1,3-共轭二烯的高选择性双官能团化反应研究及其在天然产物全合成中的应用

21871178
2018
B0106.不对称合成
陈志敏
面上项目
副教授
上海交通大学
65万元
不对称串联反应;不对称合成;天然产物合成;手性配体;不对称金属催化
2019-01-01到2022-12-31
  • 中英文摘要
  • 结题摘要
  • 结题报告
  • 项目成果
  • 项目参与人
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序号 标题 类型 作者
1 Chiral Lewis Base Catalyzed Enantioselective Selenocyclization of 1,1-Disubstituted Alkenes: Asymmetric Synthesis of Selenium-Containing 4H-3,1-Benzoxazines 期刊论文 Ren-Fei Cao;Lu Yu;Yu-Xuan Huo;Yao Li;Xiao-Song Xue;Zhi-Min Chen
2 Atroposelective Electrophilic Sulfenylation of N-Aryl Aminoquinone Derivatives Catalyzed by Chiral SPINOL-Derived Sulfide 期刊论文 Deng Zhu;Lu Yu;Hui-Yun Luo;Xiao-Song Xue;Zhi-Min Chen
3 Lewis Base/Brønsted Acid Co-Catalyzed Asymmetric Thiolation of Alkenes with Acid-Controlled Divergent Regioselectivity 期刊论文 Hui-Yun Luo;Jia-Wei Dong;Yu-Yang Xie;Xu-Feng Song;Deng Zhu;Tong-Mei Ding;Yuanyuan Liu;Zhi-Min Chen
4 Brønsted Acid-Catalyzed Solvent-Controlled Regioselective Hydrothiolation and Diastereoselective Cascade Cyclization of Dienes 期刊论文 Kai Ji;Ka Lu;Jie Huang;Zi-Hao Li;Tong-Mei Ding;Zhi-Min Chen
5 Chiral Selenide/Achiral Sulfonic Acid Cocatalyzed Atroposelective Sulfenylation of Biaryl Phenols via a Desymmetrization/Kinetic Resolution Sequence 期刊论文 Hui-Yun Luo;Zi-Hao Li;Deng Zhu;Qin Yang;Ren-Fei Cao;Tong-Mei Ding;Zhi-Min Chen
6 Phosphoric Acid Catalyzed Electrophilic Thiocyanation of Indoles: Access to SCN-Containing Aryl-Indole Compounds 期刊论文 Ai-Hui Ye;Zi-Hao Li;Tong-Mei Ding;Hua Ke;Zhi‐Min Chen
7 N-Selenocyanato-Dibenzenesulfonimide: A New Electrophilic Selenocyanation Reagent 期刊论文 朱登;叶爱慧;陈志敏
8 一种手性联萘催化剂及其制备方法和应用 专利 陈志敏;罗会云;丁同梅;朱登;杨钦
9 Oxyallyl Cation Promoted Dearomative Semipinacol Rearrangement: Facile Stereodivergent Synthesis of Spiro-indolines with Contiguous Quaternary Centers 期刊论文 谢屿阳;王云鹏;赵晓静;王爱芳;陈志敏;涂永强
10 Electrochemical Semipinacol Rearrangements of Allylic Alcohols: Construction of All-Carbon Quaternary Stereocenters 期刊论文 康骏宸;涂永强;董嘉炜;陈超;周佳;丁同梅;宰建陶;陈志敏;张书宇
11 Lewis-Acid-Mediated Thiocyano Semipinacol Rearrangement of Allylic Alcohols for Construction of α-Quaternary Center β-Thiocyano Carbonyls 期刊论文 Xu-Feng Song;Ai-Hui Ye;Yu-Yang Xie;Jia-Wei Dong;Chao Chen;Ye Zhang;Zhi-Min Chen
12 Palladium-Catalyzed Three-Component Cross-Coupling of Conjugated Dienes with Indoles Using Ethynylbenziodazolones as Electrophilic Alkynylating Reagents 期刊论文 Jie Huang;Ling-Ling Chen;Zhi-Min Chen
13 Brønsted Acid-Catalyzed Regioselective Hydrothiolation of Dienes: Solvent-Controlled Divergent Synthesis of Sulfides 期刊论文 Kai Ji;Ka Lu;Jie Huang;Zi-Hao Li;Hua Ke;Zhi-Min Chen
