新型功能化大环主体分子的合成、结构与超分子化学研究

21132005
2011
B0110.超分子化学
王梅祥
重点项目
教授
清华大学
300万元
分子识别;超分子化学;杂杯芳烃;大环化合物;分子组装
2012-01-01到2016-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Synthesis, Resolution, Structure, and Racemization of Inherently Chiral 1,3-Alternate Azacalix[4]pyrimidines: Quantification of Conformation Mobility 期刊论文 Wang, Li-Xia|Wang, De-Xian|Zhao, Liang|Wang, Mei-Xiang|
2 Construction of multiferrocenyl metallacycles and metallacages via coordination-driven self-assembly: from structure to functions 期刊论文 Xu, Lin|Wang, Yu-Xuan|Chen, Li-Jun|Yang, Hai-Bo|
3 Stimuli-Responsive Supramolecular Gels through Hierarchical Self-Assembly of Discrete Rhomboidal Metallacycles 期刊论文 Yang, Guang|Wang, De-Xian|Yu, Yihua|Yang, Hai-Bo|
4 Supramolecular Polymers Constructed through Self-sorting Host Guest Interactions 期刊论文 Wang, Xu-Qing|Wang, Wei|Wang, Yu-Xuan|Yang, Hai-Bo|
5 Construction of Supramolecular Pyrene-Modified Metallacycles via Coordination-Driven Self-Assembly and Their Spectroscopic Behavior 期刊论文 Han, Qing|Chen, Li-Jun|Xu, Lin|Yang, Hai-Bo|
6 Designed synthesis of size-tunable Ag2S nanoclusters via distinguishable C-S bond cleavage reaction of alkyl- and aryl-thiolates 期刊论文 He, Xin|Guo, Hui|Fu, Nan-Yan|Zhao, Liang|
7 Stabilization of a Reactive Polynuclear Silver Carbide Cluster through the Encapsulation within a Supramolecular Cage 期刊论文 Gao, Cai-Yan|Zhao, Liang|Wang, Mei-Xiang|
8 Synthesis, Structure, and Properties of O-6-Corona[3] arene[3]tetrazines 期刊论文 Guo, Qing-Hui|Fu, Zhan-Da|Zhao, Liang|Wang, Mei-Xiang|
9 Synthesis, structure and transition metal ion complexation property of lariat azacalix[4]pyridines 期刊论文 Yu-Fei Ao|De-Xian Wang|Liang Zhao|Mei-Xiang Wang|
10 Hierarchical self-assembly of a discrete hexagonal metallacycle into the ordered nanofibers and stimuli-responsive supramolecular gels 期刊论文 Ren, Yuan-Yuan|Li, Xiaopeng|Xu, Lin|Yang, Hai-Bo|
11 Construction of Smart Supramolecular Polymeric Hydrogels Cross linked by Discrete Organoplatinum(II) Metallacycles via Post Assembly Polymerization 期刊论文 Li, Xiaopeng|Liu, Minghua|Chen, Guosong|Yang, Hai-Bo|
12 Synthesis of trifluoromethylthiolated azacalix[1] arene[3]pyridines from the Cu(II)-mediated direct trifluoromethylthiolation reaction of arenes via reactive arylcopper(III) intermediates 期刊论文 Wang, Fei|Zhao, Liang|You, Jingsong|Wang, Mei-Xiang|
13 Recent progress in the construction of cavity-cored supramolecular metallodendrimers via coordination-driven self-assembly 期刊论文 Xu, Lin|Chen, Li-Jun|Yang, Hai-Bo|
14 Synthesis, Structure and Metal Binding Property of Internally 1,3-Arylene-Bridged Azacalix[6]aromatics 期刊论文 Fang, Yi-Xin|Zhao, Liang|Wang, De-Xian|Wang, Mei-Xiang|
15 Functionalization of Azacalixaromatics by Cu(II)-Catalyzed Oxidative Cross-Coupling Reaction between the Arene C-H Bond and Boronic Acids 期刊论文 Liu, Yang|Long, Chao|Zhao, Liang|Wang, Mei-Xiang|
16 Cu(ClO4)(2)-Mediated Arene C-H Bond Halogenations of Azacalixaromatics Using Alkali Metal Halides as Halogen Sources 期刊论文 Zhang, Hu|Wang, De-Xian|Zhao, Liang|Wang, Mei-Xiang|
17 Functionalized O-6-Corona[6]arenes: Synthesis, Structure, and Fullerene Complexation Property 期刊论文 Ren, Wen-Sheng|Zhao, Liang|Wang, Mei-Xiang|
