环境友好型多金属氧簇的结构设计与催化特性

21231002
2012
B0104.无机合成
胡长文
重点项目
教授
北京理工大学
320万元
光催化分解水;氧化脱硫;结构设计;C-H键活化;多金属氧簇
2013-01-01到2017-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 MgO modified nanoporous carbon composites for methanol separation 期刊论文 Xiaoyu Ma;Minhua Cao;Changwen Hu
2 Melamine-based mesoporous organic polymers as metal-Free heterogeneous catalyst: Effect of hydroxyl on CO2 capture and conversion 期刊论文 Nan Zhang;Bo Zou;Guoping Yang;Bing Yu;Changwen Hu
3 Polyoxometalate-Modified Sponge-Like Graphene Oxide Monolith with High Proton-Conducting Performance 期刊论文 Yiwei Liu;Shumei Liu;Xuying Lai;Jun Miao;Danfeng He;Ning Li;Fang luo;Zhan Shi;Shuxia Liu
4 Binary Pd- Polyoxometalates and Isolation of a Ternary Pd- V- Polyoxomolybdate Active Species for Selective Aerobic Oxidation of Alcohols 期刊论文 Huang Xianqiang;Zhang Xiaomei;Zhang Dan;Yang Song;Feng Xiao;Li Jikun;Lin Zhengguo;Cao Jie;Pan Ran;Chi Yingnan;Wang Bo;Hu Changwen
5 Probing the Self-Assembly Mechanism of Lanthanide-Containing Sandwich-Type Silicotungstates [{Ln(H2O)n}2{Mn4(B-α-SiW9O34)2(H2O)2}]6− Using Time-Resolved Mass Spectrometry and X‑ray Crystallography 期刊论文 Linyuan Fan;Zhengguo Lin;Jie Cao;Changwen Hu
6 Three Pd-decavanadates with a controllable molar ratio of Pd to decavanadate and their heterogeneous aerobic oxidation of benzylic C–H bonds 期刊论文 Xianqiang Huang;Jikun Li;Guodong Shen;Nana Xin;Zhengguo Lin;Yingnan Chi;Jianmin Dao;Dacheng Li;Changwen Hu
7 ZnCr Layered Double Hydroxide (LDH) Nanosheets Assisted Formation of Hierarchical Flower-Like CdZnS@LDH Microstructures with Improved Visible-Light-Driven H2 Production 期刊论文 Lihua Yao;Ding Wei;Dongpeng Yan;Changwen Hu
8 Organic-functionalized, substituted polyoxovanadium and vanadoniobates: Synthesis, structure and application 期刊论文 Yuanzhe Gao;Yingnan Chi;Changwen Hu
9 Planar {Ni6} Cluster-Containing Polyoxometalate-based Inorganic−Organic Hybrid Compound and Its Extended Structure 期刊论文 Xingquan Wang;Shuxia Liu;Yiwei Liu;Danfeng He;Ning Li;Jun Miao;Yujuan Ji;Guoyu Yang
10 Band Gap Engineering of In2TiO5 for H2 Production under Near-infrared Light 期刊论文 Ding Wei;Lihua Yao;Song Yang;Zhentao Cui;Bingxue Wei;Minhua Cao;Changwen Hu
11 Nitrogen-doped porous carbon monolith as a highly efficient catalyst for CO2 conversion 期刊论文 Xiaoyu Ma;Bo Zou;Minhua Cao;Shilu Chen;Changwen Hu
12 Cation Sensing by a Luminescent Metal−Organic Framework with Multiple Lewis Basic Sites 期刊论文 Qun Tang;Shuxia Liu;Yiwei Liu;Jun Miao;Shujun Li;Li Zhang;Zhan Shi;Zhiping Zheng
13 {Ta12}/{Ta16} Cluster-Containing Polytantalotungstates with Remarkable Photocatalytic H2 Evolution Activity 期刊论文 Shujun Li;Shumei Liu;Shuxia Liu;Yiwei Liu;Qun Tang;Zhan Shi;Shuxin Ouyang;Jinhua Ye
14 Facile fabrication of InSe nanosheets: towards efficient visible-light-driven H2 production by coupling with P25 期刊论文 Ding Wei;Lihua Yao;Song Yang;Jufang Hu;Minhua Cao;Changwen Hu
15 White-light emission by selectively encapsulating single lanthanide metal ions into alkaline earth metal-organic coordination polymers 期刊论文 Danfeng He;Qun Tang;Shumei Liu;Fang Luo;Yiwei Liu;Ning Li;Jun Miao;Xingquan Wang;Xugang Chen;Fengji Ma;Shuxia Liu
