新型P-手性膦配体以及挑战性底物的高效不对称氢化研究

21272271
2012
B0106.不对称合成
陈卫平
面上项目
教授
中国人民解放军第四军医大学
80万元
不对称氢化;挑战性底物;大咬角;P-手性膦配体;反式螯合
2013-01-01到2016-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Very Simple and Highly Modular Synthesis of Ferrocene-Based Chiral Phosphines with a Wide Variety of Substituents at the Phosphorus Atom(s) 期刊论文 Wentao Shen|Decai Tuo|Xiaoying Li|Peng Zhou|
2 An efficient and practical synthesis of BINAM derivatives by diastereoselective [3,3]-rearrangement 期刊论文 B. Li|S. Zhang|W. Chen|
3 A new type of ferrocene-based phosphine-tertbutylsulfinamide ligand: synthesis and application in asymmetric catalysis 期刊论文 Y. Lei|M. Li|R. Jiang*|W. Chen*|
4 A Stereospecific Synthesis and Unambiguous Assignment of the Absolute Configuration of (-)-erythro-Mefloquine Hydrochloride 期刊论文 X. Liu|H. Nie|S. Zhang|W. Chen|
5 Enantioselective Morita–Baylis–Hillman Reaction of Acrylates with Nitrobenzaldehydes Promoted by the Bifunctional Ferrocene-Based Phosphinothiourea Organocatalysts 期刊论文 Hui Chen|Shao-Yu Guan|Ru Jiang|Wei-Ping Chen|
6 Novel ferrocene-based bifunctional amine–thioureas for asymmetric Michael addition ofacetylacetone to nitroolefins 期刊论文 Y. Chai*|W. Yao|W. Chen|S. Zhang*|
7 Bifunctional ferrocene-based squaramide-phosphine as an organocatalyst for highly enantioselective intramolecular Morita-Baylis-Hillman reaction 期刊论文 Y. Lei|S. Zhang|R. Jiang|W. Chen|
8 Highly Enantioselective Hydrogenationof α-oxy Functionalized α, β-unsaturated Acids Catalyzed by a ChenPhos-RhComplex in CF3CH2OH 期刊论文 N. M. Wood|W. Chen*|S. Zhang*|X. Zhang*|
9 Ferrocene as a scaffold for effective bifunctional amine-thiourea organocatalysts 期刊论文 X. Liu|R. Jiang|S. Zhang|W. Chen|
10 Three-step synthesis of L-ido-1-deoxynojirimycin derivatives by reductive amination in water, “borrowing hydrogen” under neat conditions and deprotection 期刊论文 Kai Zhao|Gang Zhou|Huifang Nie|Weiping Chen|
11 Practical Access to Planar Chiral 1,2-(a-Ketotetramethylene)-ferrocene by Non-Enzymatic Kinetic Resolution and Conclusive Confirmation of its Absolute Configuration 期刊论文 T. H. Hall|G. J. Clarkson|M. Wills*|W. Chen*|
12 Highly enantioselective hydrogenation of 2-substituted-2-alkenols catalysed by a ChenPhos-Rh complex 期刊论文 B. Li|H. Nie|S. Zhang|W. Chen|
13 Diphenylprolinol silyl ether-derived thioureas as highly efficient catalysts for the asymmetric Michael addition of aldehydes to nitroalkenes 期刊论文 Y. Feng|Y. Chai*|S. Zhang|W. Chen*|
14 Enantioselective Morita–Baylis–Hillman Reaction of Acrylates with Nitrobenzaldehydes Promoted by the Bifunctional Ferrocene-Based Phosphinothiourea Organocatalysts 期刊论文 Hui Chen|Shao-Yu Guan|Ru Jiang|Wei-Ping Chen|
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