18 Anion-directed assembly of a rectangular supramolecular cage in the solid state with electron-deficient phenoxylated oxacalix[2]arene[2]triazine 期刊论文 Fa, Shi-Xin|Liu, Yang|Hou, Bao-Yong|Wang, Mei-Xiang|
19 Bottom-up chemical synthesis of three dimensional conjugated carbon nanostructures: from carbon nanocages to carbon nanotubes 期刊论文 Wei Wang|Yu-Xuan Wang|Hai-Bo Yang|
20 Construction and Multiple Exterior Surface Functionalization of Giant Molecular Cages 期刊论文 Naseer, Muhammad Moazzam|Wang, De-Xian|Zhao, Liang|Wang, Mei-Xiang|
21 Synthesis, Structure, and Fullerene-Complexing Property of Azacalix[6]aromatics 期刊论文 Wang, Li-Xia|Wang, De-Xian|Zhao, Liang|Wang, Mei-Xiang|
22 Metallamacrocycle-modified gold nanoparticles: a new pathway for surface functionalization 期刊论文 Liu, Hai-Xia|He, Xin|Zhao, Liang|
23 Synthesis and Functionalization of Inherently Chiral Tetraoxacalix[2]arene[2]pyridines 期刊论文 Pan, Shuai|Wang, De-Xian|Zhao, Liang|Wang, Mei-Xiang|
24 Hierarchical Self-Assembly of Discrete Organoplatinum(II) Metallacycles with Polysaccharide via Electrostatic Interactions and Their Application for Heparin Detection 期刊论文 Tan, Hongwei|Liu, Minghua|Li, Xiaopeng|Yang, Hai-Bo|
25 A stepwise bulk-to-cluster-to-particle transformation toward the efficient synthesis of alkynyl-protected silver nanoclusters 期刊论文 Guo, Hui|He, Xin|Wan, Chong-Qing|Zhao, Liang|
26 Synthesis and Structure of Oxacalix[2]arene[2]triazines of an Expanded pi-Electron-Deficient Cavity and Their Interactions with Anions 期刊论文 Fa, Shi-Xin|Wang, Qi-Qiang|Wang, De-Xian|Wang, Mei-Xiang|
27 Growth of single-walled carbon nanotubes from Ag-15 cluster catalysts 期刊论文 Sun, Lifei|Xu, Guanchen|Jiao, Liying|Zhao, Liang|
28 Cu(OTf)(2)-Catalyzed Selective Arene C-H Bond Hydroxylation and Nitration with KNO2 as an Ambident 0-and N-Nucleophile via a Cu(ll)-Cu(III)-Cu(I) Mechanism 期刊论文 Hu Zhang|Liang Zhao|De-Xian Wang|Mei-Xiang Wang|
29 Macrocyclic Aryl Nickel(II) Complexes: Synthesis, Structure, and Reactivity Studies 期刊论文 Yang, Chi|Wu, Wen-Di|Zhao, Liang|Wang, Mei-Xiang|
30 Synthesis of Functionalized Azacalix[1]arene[3]pyridine Macrocycles from Cu(II)-Mediated Direct Amination Reactions of Arene through High Valent Arylcopper(III) Intermediates 期刊论文 Yang Liu|Qian Zhang|Qing-Hui Guo|Mei-Xiang Wang|
31 Synthesis, Structure, and Molecular Recognition of S-6- and (SO2)(6)-Corona[6](het)arenes: Control of Macrocyclic Conformation and Properties by the Oxidation State of the Bridging Heteroatoms 期刊论文 Guo, Qing-Hui|Zhao, Liang|Wang, Mei-Xiang|
32 Copper(I)-Catalyzed Halogenation and Acyloxylation of Aryl Triflates through a Copper(I)/Copper(III) Catalytic Cycle 期刊论文 Long, Chao|Zhao, Liang|You, Jing-Song|Wang, Mei-Xiang|
33 Supramolecular chemistry: defined 期刊论文 Wang, Mei-Xiang|
34 Structural Diversity in Coordination Self-Assembled Networks of a Multimodal Ligand Azacalix[4]pyrazine 期刊论文 Wu, Jin-Cheng|Zhao, Liang|Wang, De-Xian|Wang, Mei-Xiang|
35 Self-assembly of Pyrene-modified Rhomboidal Metallodendrimers via Directional Metal-ligand Bonding Approach 期刊论文 Abliz, Zeper|Tan, Hongwei|Xu, Lin|Yang, Haibo|
36 Designed synthesis of a metal cluster-pillared coordination cage 期刊论文 He, Xin|Gao, Cai-Yan|Wang, Mei-Xiang|Zhao, Liang|