16 瑞巴派特共晶的制备方法 专利 胡长文;王晓莹;迟瑛楠;王晓鸽;马承伟
17 Photo-reduction assisted synthesis ofW-doped TiO2coupled with Au nanoparticles for highly efficient photocatalytic hydrogen evolution 期刊论文 Bing Liu;Shuangyue Su;Wenhui Zhou;Yin Wang;Ding Wei;Lihua Yao;Yuanman Ni;Minhua Cao;Changwen Hu
18 产氢活性的钽钨混配型多金属氧酸盐光催化剂及其制备方法 专利 刘术侠;李书军;刘艺伟
19 Controllable proton-conducting pathways via situating polyoxometalates in targeting pores of a metal–organic framework 期刊论文 Xuying Lai;Yiwei Liu;Guocheng Yang;Shumei Liu;Zhan Shi;Ying Lu;Fang Luo;Shuxia Liu
20 Assembly of Cu/Ag-quinoxaline-polyoxotungstate hybrids: Influence of Keggin and Wells–Dawson polyanions on the structure 期刊论文 Yingnan Chi;Fengyun Cui;Zhengguo Lin;Yan Xu;Xiaoyu Ma;Panpan Shen;Kunlin Huang;Changwen Hu
21 Color Tuning and White Light Emission via in Situ Doping of Luminescent Lanthanide Metal−Organic Frameworks 期刊论文 Qun Tang;Shuxia Liu;Yiwei Liu;Danfeng He;Jun Miao;Xingqun wang;Yujuan Ji;Zhiping Zhang
22 An arsenicniobate-based 3D framework with selective adsorption and anion-exchange properties 期刊论文 Ning Li;Yiwei Liu;Ying Lu;Danfeng he;Shumei Liu;Xingquan Wang;Yangguang Li;Shuxia Liu
23 Facile formation of 2D Co2P@Co3O4 microsheets through in-situ toptactic conversion and surface corrosion: Bifunctional electrocatalysts towards overall water splitting 期刊论文 Lihua Yao;Nan Zhang;Yin Wang;Yuanman Ni;Dongpeng Yan;Changwen Hu
24 A novel activating strategy to achieve highly porous carbon monoliths for CO2 capture 期刊论文 Xiaoyu Ma;Yao Li;Minhua Cao;Changwen Hu
25 一种2-噁唑啉酮衍生物的制备方法 专利 胡长文;於兵;程彬彬
26 Highly efficient conversion of CO2 at atmospheric pressure to cyclic carbonates with in situ-generated homogeneous catalysts from a copper-containing coordination polymer 期刊论文 Bo Zou;Liang Hao;Linyuan Fan;Zhiming Gao;Shilu Chen;Hui Li;Changwen Hu
27 Surface localization of CdZnS quantum dots onto 2D g-C3N4 ultrathin microribbons: Highly efficient visible light-induced H2-generation 期刊论文 Lihua Yao;Ding Wei;Yuanman Ni;Dongpeng Yan;Changwen Hu
28 Synthesis, structure and characterization of three different dimension inorganic–organic hybrid vanadates: ijCo2IJmIM)5IJH2O)2]V4O12, ijNi2IJmIM)7IJH2O)]V4O12ĴH2O and ijCdIJeIM)2IJH2O)]V2O6 期刊论文 Shujun Wu;Xinhang Yang;Jufang Hu;Hongwei Ma;Zhengguo Lin;Changwen Hu
29 Sulfur-centred polyoxoniobate-based 3D organic–inorganic hybrid compound and its magnetic behavior magnetic behavior 期刊论文 Jufang Hu;Tian Han;Yingnan Chi;Zhengguo Lin;Yanqing Xu;Song Yang;Ding Wei;Yanzhen Zheng;Changwen Hu
30 Symmetry Breaking of α‑[H2W12O40]6− Depends on the Transformation of Isopolyoxotungstates 期刊论文 Yingnan Chi;Panpan Shen;Fengyun Cui;Zhengguo Lin;Shilu Chen;Changwen Hu
31 Controllable Synthesis, Characterization, and Catalytic Properties of Three Inorganic-Organic Hybrid Copper Vanadates in the Highly Selective Oxidation of Sulfides and Alcohols 期刊论文 Li Jikun;Huang Xianqiang;Yang Song;Xu Yanqing;Hu Changwen
32 An unprecedented polyoxometalate-based hybrid solid constructed from a neutral metal–organic macrocycle and Dawson polyoxotungstate anions 期刊论文 Yanqing Xu;Yuanzhe Gao;Wei Wei;Zhiqin Wang;Shan Li;Changwen Hu
