烯烃共聚物及其制备方法 专利 李悦生;杨继兴;李彦国;穆红亮;刘三荣;崔磊
19 Well-defined phosphino-phenolate neutral nickel(II) catalysts for efficient (co)polymerization of norbornene and ethylene 期刊论文 Zhang Yan-Ping;Li Wei-Wei;Li Bai-Xiang;Mu Hong-Liang;Li Yue-Sheng
20 一种环烯烃共聚物及其制备方法 专利 李悦生;杨继兴;李彦国;崔磊;刘三荣;刘靖宇
21 一种环烯烃共聚物及其制备方法 专利 李彦国;杨继兴;李悦生;刘三荣;崔磊
22 一种极性环烯烃共聚物及其制备方法 专利 李悦生;崔静
23 Featured Crystallization Polymorphism and Memory Effect in Novel Butene-1/1,5-Hexadiene Copolymers Synthesized by Post- Metallocene Hafnium Catalyst 期刊论文 贺蕾蕾;王彬;杨飞;李悦生;马哲
24 Neutral Nickel Catalysts for Olefin Homo- and Copolymerization: Relationships between Catalyst Structures and Catalytic Properties 期刊论文 穆洪亮;潘莉;宋东坡;李悦生
25 Cyclopolymerization of Si-Containing alpha,omega-Diolefins by a Pyridylamidohafnium Catalyst with High Cyclization Selectivity and Stereoselectivity 期刊论文 Wang Bin;Wang Yong-Xia;Cui Jing;Long Ying-Yun;Li Yan-Guo;Yuan Xiao-Yan;Li Yue-Sheng
26 高分子材料合成 专著 李悦生;刘晓辉;李晓芳
27 水杨醛亚胺钒(Ⅲ)化合物催化乙烯聚合反应机理(英文) 期刊论文 王永霞;左明辉;李悦生
28 Ligand steric hindrance and electronic effects on b-enaminoketonato half-sandwich chromium(III) olefin polymerization catalysts 期刊论文 陶平;刘靖宇;李悦生;李彦国
29 Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of (Arylimido)Vanadium(V) Complexes Bearing Tridentate Schiff Base Ligands 期刊论文 卢令攀;王家宝;刘靖宇;李悦生
30 一种透明、高耐热环烯烃共聚物及其制备方法 专利 李悦生;崔磊;李彦国;王永霞;穆红亮
31 聚丙烯接枝己内酯型增容剂的合成及其共混增容应用 期刊论文 朱健;王晓艳;刘靖宇;童跃进;李悦生
32 Novel imidazolium-based poly(ionic liquid)s with different counterions for self-healing 期刊论文 崔静;聂凤敏;杨继兴;潘莉;马哲;李悦生
33 Theoretical investigation of the mechanism of ethylene polymerization with salicylaldiminato vanadium(III) complexes 期刊论文 王永霞;左明辉;李悦生
34 Introduction of Constrained Cyclic Skeleton into β-Enaminoketonato Vanadium Complexes: A Strategy for Stabilization of Active Centre of Vanadium Catalyst for Ethylene Polymerization 期刊论文 王凯悌;王永霞;王彬;李彦国;李悦生
35 Synthesis and Reaction of Anthracene-Containing Polypropylene: A Promising Strategy for Facile, Efficient Functionalization of Isotactic Polypropylene 期刊论文 张德广;潘莉;李彦国;王彬;李悦生
36 Convenient Syntheses and Versatile Functionalizations of Isotactic Polypropylene Containing Plentiful Pendant Styrene Groups with High Efficiency 期刊论文 Wang Xiao-Yan;Wang Yong-Xia;Li Yue-Sheng;Pan Li
37 环烯烃共聚物及其制备方法 专利 李彦国;崔磊;李悦生;王永霞;穆红亮
38 一种聚烯烃/聚酯嵌段共聚物及其制备方法 专利 李悦生;杨飞;潘莉
39 含铵根离子等规聚丙烯离聚体的合成及性能研究 期刊论文 孟晴晴;王彬;潘莉;李悦生;马哲
40 Efficient copolymerization of ethylene with norbornene or its derivatives using halfmetallocene zirconium(IV) catalysts 期刊论文 李玉莲;杨继兴;王彬;李悦生
41 一种催化乙烯与降冰片烯共聚合的方法 专利 李悦生;潘莉;王彬;杨继兴
42 Synthesis and characterization of fluoro-substituted beta-enaminoketonato titanium complexes and their catalytic behavior of regioselective ethylene/cyclopentadiene copolymerization 期刊论文 Li Yan-guo;Hong Miao;Zhang Gui-bao;Li Yue-sheng