37 Recent advances in the construction of fluorescent metallocycles and metallocages via coordination-driven self-assembly 期刊论文 Xu, Lin|Wang, Yu-Xuan|Yang, Hai-Bo|
38 Direct Synthesis of High-Valent Aryl-Cu(II) and Aryl-Cu(III) Compounds: Mechanistic Insight into Arene C-H Bond Metalation 期刊论文 Liang Zhao|De-Xian Wang|Bo-Qing Xu|Mei-Xiang Wang|
39 Selective Formylation of Azacalixpyridine Macrocycles and TheirTransformation to Molecular Semicages 期刊论文 Wen-Sheng Ren|Liang Zhao|Mei-Xiang Wang|
40 Synthesis of Electron-Deficient Oxacalix[2]arene[2]triazines and Their Isomeric Analogs from a One-Pot Reaction of Perfluorinated Dihydroxybenzenes with Dichlorotriazines 期刊论文 Chen, Yin|Wang, De-Xian|Zhao, Liang|Wang, Mei-Xiang|
41 Anion-pi Interactions: Generality, Binding Strength, and Structure 期刊论文 Wang, De-Xian|Wang, Mei-Xiang|
42 Design and construction of supramolecular polysulfurated metallodendrimers with various shapes and sizes via coordination-driven self-assembly 期刊论文 Ou-Yang, Jiang-Kun|Tan, Hongwei|Abliz, Zeper|Yang, Hai-Bo|
43 Syntheses and conformational structures of functionalized tetraoxacalix[2]arene[2]triazines 期刊论文 Pan, Shuai|Wang, De-Xian|Zhao, Liang|Wang, Mei-Xiang|
44 Novel platinum-acetylide metallocycles constructed via a stepwise fragment coupling approach and their aggregation behaviour 期刊论文 Xu, Lin|Wang, Cui-Hong|Zhao, Xiao-Li|Yang, Hai-Bo|
45 Cross-linked supramolecular polymer metallogels constructed via a self-sorting strategy and their multiple stimulus-response behaviors 期刊论文 Zhang, Chang-Wei|Shi, Jia-Meng|Yu, Yihua|Yang, Hai-Bo|
46 Positive homotropic allosteric binding of silver(I) ions in multidentate azacalixpyridine macrocycles: effect on the formation and stabilization of silver nanoparticles 期刊论文 He, Xin|Xu, Xiao-Bin|Wang, Xun|Zhao, Liang|
47 A macrocycle-assisted nanoparticlization process for bulk Ag2S 期刊论文 Wang, Yuechao|Gao, Cai-Yan|Jiang, Hong|Zhao, Liang|
48 C-aryl-C-alkyl bond formation from Cu(ClO4)(2)-mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar-Cu(III) intermediates 期刊论文 Wang, Zu-Li|Zhao, Liang|Wang, Mei-Xiang|
49 Synthesis, Structure and Coordination Self-Assembly of Azacalix[4-n]pyridine[n]pyrazines (n=1-3) 期刊论文 Wu, Jincheng|Zhao, Liang|Wang, Dexian|Wang, Meixiang|
50 Liquid crystalline macrocyclic azacalix[4]pyridine and its complexes with the zinc ion: conformational change from the saddle to flattened shape 期刊论文 Wang, De-Xian|Zhao, Liang|Chen, Er-Qiang|Wang, Mei-Xiang|
51 Light-Triggered Reversible Supramolecular Transformations of Multi-Bisthienylethene Hexagons 期刊论文 Chen, Li-Jun|Yang, Hai-Bo|Tian, He|Zhu, Weihong|
52 Synthesis and Molecular Recognition of Water-Soluble S-6-Corona[3]arene[3]pyridazines 期刊论文 Guo, Qing-Hui|Zhao, Liang|Wang, Mei-Xiang|
53 Cross-Linked Supramolecular Polymer Gels Constructed from Discrete Multi-pillar[5]arene Metallacycles and Their Multiple Stimuli-Responsive Behavior 期刊论文 Tan, Hongwei|Yu, Yihua|Lo, Xiaopeng|Yang, Hai-Bo|
54 Synthesis of Triangular Metallodendrimers via Coordination-Driven Self-Assembly 期刊论文 Tan, Hongwei|Abliz, Zeper|Yu, Yihua|Yang, Hai-Bo|
55 Designing a Cu(II)-ArCu(II)-ArCu(III)-Cu(I) Catalytic Cycle: Cu(II)-Catalyzed Oxidative Arene C-H Bond Azidation with Air as an Oxidant under Ambient Conditions 期刊论文 Liu, Yang|Zhao, Liang|Wang, De-Xian|Wang, Mei-Xiang|