33 A simple reduction process to synthesize MoO2/C composites with cage-like structure for high performance lithium-ion batteries 期刊论文 Bing Liu;Xinyu Zhao;Yuan Tian;Di Zhao;Changwen Hu;Minhua Cao
34 一类基于Keggin型多金属氧酸盐的离子液体及其合成方法 专利 刘术侠;蒋云霞;苗骏
35 Proton conductive watery channels constructed by Anderson polyanions and lanthanide coordination cations 期刊论文 Jun Miao;Yiwei Liu;Qun Tang;Danfeng He;Guocheng Yang;Zhan Shi;Shuxia Liu;Qingyin Wu
36 Three New Imidazole-Functionalized Hexanuclear Oxidovanadium Clusters with Exceptional Catalytic Oxidation Properties for Alcohols 期刊论文 Baokuan Chen;Xianqiang Huang;Bo Wang;Zhengguo Lin;Jufang Hu;Yingnan Chi;Changwen Hu
37 钯-钒-多金属氧簇单组份三活性中心催化剂的制备方法及应用 专利 胡长文;黄现强;张小梅;迟瑛楠;王博;李季坤
38 Improving water splitting performance of Cu2O through a synergistic ‘‘two-way transfer’’ process of Cu and graphene 期刊论文 Dingkun Zhang;Ding Wei;Zhentao Cui;Shanshan Wang;Song Yang;Minhua Cao;Changwen Hu
39 钯配合物-钼磷酸单组份双活性中心催化剂的制备方法及应用 专利 迟瑛楠;黄现强;胡长文;张小梅;王博
40 Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion 期刊论文 Xianqiang Huang;Yifa chen;Zhengguo Lin;Xiaoqian Ren;Yuna Song;Zhenzhu Xu;Xinmei Dong;Xingguo Li;Changwen Hu;Bo Wang
41 High Proton Conduction at above 100 °C Mediated by Hydrogen Bonding in a Lanthanide Metal−Organic Framework 期刊论文 Qun Tang;Yiwei Liu;Shuxia Liu;Danfeng He;Jun Miao;Xingquan Wang;Guocheng Yang;Zhan Shi;Zhiping Zhang
42 Borate-templated self-assembly of multinuclear nickel(II)-containing POMs 期刊论文 Shujun Li;Shuxia Liu;Qun Tang;Yiwei Liu;Danfeng He;Shengtian Wang;Zhan Shi
43 One-pot, low-temperature synthesis of self-doped NaTaO3 nanoclusters for visible-light-driven photocatalysis 期刊论文 Jianqiang Wang;Shuangyue Su;Bing Liu;Minhua Cao;Changwen Hu
44 Crystal Facets Make a Profound Difference in Polyoxometalate-Containing Metal-Organic Frameworks as Catalysts for Biodiesel Production 期刊论文 Liu Yiwei;Liu Shumei;He Danfeng;Li Ning;Ji Yujuan;Zheng Zhiping;Luo Fang;Liu Shuxia;Shi Zhan;Hu Changwen
45 Bifunctional HNO3 catalytic synthesis of N-doped porous carbons for CO2 capture 期刊论文 Xiaoyu Ma;Minhua Cao;Changwen Hu
46 Palladium-Catalyzed Decarboxylative Synthesis of Arylamines 期刊论文 Qipu Dai;Peihe Li;Nuannuan Ma;Changwen Hu
47 A newly-designed polyoxometalate-based plasmonic visible-light catalyst for the photodegradation of methyl blue 期刊论文 Wenhui Zhou;Minhua Cao;Shuangyue Su;Na Li;Xinyu Zhao;Jianqiang Wang;Xianghua Li;Changwen Hu
48 Construction of hierarchically porous graphitized carbon-supported NiFe layered double hydroxides with a core–shell structure as an enhanced electrocatalyst for the oxygen evolution reaction 期刊论文 Yuanman Ni;Lihua Yao;Yin Wang;Bing Liu;Minhua Cao;Changwen Hu
49 Aminated Graphene Oxide Impregnated with Photocatalytic Polyoxometalate for Effcient Adsorption of Dye Pollutants and Its Facile and Complete Photoregeneration 期刊论文 Yiwei Liu;Fang Luo;Shumei Liu;Shuxia Liu;Xuying Lai;Xiaohui Li;Ying Lu;Yangguang Li;Changwen Hu;Zhan Shi;Zhiping Zhang