43 Efficient synthesis of diverse well-defined functional polypropylenes with high molecular weights and high functional group contents via thiol-halogen click chemistry 期刊论文 Wang Xiao-Yan;Li Yan-Guo;Mu Hong-Liang;Pan Li;Li Yue-Sheng
44 Non-porous ultra low dielectric constant materials based on novel silicon-containing cycloolefin copolymers with tunable performance 期刊论文 王彬;商睿凝;马哲;潘莉;李悦生
45 Synthesis and characterization of phosphine( thio)phenolate-based half-zirconocenes and their application in ethylene (co-)polymerization 期刊论文 Tang Xiao-Yan;Long Ying-Yun;Wang Yong-Xia;Liu Jing-Yu;Li Yue-Sheng
46 [ONN]-type amine pyridine(s) phenolate-based oxovanadium(v) catalysts for ethylene homo- and copolymerization 期刊论文 Wang Jia-Bao;Lu Ling-Pan;Liu Jing-Yu;Li Yue-Sheng
47 Novel Vanadium(III) Complexes with Tridentate Phenoxy-Phosphine [O,P(=O),O] Ligands: Synthesis, Characterization, and Catalytic Behavior of Ethylene Polymerization and Copolymerization with 10-Undecen-1-ol 期刊论文 Zhang Sen-Wang;Zhang Gui-Bao;Lu Ling-Pan;Li Yue-Sheng
48 [O(S),O=P]型配体修饰的单氯单茂锆催化剂的高温乙烯聚合 期刊论文 刘三荣;刘靖宇;李悦生
49 Insights into Propylene/w-halo-a-alkenes copolymerizationpromoted by rac-Et(Ind)2ZrCl2 and (pyridyl-amido)hafnium catalysts 期刊论文 王晓艳;王永霞;龙映云;李悦生
50 Theoretical investigation of the mechanism of ethylene polymerization with salicylaldiminato vanadium(III) complexes 期刊论文 Wang Yongxia;Zuo Minghui;Li Yuesheng
51 Cyclic olefin copolymers of propylene with asymmetric Si-containing alpha,omega-diolefins: The tailored thermal and mechanical properties 期刊论文 Wang Bin;Long Ying-Yun;Li Yan-Guo;Men Yong-Feng;Li Yue-Sheng
52 大位阻中性镍催化剂及制备方法和制备乙烯/极性单体共聚物的应用 专利 李悦生;张艳平;穆红亮
53 Article Facile, Efficient Copolymerization of Ethylene with Norbornene-Containing Dienes Promoted by Single Site Non-Metallocene Oxovanadium(V) Catalytic System 期刊论文 王凯悌;王家宝;李彦国;潘莉;李悦生
54 Synthesis of Novel Cyclic Olefin Polymer with High Glass Transition Temperature via Ring-Opening Metathesis Polymerization 期刊论文 崔静;杨继兴;潘莉;李悦生
55 [ONNO]-type oxovanadium(V) complexes containing amine pyridine bis(phenolate) ligands: synthesis, characterization and catalytic behavior for ethylene (co)polymerization 期刊论文 Wang Jia-Bao;Lu Ling-Pan;Liu Jing-Yu;Mu Hong-liang;Li Yue-Sheng
56 Ethylene Polymerization and Ethylene/Hexene Copolymerization by Vanadium(III) Complexes Bearing Bidentate Phenoxy-Phosphine Oxide Ligands 期刊论文 Zhang Sen-Wang;Lu Ling-Pan;Long Ying-Yun;Li Yue-Sheng
57 一种环烯烃共聚物及其制备方法 专利 李悦生;杨继兴;李彦国;刘三荣;崔磊;穆红亮
58 Spontaneously healable thermoplastic elastomers achieved through one-pot livingring-opening metathesis copolymerization of well-designed bulky monomers 期刊论文 杨继兴;龙映云;潘莉;门永锋;李悦生
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