14 Lewis Base/Brønsted Acid Co-catalyzed Enantioselective Sulfenylation/Semipinacol Rearrangement of Di- and Trisubstituted Allylic Alcohols 期刊论文 Yu-Yang Xie;Zhi-Min Chen;Hui-Yun Luo;Hui Shao;Yong-Qiang Tu;Xiaoguang Bao;Ren-Fei Cao;Shu-Yu Zhang;JIn-Miao Tian
15 Catalytic Enantioselective Dihalogenation of Alkenes 期刊论文 Jia-Wei Dong;Ren-Fei Cao;Zhi-Min Chen
16 Electrophilic Thiocyanation of Tryptamine Derivatives: Divergent Synthesis of SCN-Containing Indole Compounds 期刊论文 Ai-Hui Ye;Xu-Feng Song;Zhi‐Min Chen
17 Iron-Catalyzed Hydroarylation of 1,3-Dienes with Indoles 期刊论文 Jie Huang;Ling-Ling Chen;Tong-Mei Ding;Zhi-Min Chen
18 一种手性硫/硒化合物及其制备方法和应用 专利 陈志敏;宋旭峰;丁同梅;罗会云
19 上海市高校特聘教授计划(东方学者) 奖励 陈志敏
20 Lewis-Acid-Mediated Intramolecular Trifluoromethylthiolation of Alkenes with Phenols: Access to SCF3-Containing Chromane and Dihydrobenzofuran Compounds 期刊论文 宋旭峰;丁同梅;朱登;黄杰;陈志敏
21 Selenium-Catalyzed Trifluoromethylsulfinylation/Rearrangement of Allylic and Propargylic Alcohols: Access to Allylic and Allenic Triflones 期刊论文 Deng Zhu;Hui-Yun Luo;Zhi-Min Chen
22 The alkynylative difunctionalization of alkenes 期刊论文 Jie Huang;Zhi-Min Chen
23 Lewis Base-Catalyzed Asymmetric Sulfenylation of Alkenes: Construction of Sulfenylated Lactones and Application to the Formal Syntheses of (-)-Nicotlactone B and (-)-Galbacin 期刊论文 Hui-Yun Luo;Yu-Yang Xie;Xu-Feng Song;Jia-Wei Dong;Deng Zhu;Zhi-Min Chen
24 Chiral Sulfide/Phosphoric Acid Cocatalyzed Enantioselective Intermolecular Oxysulfenylation of Alkenes with Phenol and Alcohol O-nucleophiles 期刊论文 Xiao-Dong Liu;Yicong Luo;Xiaohong Huo;Hui-Yun Luo;Ren-Fei Cao;Zhi-Min Chen
25 Enantioselective 1,1-Diarylation of Allyl Sulfones Catalyzed by Palladium with a Chiral Phosphoric Acid 期刊论文 Kai Ji;Jie Huang;Xin-Yu Zhang;Zhi-Min Chen
26 TMSCl-Catalyzed Electrophilic Thiocyano Oxyfunctionalization of Alkenes Using N-Thiocyano-dibenzenesulfonimide 期刊论文 Ai-Hui Ye;Ye Zhang;Yu-Yang Xie;Hui-Yun Luo;Jia-Wei Dong;Xiao-Dong Liu;Xu-Feng Song;Tong-Mei Ding;Zhi-Min Chen
27 Electrochemical halogenation/semi-pinacol rearrangement of allylic alcohols using inorganic halide salt: an eco-friendly route to the synthesis of β-halocarbonyls 期刊论文 陈超;康骏宸;毛辰;董嘉炜;谢屿阳;丁同梅;涂永强;陈志敏;张书宇
28 Divergent Synthesis of Trifluoromethyl Sulfoxides and beta-SCF3 Carbonyl Compounds by Tandem Trifluoromethylthiolation/Rearrangement of Allylic and Propargylic Alcohols 期刊论文 朱登;丁同梅;罗会云;柯华;陈志敏
29 Application of Chiral Lewis Base/Brønsted Acid Synergistic Catalysis Strategy in Enantioselective Synthesis of Organic Sulfides 期刊论文 朱登;陈志敏
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