50 Controlled Synthesis of Polyoxopalladates, and Their Gas-Phase Fragmentation Study by Electrospray Ionization Tandem Mass Spectrometry 期刊论文 Zhengguo Lin;Bo Wang;Jie Cao;Baokuan Chen;Cong Xu;Xianqiang Huang;Yanxuan Fan;Changwen Hu
51 Stable visible-light photocatalytic degradation of organic pollutant by silver salt of Ti-substituted Keggin-type polyoxotungstate 期刊论文 Shumei Liu;Yiwei Liu;Shaoping Jiang;Shuxia Liu;Danfeng He;Ning Li;Jun Miao;Jinhua Ye
52 钯配合物-钒取代钼磷酸单组分双活性中心催化剂的制备方法及应用 专利 迟瑛楠;黄现强;胡长文;张小梅;王博
53 Controllable Assembly of Vanadium-Containing Polyoxoniobate Based Three-Dimensional Organic−Inorganic Hybrid Compounds and Their Photocatalytic Properties 期刊论文 Jufang Hu;Yin wang;Xinning Zhang;Yingnan Chi;Song Yang;Jikun Li;Changwen Hu
54 Enhanced microwave absorbing performance of CoNi alloy nanoparticles anchored on a spherical carbon monolith 期刊论文 Na Li;Changwen Hu;Minhua Cao
55 Phase modulation of thermotropic liquid crystals of tetra-n-alkylammonium polyoxometalate ionic complexes 期刊论文 Yunxia Jiang;Shuxia Liu;Jing Zhang;Lixin Wu
56 A highly stable metal- and nitrogen-doped nanocomposite derived from Zn/Ni-ZIF-8 capable of CO2 capture and separation 期刊论文 Rui Li;Xiaoqian Ren;Xiao Feng;Xingguo Li;Changwen Hu;Bo Wang
57 A Polyoxoniobate–Polyoxovanadate Double-Anion Catalyst for Simultaneous Oxidative and Hydrolytic Decontamination of Chemical Warfare Agent Simulants 期刊论文 Jing Dong;Jufang Hu;Yingnan Chi;Zhengguo Lin;Bo Zou;Song Yang;Craig L. Hill;Changwen Hu
58 Immobilization of Keggin polyoxovanadoniobate in crystalline solids to produce effective heterogeneous catalysts towards selective oxidation of benzyl-alkanes 期刊论文 Jufang Hu;Jing Dong;Xianqiang Huang;Yingnan Chi;Zhengguo Lin;Jikun Li;Song Yang;Hongwei Ma;Changwen Hu
59 Facile Synthesis of a Nanocrystalline Metal–Organic Framework Impregnated with a Phosphovanadomolybdate and Its Remarkable Catalytic Performance in Ultradeep Oxidative Desulfurization 期刊论文 Yiwei Liu;Shumei Liu;Shuxia Liu;Dadong Liang;Shujun Li;Qun Tang;Xingquan Wang;Jun Miao;Zhan Shi;Zhiping Zhang
60 Vertically oriented CoO@FeOOH nanowire arrays anchored on carbon cloth as a highly efficient electrode for oxygen evolution reaction 期刊论文 Yin wang;Yuanman Ni;Bing Liu;Shuxia Shang;Song Yang;Minhua Cao;Changwen Hu
61 Magnetic and luminescence properties of an inorganic 3D nickel–vanadium bimetallic framework 期刊论文 Ning Li;Zhong Zhang;Yiwei Liu;Ying Lu;Danfeng He;Li Xu;Xiahua Zhong;Shuxia Liu
62 Design and synthesis of hybrid solids based on the tetravanadate core toward improved catalytic properties 期刊论文 Yanhong Niu;Song Yang;Jikun Li;Yanqing Xu;Changwen Hu
63 Recoverable amphiphilic polyoxoniobates catalyzing oxidative and hydrolytic decontamination of chemical warfare agent simulants in emulsion 期刊论文 Xiaoqin Li;Jing Dong;Huifang Liu;Xiangrong Sun;Yingnan Chi;Changwen Hu
64 In situ synthesis of a novel dioxidovanadium-based nickel complex as catalyst for deep oxidative desulfurization with molecular oxygen 期刊论文 Jikun Li;Yanqing Xu;Changwen Hu
65 Four Alkoxohexavanadate-Based Pd-Polyoxovanadates as Robust Heterogeneous Catalysts for Oxidation of Benzyl-Alkanes 期刊论文 Li Jikun;Huang Xianqiang;Yang Song;Ma Hongwei;Chi Yingnan;Hu Changwen