56 Synthesis of functionalized azacalix[3]aromatics from azacalix[4]pyrimidine: unexpected macrocyclic transannular reactions 期刊论文 Li, Jiang-Tao|Wang, De-Xian|Zhao, Liang|Wang, Mei-Xiang|
57 Design and Construction of Endo-Functionalized Multiferrocenyl Hexagons via Coordination-Driven Self-Assembly and Their Electrochemistry 期刊论文 He, Jiuming|Tan, Hongwei|Abliz, Zeper|Yang, Hai-Bo|
58 Self-assembly of supramolecular tris(crown ether) hexagons with dendritic dibenzylammonium cations 期刊论文 Zhang, Yan-Yan|Gong, Han-Yuan|Yu, Yihua|Yang, Hai-Bo|
59 Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums 期刊论文 He, Xin|An, Ke|Zhu, Jun|Zhao, Liang|
60 One-pot synthesis of oxygen and nitrogen-bridged calix[2]arene[2]triazines 期刊论文 Wang, Xu-Dong|Wang, De-Xian|Huang, Zhi-Tang|Wang, Mei-Xiang|
61 Construction of C-aryl-C-alkynyl Bond from Copper-Mediated Arene-Alkyne and Aryl Iodide-Alkyne Cross-Coupling Reactions: A Common Aryl-Cu-III Intermediate in Arene C-H Activation and Castro-Stephens Reaction 期刊论文 Wang, Zu-Li|Zhao, Liang|Wang, Mei-Xiang|
62 Structurally Well-Defined Sigmoidal Gold Clusters: Probing the Correlation between Metal Atom Arrangement and Chiroptical Response 期刊论文 He, Xin|Wang, Yuechao|Jiang, Hong|Zhao, Liang|
63 Synthesis and Structure of Azacalix[2]pyrimidine[2]triazines and Their Self-assembly in the Solid State 期刊论文 Wang, Lixia|Wang, Dexian|Wang, Meixiang|
64 Coordination-Driven Self-Assembly of Charged and Neutral Dendritic Tetrakis(ferrocenyl) Rhomboids 期刊论文 Wang, De-Xian|Lehman, Danielle A.|Muddiman, David C.|Yang, Hai-Bo|
65 Dual templated synthesis of silver acetylide cluster-encapsulated supramolecular boxes 期刊论文 Gao, Cai-Yan|He, Xin|Zhao, Liang|Wang, Mei-Xiang|
66 A new family of supramolecular multiferrocenyl rhomboids: Synthesis, characterization, and their electrochemical behavior 期刊论文 Chen, Li-Jun|Xu, Lin|Wang, Cui-Hong|Yang, Hai-Bo|
67 A series of new star-shaped or branched platinum-acetylide derivatives: synthesis, characterization, and their aggregation behavior 期刊论文 Chen, Li-Jun|Xu, Lin|Liu, Shun-Ying|Yang, Hai-Bo|
68 Integration of acetylenic carbon clusters and silver clusters: template synthesis and stability enhancement 期刊论文 He, Xin|Liu, Hai-Xia|Zhao, Liang|
69 Synthesis and Structure of Corona[6](het)arenes Containing Mixed Bridge Units 期刊论文 Guo, Qjng-Hui|Zhao, Liang|Wang, De-Xian|Wang, Mei-Xiang|
70 Hierarchical self-assembly of a discrete hexagonal metallacycle into the ordered nanofibers and stimuli-responsive supramolecular gels 期刊论文 Ren, Yuan-Yuan|Li, Xiaopeng|Xu, Lin|Yang, Hai-Bo|
71 Cross-linked supramolecular polymer metallogels constructed via a self-sorting strategy and their multiple stimulus-response behaviors 期刊论文 Zhang, Chang-Wei|Shi, Jia-Meng|Yu, Yihua|Yang, Hai-Bo|
72 Recent progress in the construction of cavity-cored supramolecular metallodendrimers via coordination-driven self-assembly 期刊论文 Xu, Lin|Chen, Li-Jun|Yang, Hai-Bo|
73 Construction of Smart Supramolecular Polymeric Hydrogels Cross linked by Discrete Organoplatinum(II) Metallacycles via Post Assembly Polymerization 期刊论文 Li, Xiaopeng|Liu, Minghua|Chen, Guosong|Yang, Hai-Bo|
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