66 A new synthetic approach to functionalize oxomolybdenum complexes 期刊论文 Baokuan Chen;Zhengguo Lin;Bo Wang;Xiao Feng;Linyuan Fan;Song Yang;Xianqiang Huang;Changwen Hu
67 Controllable Synthesis of Lindqvist Alkoxopolyoxovanadate Clusters as Heterogeneous Catalysts for Sulfoxidation of Sulfides 期刊论文 Jikun Li;Jing Dong;Chuanping Wei;Song Yang;Yingnan Chi;Yanqin Xu;Changwen Hu
68 Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations 期刊论文 Zhengguo Lin;Linyuan Fan;Aleksandar Kondinski;Nina Vankova;Thomas Heine;Baokuan Chen;Ali Haider;Bo Wang;Ulrich Kortz;Changwen Hu
69 Polyoxometallates trapped in a zeolitic imidazolate framework leading to high uptake and selectivity of bioactive molecules 期刊论文 Rui Li;Xiaoqian Ren;Jingshu Zhao;Xiao Feng;Xin Jiang;Xinxin Fan;Zhengguo Lin;Xingguo Li;Changwen Hu;Bo Wang
70 Two chiral multinuclear palladium(II) complexes comprising alternately arranged isomerous hexanuclear clusters 期刊论文 Zhengguo Lin;Baokuan Chen;Xiao Feng;Bo Wang;Yingnan Chi;Yanxuan Fan;Xinhang Yang;Xianqiang Huang;Changwen Hu
71 A new supramolecular assembly composed of decatungstate polyanion and Cu/O/W heterometallic cluster 期刊论文 Panpan Shen;Yinnan Chi;Zhengguo Lin;Changwen Hu
72 Polyoxometalate-functionalized metal–organic frameworks with improved water retention and uniform proton-conducting pathways in three orthogonal directions 期刊论文 Yiwei Liu;Xiao Yang;Jun Miao;Qun Tang;Shumei Liu;Zhan Shi;Shuxia Liu
73 An UV equipped box for photoactivation with a fluorescent coordination polymer for recognizing amine gases by “turn-color” in air 期刊论文 Danfeng He;Yiwei Liu;Ying Lu;Shumei Liu;Xugang Chen;Ning Li;Fang Luo;Shuxia Liu
74 Assembly and spontaneous resolution of the chiral inorganic polyoxometalates-based frameworks via helical chains association 期刊论文 Qun Tang;Shuxia Liu;Yiwei Liu;Shujun Li;Fengji Ma;Jianxin Li;Shengtian Wang;Chengzhan Liu
75 A Vanadogermanate Dimer-Based Chain with Magnetic and Luminescent Properties 期刊论文 Ning Li;Danfeng He;Ying Lu;Yiwei Liu;Li Xu;Xiahua Zhong;Zehong Guo;Shuxia Liu
76 Germanium Quantum Dots Embedded in N-Doping Graphene Matrix with Sponge-Like Architecture for Enhanced Performance in Lithium-Ion Batteries 期刊论文 Jinwen Qin;Xia Wang;Minhua Cao;Changwen Hu
77 A Highly Symmetric Ionic Crystal Constructed by Polyoxoniobates and Cobalt Complexes for Preferential Water Uptake over Alcohols 期刊论文 Jufang Hu;Yanqing Xu;Dingkun Zhang;Baokuan Chen;Zhengguo Lin;Changwen Hu
78 担载型钒取代多酸脱硫催化剂多孔纳米晶及其制备方法 专利 刘术侠;梁大栋;刘艺伟
79 Facile fabrication of magnetically recyclable metal-organic framework nanocomposites for highly efficient and selective catalytic oxidation of benzylic C-H bonds 期刊论文 Chen Yifa;Huang Xianqiang;Feng Xiao;Li Jikun;Huang Yingyu;Zhao Jingshu;Guo Yuexin;Dong Xinmei;Han Ruodan;Qi Pengfei;Han Yuzhen;Li Haiwei;Hu Changwen;Wang Bo
80 Two-step fabrication of a porous In2Se3 tetragonal photocatalyst for water splitting 期刊论文 Ding Wei;Zhengguo Lin;Zhentao Cui;Shuangyue Su;Dingkun Zhang;Minhua Cao;Changwen Hu
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